Herbicide composition comprising herbicide compound in acid form and acidifying agent
Described are herbicide compositions and methods for their preparation and use, in particular, herbicide compositions and methods relating to herbicide compositions containing herbicide compounds in acid form, and further including an acidifying agent.
1. A method of controlling plant growth, the method comprising:
preparing a herbicide composition, by:
providing a herbicide concentrate composition comprising a herbicide compound in its charge neutral acid form; and
combining the herbicide concentrate composition with acidifying agent and water to form a herbicide application composition having a pH below the pKa of the herbicide compound in acid form, wherein the pKa of the herbicide compound is below 6; and
applying the herbicide application composition to a plant to control plant growth by the herbicide compound, wherein the herbicide compound damages and penetrates the plant surface and wherein the herbicide compound is dicamba acid (3,6-dichloro-O-anisic acid).
2. The method of claim 1 comprising:
providing the herbicide concentrate composition,
adding acidifying agent to the herbicide concentrate composition, and
adding water to the herbicide concentrate composition.
3. The method of claim 2 wherein the herbicide concentrate composition is selected from the group consisting of: a microemulsion-forming concentrate, a microemulsion, and a suspension concentrate.
4. The method of claim 1 comprising combining the herbicide concentrate composition with water and acidifying agent in a spray tank to form the herbicide application composition.
5. The method of claim 1 wherein the herbicide concentrate composition is selected from the group consisting of: a microemulsion-forming concentrate, a microemulsion, and a suspension concentrate.
6. The method of claim 1 wherein the pKa of the herbicide compound is below 5.
7. The method of claim 1 wherein the acidifying agent is sulfuric acid.
8. The method of claim 1 wherein the acidifying agent is selected from the group consisting of: hydrochloric acid, nitric acid, acetic acid, phosphoric acid, polyphosphoric acid, perchloric acid, and combinations thereof, and the herbicide composition does not include sulfuric acid.
9. The method of claim 1 wherein the acidifying agent is selected from the group consisting of: sulfuric acid, hydrochloric acid, nitric acid, acetic acid, phosphoric acid, perchloric acid, polyphosphoric acid, and combinations thereof.
10. The method of claim 1 wherein the acidifying agent is selected from the group consisting of: sulfuric acid, hydrochloric acid, nitric acid, acetic acid, phosphoric acid, perchloric acid, and polyphosphoric acid, and the composition does not include a sulfuric acid adduct of the formula:
wherein X is chalcogen, and each of R 1 , R 2 , and R 3 is independently selected from hydrogen and organic radicals.
11. The method of claim 1 wherein the herbicide application composition does not include glyphosate acid.
12. The method of claim 1 wherein the herbicide concentrate composition contains essentially no organic solvent.
13. The method of claim 1 wherein the step of applying, the herbicide application composition is applied to control the growth of bushes, scrub brush, vines, or weeds.