Method of controlling a polymerization reactor
Embodiments of the invention provide a method of controlling a gas-phase polymerization process. The method includes determining a difference between a control variable of the polymerization process, such as the production rate, and the desired value of the control variable; adjusting or maintaining a first manipulated variable to at least partially compensate for the difference between the control variable and the desired value; and adjusting or maintaining a second manipulated variable to at least partially compensate for the effect of adjusting or maintaining the first manipulated variable. The first and second manipulated variables can include process variables such as the fluidized bed weight, the catalyst concentration, the concentration of one or more monomers, the flow of one or more comonomers, the ratio of one comonomer to another comonomer, the activator concentration, the ratio of an activator to selectivity control agent, the concentration of a chain transfer agent, and the retardant concentration.
1. A method of controlling resin production rate of a polymerization reactor independently of controlling other polymerization conditions in a gas-phase polymerization process, comprising:
(a) continuously, periodically or intermittently determining a difference between an actual or estimated value of the resin production rate and a desired value of the resin production rate;
(b) adjusting or maintaining at least a first manipulated variable to at least partially compensate for the difference between the actual or estimated value of the resin production rate and the desired value; and
(c) adjusting or maintaining a second manipulated variable to at least partially compensate for the effect of adjusting or maintaining the first manipulated variable;
wherein the first and second manipulated variables are selected from the group of process conditions consisting of a catalyst concentration, a weight of fluidized bed, a concentration of one or more monomers, a flow of one or more comonomers, a ratio of a first comonomer to a second comonomer, a first activator concentration, a ratio of a second activator to selectivity control agent, a concentration of a chain transfer agent, and a retardant concentration.
2. The method of claim 1 , further including the proviso that when the first manipulated variable is the catalyst concentration, the second manipulated variable is selected from the group consisting of the weight of fluidized bed, the activator concentration, and the retardant concentration.
3. The method of claim 1 , wherein the first and second manipulated variables are selected from the activator concentration and the fluidized bed weight.
4. The method according to claim 1 , wherein the first and second manipulated variables are selected from the concentration of one or more monomers and the fluidized bed weight.
5. The method according to claim 1 , wherein the first and second manipulated variables are selected from the fluidized bed weight and the retardant concentration.
6. The method according to claim 1 , wherein the bed weight is maintained within about 5% of a target bed weight.
7. The method according to claim 1 , wherein the process forms an alpha-olefin homopolymer or interpolymer.
8. The method according to claim 7 , wherein the alpha-olefin homopolymer or interpolymer comprises a polyethylene homopolymer or an interpolymer of ethylene with at least one comonomer selected from the group consisting of a C 4 -C 20 linear, branched or cyclic diene, vinyl acetate, and a compound represented by the formula H 2 C═CHR wherein R is a C 1 -C 20 linear, branched or cyclic alkyl group or a C 6 -C 20 aryl group.