Shampoo composition containing a gel network
A shampoo composition having from about 5% to about 50% of a combination of sodium lauryl sulfate and sodium laureth-n sulfate, less than 3.82% of sodium laureth-n sulfate having n>1. The shampoo composition further includes from about 0.5% to about 3% of a co-surfactant selected from the group consisting of amphoteric, zwitterionic, and nonionic surfactants. The shampoo composition has a dispersed gel network phase having at least 0.05% of one or more fatty alcohols, at least 0.01% of one or more secondary surfactants, and water. The shampoo composition further includes at least about 20% of an aqueous carrier. The shampoo composition further has an enthalpy of transition from about 0 J/g to about 0.2 J/g as measured according to differential scanning calorimetry in a peak melt transition temperature range between about 18° C. to about 30° C.
1. A shampoo composition comprising:
a. a dispersed gel network phase comprising:
i. at least 0.05% of one or more fatty alcohols, by weight of said shampoo composition;
ii. at least 0.01% of one or more secondary surfactants by weight of said shampoo composition selected from the group consisting of anionic surfactants, cationic surfactants, non-ionic surfactants and mixtures thereof; and
iii. water; and
b. from about 5% to about 50% of a combination of sodium lauryl sulfate and sodium laureth-n sulfate;
c. less than 3.82% of sodium laureth-n sulfate having n>1;
d. greater than 0.5% sodium laureth-1 sulfate;
e. from about 0.5% to about 3% of a co-surfactant selected from the group consisting of amphoteric, zwitterionic, and nonionic surfactants, by weight of said shampoo composition;
f. at least 20% of an aqueous carrier, by weight of said shampoo composition;
wherein said shampoo composition has an enthalpy of transition from about 0 J/g to about 0.2 J/g as measured according to differential scanning calorimetry in a peak melt transition temperature range between about 18° C. to about 30° C.
2. The shampoo composition according to claim 1 , wherein said shampoo composition comprises from about 10% to about 17% of said combination of sodium lauryl sulfate and sodium laureth-n sulfate.
3. The shampoo composition according to claim 1 , wherein said shampoo composition comprises from about 0.5% to about 2% of a co-surfactant selected from the group consisting of amphoteric, zwitterionic, and nonionic surfactants, by weight of said shampoo composition.
4. The shampoo composition according to claim 1 , wherein said shampoo composition comprises from about 0.5% to about 1.75% of a co-surfactant selected from the group consisting of amphoteric, zwitterionic, and nonionic surfactants, by weight of said shampoo composition.
5. The shampoo composition according to claim 1 , wherein said shampoo composition comprises from about 4% to about 9% sodium lauryl sulfate, by weight of said shampoo composition.
6. The shampoo composition according to claim 1 , wherein said shampoo composition comprises from 0.5% to about 5% sodium laureth-1 sulfate, by weight of said shampoo composition.
7. The shampoo composition according to claim 1 , wherein said dispersed gel network phase comprises from about 0.05% to about 14% of one or more fatty alcohols by weight of said shampoo composition.
8. The shampoo composition according to claim 1 , wherein said one or more fatty alcohols is selected from the group consisting of cetyl alcohol, stearyl alcohol, behenyl alcohol, and mixtures thereof.
9. The shampoo composition according to claim 1 , wherein said dispersed gel network phase comprises from about 0.2% to about 5% of one or more secondary surfactants by weight of said shampoo composition.
10. The shampoo composition according to claim 1 , wherein said secondary surfactant is selected from the group consisting of anionic surfactants, cationic surfactants, non-ionic surfactants and mixtures thereof.
11. The shampoo composition according to claim 1 , wherein said secondary surfactant is selected from the group consisting of cetrimonium chloride, stearimonium chloride, behentrimonium chloride, behentrimonium methosulfate, behenamidopropyltrimonium methosulfate, stearamidopropyltrimonium chloride, arachidtrimonium chloride, distearyldimonium chloride, dicetyldimonium chloride, tricetylmonium chloride, and mixtures thereof.
12. The shampoo composition according to claim 1 , wherein said secondary surfactant is selected from the group consisting of ammonium lauryl sulfate, ammonium laureth sulfate, triethylamine lauryl sulfate, triethylamine laureth sulfate, triethanolamine lauryl sulfate, triethanolamine laureth sulfate, monoethanolamine lauryl sulfate, monoethanolamine laureth sulfate, diethanolamine lauryl sulfate, diethanolamine laureth sulfate, lauric monoglyceride sodium sulfate, sodium lauryl sulfate, sodium laureth sulfate, potassium lauryl sulfate, potassium laureth sulfate, sodium lauryl sarcosinate, sodium lauroyl sarcosinate, lauryl sarcosine, cocoyl sarcosine, ammonium cocoyl sulfate, ammonium lauroyl sulfate, sodium cocoyl sulfate, sodium lauroyl sulfate, potassium cocoyl sulfate, potassium lauryl sulfate, triethanolamine lauryl sulfate, triethanolamine lauryl sulfate, monoethanolamine cocoyl sulfate, monoethanolamine lauryl sulfate, sodium tridecyl benzene sulfonate, sodium dodecyl benzene sulfonate, sodium cocoyl isethionate, and mixtures thereof.
13. The shampoo composition according to claim 1 , wherein said shampoo composition has an enthalpy of transition from about 0 J/g to about 0.1 J/g as measured according to differential scanning calorimetry in a peak melt transition temperature range between about 18° C. to about 30° C.
14. The shampoo composition according to claim 1 , wherein said dispersed gel network phase further comprises one or more fatty compounds selected from the group consisting of fatty amides, di-fatty ethers, fatty carbamates, fatty acids, fatty esters, fatty phosphorous compounds, fatty sorbitan derivatives, alkyl sulfoxides, and mixtures thereof.
15. The shampoo composition according to claim 1 , wherein said zwitterionic surfactant is a betaine.
16. The shampoo composition according to claim 1 , wherein said zwitterionic surfactant is a sultaine.
17. The shampoo composition according to claim 1 , wherein said nonionic surfactant is a cocomonethanolamine.
18. The shampoo composition according to claim 1 , wherein said shampoo composition has:
a. a zero shear viscosity between about 1,000 cps to about 30,000 cps; and
b. a frequency at a crossover point greater than 2 Hz.
19. A process for preparing the shampoo composition according to claim 1 , said process comprising the steps of:
a. combining a fatty alcohol and a surfactant in a weight ratio of fatty alcohol to surfactant of about 1:1 to about 40:1 and at a temperature sufficient to allow partitioning of the surfactant into the fatty alcohol to form a premix;
b. cooling the premix below the chain melt temperature of the fatty alcohol to form a solid crystalline gel network; and
c. adding the solid crystalline gel network to a detersive surfactant and an aqueous carrier to form a shampoo composition.
20. A shampoo composition comprising:
a. a dispersed gel network phase comprising:
i. at least 0.05% of one or more fatty alcohols, by weight of said shampoo composition;
ii. at least 0.01% of one or more secondary surfactants by weight of said shampoo composition selected from the group consisting of anionic surfactants, cationic surfactants, non-ionic surfactants and mixtures thereof; and
iii. water; and
b. from about 5% to about 50% of a combination of sodium lauryl sulfate and sodium laureth-n sulfate;
c. less than 3.82% of sodium laureth-n sulfate having n>1;
d. greater than 0.5% sodium laureth-1 sulfate;
e. from about 0.5% to about 3% of a co-surfactant selected from the group consisting of amphoteric, zwitterionic, and nonionic surfactants, by weight of said shampoo composition;
f. at least 20% of an aqueous carrier, by weight of said shampoo composition;
wherein said shampoo composition has an enthalpy of transition from about 0 J/g to about 0.2 J/g as measured according to differential scanning calorimetry in a peak melt transition temperature range between about 18° C. to about 30° C.; and
wherein said shampoo composition has a zero shear viscosity between about 1,000 cps to about 30,000 cps, and a frequency at a crossover point greater than 2 Hz.