IP Library Granted Patent US 8,673,211
Granted Patent B1
US 8,673,211 · App. 13/134,958 · Granted Mar 18, 2014

Method to reduce corrosion of aluminum alloys exposed to seawater

Inventors: Luis E. Lema (North Attleboro, MA); Robert J. Angeli (Portsmouth, RI)
Assignee: The United States of America as repesented by the Secretary of Navy
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Quick Facts
Patent No.
US 8,673,211
App. No.
13/134,958
Granted
Mar 18, 2014
Kind
B1
Abstract

A method is taught to alleviate some of the expected seawater corrosion of aluminum alloy fuel tanks originating from the chlorides present in seawater through the use of a dicarboxylic acid additive that is added to the aluminum alloy fuel tank when seawater enters the tank.

Claims (31)

1. A method for reducing corrosion of aluminum alloys exposed to seawater comprising:

providing a dicarboxylic organic acid;

reacting the dicarboxylic organic acid to make a salt of the dicarboxylic organic acid;

adding 2-nitrodiphenylamine at a percentage of 6.25% to the salt of the dicarboxylic organic acid;

exposing the mixture of 2-nitrodiphenylamine and the salt of dicarboxylic organic, acid to the interior surface of an aluminum alloy fuel tank for use with Otto fuel.

2. The method of claim 1 wherein the dicarboxylic organic acid is sebacic acid.

3. The method of claim 2 wherein the salt of dicarboxylic organic acid is zinc monohydrate sebacate.

4. The method of claim 2 wherein the salt of dicarboxylic organic acid is aluminum monohydrate sebacate.

5. The method of claim 1 wherein the step of exposing the mixture of 2-nitrodiphenylamine and the salt of dicarboxylic organic acid to the interior surface of an aluminum alloy fuel tank comprises adding the mixture of 2-nitrodiphenylamine and the salt of dicarboxylic organic acid to a quantity of Otto fuel for use in said aluminum alloy fuel tank.

6. The method of claim 1 wherein the step of exposing the mixture of 2-nitrodiphenylamine and the salt of dicarboxylic organic acid to the interior surface of an aluminum alloy fuel tank comprises:

combining the mixture of 2-nitrodiphenylamine and the salt of dicarboxylic organic acid with a chemically neutral grease; and

applying the combined chemically neutral grease and mixture of 2-nitrodiphenylamine and the salt of dicarboxylic organic acid to the interior surface of the aluminum alloy fuel tank.

7. The method of claim 1 wherein the step of exposing the mixture of 2-nitrodiphenylamine and the salt of dicarboxylic organic acid to the interior surface of an aluminum alloy fuel tank comprises:

combining the mixture of 2-nitrodiphenylamine and the salt of dicarboxylic organic acid with a chemically neutral liquid; and

spraying the combined chemically neutral liquid and mixture of 2-nitrodiphenylamine and the salt of dicarboxylic organic acid to the interior surface of the aluminum alloy fuel tank.

8. The method of claim 1 wherein the step of exposing the mixture of 2-nitrodiphenylamine and the salt of dicarboxylic organic acid to the interior surface of an aluminum alloy fuel tank comprises applying the mixture of 2-nitrodiphenylamine and the salt of dicarboxylic organic acid to the interior surface of the aluminum alloy fuel tank through cathodic application.

9. A method for reducing corrosion of aluminum alloys exposed to seawater comprising:

providing a dicarboxylic organic acid;

reacting the dicarboxylic organic acid to make an ester of the dicarboxylic organic acid;

adding 2-nitrodiphenylamine at a percentage of 6.25% to the ester of the dicarboxylic organic acid;

exposing the mixture of 2-nitrodiphenylamine and the salt of dicarboxylic organic acid to the interior surface of an aluminum alloy fuel tank for use with Otto fuel.

10. The method of claim 9 wherein the dicarboxylic organic acid is sebacic acid.

11. The method of claim 10 wherein the ester of dicarboxylic organic acid is butyl monohydrate sebacate.

12. The method of claim 9 wherein the step of exposing the mixture of 2-nitrodiphenylamine and the ester of dicarboxylic organic acid to the interior surface of an aluminum alloy fuel tank comprises adding the mixture of 2-nitrodiphenylamine and the ester of dicarboxylic organic acid to a quantity of Otto fuel for use in said aluminum alloy fuel tank.

13. The method of claim 9 wherein the step of exposing the mixture of 2-nitrodiphenylamine and the ester of dicarboxylic organic acid to the interior surface of an aluminum alloy fuel tank comprises:

combining the mixture of 2-nitrodiphenylamine and the ester of dicarboxylic organic acid with a chemically neutral grease; and

applying the combined chemically neutral grease and mixture of 2-nitrodiphenylamine and the ester of dicarboxylic organic acid to the interior surface of the aluminum alloy fuel tank.

14. The method of claim 9 wherein the step of exposing the mixture of 2-nitrodiphenylamine and the ester of dicarboxylic organic acid to the interior surface of an aluminum alloy fuel tank comprises:

combining the mixture of 2-nitrodiphenylamine and the ester of dicarboxylic organic acid with a chemically neutral liquid; and

spraying the combined chemically neutral liquid and mixture of 2-nitrodiphenylamine and the ester of dicarboxylic organic acid to the interior surface of the aluminum alloy fuel tank.

15. The method of claim 9 wherein the step of exposing the mixture of 2-nitrodiphenylamine and the ester of dicarboxylic organic acid to the interior surface of an aluminum alloy fuel tank comprises applying the mixture of 2-nitrodiphenylamine and the ester of dicarboxylic organic acid to the interior surface of the aluminum alloy fuel tank through cathodic application.

Assignments (1)
CONFIRMATORY LICENSE Recorded Jul 14, 2011
From: LEMA, LUIS E.; ANGELI, ROBERT J.
To: UNITED STATES OF AMERICA NAVAL UNDERSEA WARFARE CENTER, DIVISION, NEWPORT, OFFICE OF COUNSEL, THE
Reel/Frame 026595/0584 →