Cutting element and a method of manufacturing a cutting element
The present disclosure relates in one aspect to a cutting element comprising a substrate and a cutting layer disposed on a surface of the substrate. The cutting layer comprises an ultra hard material. The substrate comprises tungsten carbide and a metal binder. The substrate has a magnetic saturation value in the range of from 80% to less than 85%. In another aspect, the magnetic saturation value may increase within the substrate along a gradient, wherein proximal to the interface with the cutting layer, the substrate has a magnetic saturation value in the range of from 80% to less than 85%. Also included are drill bits incorporating such cutting elements. Additionally, the present disclosure relates to methods of manufacturing cutting elements.
1. A cutting element comprising:
a substrate comprising tungsten carbide and a metal binder which substrate has a magnetic saturation value in the range of from 80% to less than 85%; and
a cutting layer disposed on a surface of the substrate which cutting layer comprises an ultra hard material said cutting element formed by high pressure high temperature (HPHT) sintering.
2. The cutting element of claim 1 , wherein the substrate has a magnetic saturation value in the range of from 80.5% to 84.5%.
3. The cutting element of claim 1 , wherein the substrate has a magnetic saturation value in the range of from 81% to 84%.
4. The cutting element of claim 1 , wherein the substrate has a tungsten carbide grain size distribution such that the span of the grain size distribution curve has a value in the range of from 1 to 2.5, wherein the span of the grain size distribution curve is characterized by the following equation: GSDC=(d 95 −d 5 )/d 50
wherein d 95 is a grain size for which 95% by volume of the grain sizes are smaller, d 50 is a grain size for which 50% by volume of the grain sizes are smaller, and d 5 is a grain size for which 5% by volume of the grain sizes are smaller.
5. The cutting element of claim 1 , wherein the cutting layer comprises thermally stable polycrystalline diamond.
6. The cutting element of claim 1 , wherein the metal binder comprises cobalt.
7. The cutting element of claim 1 , wherein in the ultra hard material comprises polycrystalline diamond.
8. The cutting element of claim 1 , wherein the substrate is substantially free of tungsten carbide grains having a grain size of greater than 6 times the median grain size of the pre-sintered tungsten carbide.
9. The cutting element of claim 1 , wherein the substrate has a magnetic saturation range from 80% to 83.4%.
10. The cutting element of claim 1 , wherein the cutting layer comprises a catalyst material at an amount less than 5 wt % based on the total weight of the cutting layer.
11. The cutting element of claim 1 , wherein a surface of the cutting layer opposite the substrate is leached.
12. The cutting element of claim 1 wherein the ultra hard particles have an average diameter grain size in the range of from 1 nm to 50 nm.
13. A cutting element comprising:
a substrate comprising a tungsten carbide and a metal binder; and
a cutting layer disposed on a surface of the substrate which cutting layer comprises an ultra hard material;
wherein the magnetic saturation value increases within the substrate along a gradient in the direction away from the interface of the substrate and the cutting layer, and wherein within the substrate proximal to the interface, the magnetic saturation value is in the range of from 80% to less than 85%, said cutting element formed by high pressure high temperature (HPHT) sintering.
14. The cutting element of claim 13 , wherein the magnetic saturation value varies such that there is a uniform gradient within the substrate.
15. The cutting element of claim 13 , wherein the substrate has a first region proximal to the interface of the substrate and the cutting layer which first region has a magnetic saturation value in the range of from 80% to less than 85% and a second region proximal to the first region which second region has a magnetic saturation value of at least 85%.
16. The cutting element of claim 13 , wherein the substrate has a magnetic saturation range from 80% to 83.4%.
17. A drill bit comprising:
a bit body; and
a plurality of cutting elements formed by high pressure high temperature (HPHT) sintering affixed to said bit body, wherein at least one of said plurality of cutting elements comprises a substrate containing tungsten carbide and a metal binder which substrate has a magnetic saturation value in the range of from 80% to less than 85%, and a cutting layer disposed on a surface of the substrate which cutting layer comprises an ultra hard material.
18. The drill bit of claim 17 , wherein the substrate has a magnetic saturation value in the range of from 80.5% to 84.5%.
19. The drill bit of claim 17 , wherein the substrate has a magnetic saturation value in the range of from 81% to 84%.
20. The drill bit of claim 17 , wherein the substrate has a tungsten carbide grain size distribution such that the span of the grain size distribution curve has a value in the range of from 1 to 2.5, wherein the span of the grain size distribution curve is characterized by the following equation: GSDC=(d 95 −d 5 )/d 50
wherein d 95 is a grain size for which 95% by volume of the grain sizes are smaller, d 50 is a grain size for which 50% by volume of the grain sizes are smaller, and d 5 is a grain size for which 5% by volume of the grain sizes are smaller.
21. The drill bit of claim 17 , wherein the cutting layer comprises thermally stable polycrystalline diamond.
22. The drill bit of claim 17 , wherein the metal binder comprises cobalt.
23. The drill bit of claim 17 , wherein in the ultra hard material comprises polycrystalline diamond.
24. The drill bit of claim 17 , wherein the substrate is substantially free of tungsten carbide grains having a grain size of greater than 6 times the median grain size of the pre-sintered tungsten carbide.
25. The drill bit of claim 17 , wherein the substrate has a magnetic saturation range from 80% to 83.4%.
26. A cutting element, comprising:
a substrate comprising tungsten carbide and a metal binder which substrate has a magnetic saturation value in the range of from 80% to less than 85% and a tungsten carbide grain size distribution such that the span of the grain size distribution curve has a value in the range of from 1 to 2.5, wherein the span of the grain size distribution curve is characterized by the following equation: GSDC=(d 95 −d 5 )/d 50 and wherein d 95 is a grain size for which 95% by volume of the grain sizes are smaller, d 50 is a grain size for which 50% by volume of the grain sizes are smaller, and d 5 is a grain size for which 5% by volume of the grain sizes are smaller; and
a cutting layer disposed on a surface of the substrate which cutting layer comprises an ultra hard material,
the cutting element formed by high pressure high temperature (HPHT) sintering.
27. The cutting element of claim 26 , wherein the substrate has a magnetic saturation range from 80% to 83.4%.