Adhesive agent
Provided are a pressure-sensitive adhesive having excellent durability and reliability under high-temperature or high-humidity conditions, adhesion strength, workability, re-movability, and the ability to inhibit light leakage; a method for preparing the pressure-sensitive adhesive; a polarizer including the pressure-sensitive adhesive; and a liquid crystal display incorporating the polarizer.
1. A polarizer including a pressure-sensitive adhesive on one or both surfaces of a polarizing film or a polarizing element,
wherein the pressure-sensitive adhesive comprises a hard area and a soft area having a lower storage modulus than the hard area, the hard area and the soft area being patterned within a single plane.
2. The polarizer according to claim 1 , wherein the hard area has a storage modulus ranging from 1 MPa to 50 MPa at 30° C.
3. The polarizer according to claim 1 , wherein the soft area has a storage modulus ranging from 0.01 MPa to 5.0 MPa at 30° C.
4. The polarizer according to claim 1 , wherein the hard area is patterned in the shape of a line.
5. The polarizer according to claim 4 , wherein the hard area is patterned in the shape of a continuous line.
6. The polarizer according to claim 4 , wherein the hard area patterned in the shape of a line has a width of 90 μm to 1,000 μm.
7. The polarizer according to claim 1 , wherein the ratio (G′ hard /G′ soft ) of the storage modulus (G′ hard ) of the hard area to the storage modulus (G′ soft ) of the soft area is 3 to 100.
8. The polarizer according to claim 1 , wherein the hard area occupies an area of 10% to 60%, relative to the entire area of the pressure-sensitive adhesive.
9. The polarizer according to claim 1 , wherein the pressure-sensitive adhesive has a gel content of 50% to 99%, the gel content being expressed by equation 1 below:
Gel Content = B/A ×100 [Equation 1]
where A represents the weight of the pressure-sensitive adhesive, and B represents the weight of the undissloved parts of the pressure-sensitive adhesive, the weight of the undissloved parts being measured after depositing the pressure-sensitive adhesive in ethyl acetate for 72 hours at room temperature, and drying the deposits.
10. The polarizer according to claim 1 , wherein the pressure-sensitive adhesive includes an interpenetrating polymer network.
11. The polarizer according to claim 1 , wherein the hard area in the pressure-sensitive adhesive is patterned in the shape of a line, and the line pattern is formed parallel to the direction of elongation of the polarizing film or the polarizing element.
12. The polarizer according to claim 1 , wherein the hard area in the pressure-sensitive adhesive is patterned in the shape of a line, and the line pattern is formed perpendicular to the direction of elongation of the polarizing film or the polarizing element.
13. The polarizer according to claim 1 , wherein the hard area in the pressure-sensitive adhesive is patterned in a shape of a line, and the line pattern includes a pattern formed parallel to the direction of elongation of the polarizing film or the polarizing element and a pattern formed perpendicular to the direction of elongation.
14. A liquid crystal display comprising a liquid crystal panel, in which the polarizer according to claim 1 is attached on one or both surfaces of a liquid crystal cell.