Method of forming a dental appliance
The present disclosure includes dental appliances and methods of making and using such appliances. One method for forming a dental appliance includes forming a liquid thermoset polymer material into a semi-solid first shape, thermoforming the semi-solid first shape of thermoset polymer material onto a dentition mold, and curing the thermoset polymer on the dentition mold with a curative trigger to complete a molecular cross-linking reaction.
1. A method for forming a dental appliance, comprising:
partially curing a thermoset polymer material into a semi-solid formable first shape in a first mold;
removing the semi-solid formable first shape from the first mold;
thermoforming the semi-solid formable first shape of thermoset polymer material onto a dentition mold, wherein the first mold is a different mold than the dentition mold; and
fully curing, by application of heat, the thermoset polymer on the dentition mold to complete a molecular cross-linking reaction to form the dental appliance, wherein the dental appliance is a shell having a number of cavities to receive one or more teeth.
2. The method of claim 1 , wherein curing the thermoset polymer on the dentition mold includes adding a curative trigger to complete the molecular cross-linking reaction.
3. The method of claim 2 , wherein the curative trigger is energy.
4. The method of claim 1 , wherein the dental appliance is formed by a process selected from the group including molding, extrusion, and rolling.
5. The method of claim 1 , wherein the forming is accomplished by a process selected from the group including compression molding, liquid injection molding, or reaction injection molding.
6. The method of claim 1 , wherein the semi-solid formable first shape is substantially horseshoe-shaped in at least one dimension, having proportions at least as large as a top view of the dentition mold.
7. The method of claim 1 , wherein the semi-solid formable first shape is substantially horseshoe-shaped in at least two dimensions.
8. The method of claim 1 , wherein the semi-solid formable first shape has a uniform thickness.
9. The method of claim 1 , wherein the semi-solid formable first shape has a thickness based on jaw size.
10. The method of claim 1 , wherein the semi-solid formable first shape has a thickness based on a crown height.
11. The method of claim 1 , wherein the semi-solid formable first shape has a non-uniform thickness.
12. The method of claim 11 , wherein thickness of the semi-solid formable first shape varies such that the thermoset polymer material has a greater thickness along a gingival line than along an occlusal surface after thermoforming onto the dentition mold.
13. The method of claim 11 , wherein thickness of the semi-solid formable first shape varies such that the thermoset polymer material has a substantially uniform thickness after thermoforming onto the dentition mold.
14. The method of claim 11 , further comprising partially curing the thermoset polymer material in the semi-solid formable first shape prior to thermoforming.
15. A method for forming a dental appliance, comprising:
delivering a fluid thermoset polymer precursor to a first mold;
partially curing the thermoset polymer precursor in the first mold into a semi-solid formable first shape;
removing the partially cured semi-solid formable first shape from the first mold;
thermoforming the partially cured semi-solid formable first shape of thermoset polymer precursor onto a dentition mold; and
curing, by application of heat, the thermoset polymer precursor on the dentition mold to induce a cross-linking reaction to form the dental appliance, wherein the dental appliance is a shell having a number of cavities to receive one or more teeth.
16. The method of claim 15 , wherein curing the thermoset polymer precursor on the dentition mold includes adding a curative trigger to induce the cross-linking reaction.
17. The method of claim 16 , wherein the curative trigger is energy.
18. The method of claim 17 , wherein the energy to induce the cross-linking reaction is selected from the group including light, radiation, and heat.
19. The method of claim 15 , wherein the first mold is configured to form the semi-solid formable first shape includes forming the partially cured thermoset polymer precursor into a flat sheet.
20. A method for forming a dental positioning appliance, comprising:
delivering a fluid thermoset polymer precursor to a first mold having an internal cavity, the internal cavity having a surface corresponding to an external surface of the dental positioning appliance;
partially curing the fluid thermoset polymer precursor in the first mold into a semi-solid formable first shape;
placing a second mold in proximity to the first mold such that a volume for the fluid thermoset polymer precursor remains there between, the second mold being a positive dentition mold having an external surface corresponding to an internal surface of the dental positioning appliance; and
curing the fluid thermoset polymer precursor to cause molecules of the fluid thermoset polymer precursor to irreversibly cross-link into a rigid three dimensional structure to form the dental positioning appliance, wherein the dental positioning appliance is a shell having a number of cavities to receive one or more teeth.
21. The method of claim 20 , wherein curing the thermoset polymer precursor includes adding a curative trigger to cause molecules of the fluid thermoset polymer precursor to irreversibly cross-link into a rigid three dimensional structure.
22. The method of claim 21 , wherein the curative trigger is energy.
23. The method of claim 20 , where the fluid thermoset polymer precursor includes two or more prepolymer components and at least one curative to initiate a chemical reaction involving the two or more components.
24. The method of claim 23 , where the fluid thermoset polymer precursor includes at least one or more isocyanates, one or more polyols, and a curative.