Process for production of heat-shrinkable polyester film, heat-shrinkable polyester film and packages
The invention aims at providing a heat-shrinkable polyester film which is excellent in tearability along perforations and in break resistance after storage when used as labels of beverage bottles. The invention relates to a heat-shrinkable polyester film which is made of a polyester resin comprising ethylene terephthalate as the main constituent and containing at least 13 mol % of at least one monomer capable of forming an amorphous component in the whole polyester resin component and which has specific heat shrinkage characteristics and exhibits specific mechanical characteristics after heat shrinking treatment. The film can be produced by a sequential biaxial orientation process comprising longitudinal orientation step, intermediate heat treatment step, positive cooling step, transverse orientation step, and final heat treatment step.
1. A process for producing a heat-shrinkable polyester film comprising the following steps (a) to (e) with respect to an undrawn polyester film prepared from a polyester resin component comprising (i) a polyester resin with ethylene terephthalate as the main constituent and (ii) at least 13 mo1% of at least one monomer component capable of forming an amorphous component in the polyester resin component:
(a) a lengthwise drawing step of drawing the undrawn film at a temperature of not less than 75° C. and not more than 100° C. by not less than 1.1 times and not more 1.8 times in the longitudinal direction;
(b) an intermediate heat treatment step of heat-treating the film after the lengthwise drawing at a temperature of not less than 110° C. and not more than 150° C. for not less than 7 seconds and not more than 28 seconds in a state of holding both ends in the width direction by clips in a tenter;
(c) a forced cooling step of positively cooling the film after the intermediate heat treatment till the surface temperature becomes a temperature of not less than 70° C. and not more than 90° C.;
(d) a transverse drawing step of drawing the film after the forced cooling at a temperature of not less than 65° C. and not more than 90° C. by not less than 3.5 times and not more than 5.0 times in the width direction; and
(e) a final heat treatment step of heat-treating the film after the transverse drawing at a temperature of not less than 80° C. and not more than 100° C. for not less than 5 seconds and not more than 30 seconds in a state of holding both ends in the width direction by clips in a tenter,
wherein the heat-shrinkable polyester film satisfies the following requirements (1) to (4):
(1) the hot-water shrinkage in the longitudinal direction is not less than −2% and not more than 4% when the heat-shrinkable polyester film is treated in hot water of 80° C. for 10 seconds;
(2) the hot-water shrinkage in the width direction is not less than 50% and not more than 80% when the heat-shrinkable polyester film is treated in hot water of 95° C. for 10 seconds;
(3) the number of initial breakages, which is the number of breakages before 5% extension, is not more than 7 when the heat-shrinkable polyester film is repeatedly subjected to a tensile test 10 times in the longitudinal direction using a tensile tester with a distance between chucks of 100 mm after being aged in an atmosphere of 85%RH at 30° C. for 672 hours; and
(4) the perpendicular tear strength to the longitudinal direction per unit thickness is not less than 300 N/mm and not more than 410 N/mm after the heat-shrinkable polyester film is shrunk by 10% in the width direction in hot water of 80° C.
2. The process of claim 1 , wherein the heat-shrinkable polyester film has a solvent adhesive strength of 2 N/15mm width or more and 10 N/15mm width or less.