Methods and systems for separating condensable vapors from gases
Condensable vapors such as carbon dioxide are separated from light gases in a process stream. The systems and methods employ a particle bed cooled by an in-bed heat exchanger to desublimate the condensable vapors from the process stream. The condensable vapors are condensed on the bed particles while the light gases from the process stream, which are not condensed, form a separated light-gas stream. The separated light-gas stream can be used in a recuperative heat exchanger to cool the process stream.
1. A system for separating condensable vapors from gases to form a solid, comprising:
a separation vessel having a process stream inlet, a light gas outlet, and a solids outlet separate from the light gas outlet, wherein the process stream inlet is in fluid communication with a process stream that includes condensable vapors;
a bed of particles within the separation vessel, the bed of particles in fluid communication with the process stream, wherein the process stream has sufficient pressure to flow through at least a portion of the bed of particles; and
an in-bed heat exchanger comprising one or more conduits at least partially submerged in the bed of particles;
wherein the temperature and pressure within the bed are sufficient to desublimate at least a portion of the condensable vapors from the process stream onto the bed of particles and/or onto an exterior of the conduit of the in-bed heat exchanger so as to form a condensed solid and a separated light gas stream,
wherein the light gas outlet is configured so that the separated light gas stream exits the separation vessel through the light gas outlet,
wherein the solids outlet is configured so that the condensed solid exits the separation vessel through the solids outlet.
2. A system as in claim 1 , wherein the bed of particles is fluidized.
3. A system as in claim 2 , wherein an impingement of the particles of the bed removes a portion of buildup of condensed solid from the exterior of the conduit.
4. A system as in claim 1 , wherein the condensable vapors include carbon dioxide and the condensed solid includes solid carbon dioxide.
5. A system as in claim 4 , wherein the temperature and pressure within the bed are suitable for desublimating at least a portion of the carbon dioxide vapors.
6. A system as in claim 1 , wherein the pressure is within a range from about atmospheric pressure to about 15 psi.
7. A system as in claim 1 , wherein the pressure is within a range from about atmospheric pressure to about 5 psi.
8. A system as in claim 1 , wherein the temperature within the bed is less than about −78° C.
9. A system as in claim 1 , wherein the bed of particles have an average particle size in a range from about 0.05 mm to about 20 mm.
10. A system as in claim 1 , wherein the bed of particles have an average particle size in a range from about 0.1 mm to about 10 mm.
11. A system as in claim 1 , wherein the bed of particles includes particles comprising solid carbon dioxide.
12. A system as in claim 1 , further comprising an expansion device downstream from the separation vessel, the expansion device configured to cool the light gas stream by reducing the pressure, wherein the cooled light gas stream flows through an interior of the conduit of the in-bed heat exchanger.
13. A system as in claim 1 , further comprising a recuperative heat exchanger configured to cool the process stream upstream from the separation vessel using the separated light gas downstream from the separation vessel.
14. A system as in claim 1 , further comprising a particle inlet for introducing particles into the separation vessel.
15. A system as in claim 1 , further comprising an auger or other mechanism for removing particles from the separation vessel.
16. A system as in claim 1 , wherein the one or more conduits of the in-bed heat exchanger at least partially submerged in the bed of particles are placed horizontally relative to one another.
17. A system as in claim 1 , wherein the one or more conduits of the in-bed heat exchanger at least partially submerged in the bed of particles are placed vertically relative to one another.
18. A system for separating condensable carbon dioxide from gases to form solid carbon dioxide, comprising:
a separation vessel having a process stream inlet, a light gas outlet, and a solids outlet separate from the light gas outlet, wherein the process stream inlet is in fluid communication with a process stream that includes condensable carbon dioxide vapor;
a bed of particles within the separation vessel, the bed of particles in fluid communication with the process stream, wherein the process stream has sufficient pressure to flow through at least a portion of the bed of particles; and
an in-bed heat exchanger comprising one or more conduits at least partially submerged in the bed of particles;
wherein the temperature and pressure within the bed are sufficient to desublimate at least a portion of the carbon dioxide from the process stream onto the bed of particles and/or onto an exterior of the conduit of the in-bed heat exchanger so as to form a condensed solid carbon dioxide and a separated light gas stream,
wherein the light gas outlet is configured so that the separated light gas stream exits the separation vessel through the light gas outlet,
wherein the solids outlet is configured so that the condensed solid carbon dioxide exits the separation vessel through the solids outlet.
19. A system as in claim 18 , wherein the bed of particles is fluidized and wherein an impingement of the particles of the bed removes a portion of buildup of condensed solid carbon dioxide from the exterior of the conduit.
20. A system as in claim 18 , wherein the in-bed heat exchanger is configured so that the temperature within the bed is less than about −78° C.
21. A system for separating condensable vapors from gases to form a solid, comprising:
a separation vessel having a process stream inlet, a light gas outlet, and a solids outlet separate from the light gas outlet, wherein the process stream inlet is in fluid communication with a process stream that includes condensable vapors;
a bed of fluidizable particles within the separation vessel, the bed of fluidizable particles in fluid communication with the process stream, wherein the process stream has sufficient pressure to flow through at least a portion of the bed of fluidizable particles and sufficient mass air flow to cause the particles to be fluidized; and
an in-bed heat exchanger comprising one or more conduits at least partially submerged in the bed of particles;
wherein the temperature and pressure within the bed are sufficient to desublimate at least a portion of the condensable vapors from the process stream onto the bed of particles and/or onto an exterior of the conduit of the in-bed heat exchanger so as to form a condensed solid and a separated light gas stream,
wherein the light gas outlet is configured so that the separated light gas stream exits the separation vessel through the light gas outlet,
wherein the solids outlet is configured so that the condensed solid exits the separation vessel through the solids outlet,
wherein impingement of the fluidized particles of the bed reduces buildup of condensed solid from the exterior of the conduit.
22. A system as in claim 21 , wherein the process stream contains carbon dioxide and wherein the temperature within the bed is less than about −78° C.
23. A system as in claim 21 , wherein impingement of the fluidized particles of the bed reduces buildup of condensed solid carbon dioxide from the exterior of the conduit.