Organic electroluminescence device and material for organic electroluminescence device
An organic electroluminescence device includes: a cathode; an anode; and a single-layered or multilayered organic thin-film layer provided between the cathode and the anode. The organic thin-film layer includes at least one emitting layer. The at least one emitting layer contains at least one phosphorescent material and a host material represented by the following formula (1). Ra—Ar 1 —Rb (1) In the formula, Ar 1 , Ra and Rb each represent a substituted or unsubstituted benzene ring or a condensed aromatic hydrocarbon ring selected from a substituted or unsubstituted naphthalene ring, a substituted or unsubstituted chrysene ring, a substituted or unsubstituted fluoranthene ring, a substituted or unsubstituted phenanthrene ring, a substituted or unsubstituted benzophenanthrene ring, a substituted or unsubstituted dibenzophenanthrene ring, a substituted or unsubstituted triphenylene ring, a substituted or unsubstituted benzo[a]triphenylene ring, a substituted or unsubstituted benzochrysene ring, a substituted or unsubstituted benzo[b]fluoranthene ring and a substituted or unsubstituted picene ring. Substituents for Ra and Rb are not aryl groups.
1. An organic electroluminescence device, comprising:
a cathode;
an anode; and
a single-layered or multilayered organic thin-film layer provided between the cathode and the anode, wherein
the organic thin-film layer comprises at least one emitting layer, and
the at least one emitting layer comprises: at least one phosphorescent material; and a host material having excited triplet energy of of 2.0 eV to 2.8 eV, the host material represented by a formula (1) as follows,
Ra—Ar 1 —Rb (1)
where:
Ar 1 represents a condensed aromatic hydrocarbon ring selected from a substituted or unsubstituted benzochrysene ring, and a substituted or unsubstituted picene ring;
Ra and Rb each represent a substituted or unsubstituted benzene ring or a condensed aromatic hydrocarbon ring selected from a substituted or unsubstituted naphthalene ring, a substituted or unsubstituted chrysene ring, a substituted or unsubstituted fluoranthene ring, a substituted or unsubstituted phenanthrene ring, a substituted or unsubstituted benzophenanthrene ring, a substituted or unsubstituted dibenzophenanthrene ring, a substituted or unsubstituted benzochrysene ring, and a substituted or unsubstituted picene ring, wherein the substituents for Ra and Rb are not aryl groups,
wherein when Ra, Rb, or both are substituted with a substituent, the substituent is one or more of an alkyl group comprising 1 to 20 carbon atoms, a haloalkyl group comprising 1 to 20 carbon atoms, a cycloalkyl group comprising 5 to 18 carbon atoms, a silyl group comprising 3 to 20 carbon atoms, a cyano group, and a halogen atom,
wherein when Ar 1 is substituted with a substituent, the substituent is one or more of an aryl group comprising 6 to 22 carbon atoms, an alkyl group comprising 1 to 20 carbon atoms, a haloalkyl group comprising 1 to 20 carbon atoms, a cycloalkyl group comprising 5 to 18 carbon atoms, a silyl group comprising 3 to 20 carbon atoms, a cyano group, and a halogen atom.
2. The organic electroluminescence device according to claim 1 , wherein
the phosphorescent material comprises a metal complex, and
the metal complex comprises: a metal atom selected from Ir, Pt, Os, Au, Cu, Re and Ru; and a ligand.
3. The organic electroluminescence device according to claim 2 , wherein the ligand has an ortho-metal bond.
4. The organic electroluminescence device according to claim 1 , wherein a maximum wavelength of light emission of the at least one phosphorescent material contained in the emitting layer is in a range of 500 nm to 720 nm.
5. The organic electroluminescence device according to claim 1 , wherein
the organic thin-film layer comprises an electron transporting layer or an electron injecting layer between the cathode and the emitting layer, and
the electron transporting layer or the electron injecting layer comprises an aromatic ring having a nitrogen-containing six-membered or five-membered ring skeleton, or a condensed aromatic cyclic compound having a nitrogen-containing six-membered or five-membered ring skeleton.
6. The organic electroluminescence device according to claim 1 , wherein a reductive dopant is present at an interfacial region between the cathode and the organic thin-film layer.
7. The organic electroluminescence device according to claim 1 , wherein Ra, Rb, or both represent a substituted or unsubstituted naphthalene ring.
8. The organic electroluminescence device according to claim 1 , wherein Ra, Rb, or both represent a substituted or unsubstituted chrysene ring.
9. The organic electroluminescence device according to claim 1 , wherein Ra, Rb, or both represent a substituted or unsubstituted fluoranthene ring.
10. The organic electroluminescence device according to claim 1 , wherein Ra, Rb, or both represent a substituted or unsubstituted phenanthrene ring.
11. The organic electroluminescence device according to claim 1 , wherein Ra, Rb, or both each represent a substituted or unsubstituted benzophenanthrene ring.
12. The organic electroluminescence device according to claim 1 , wherein Ra, Rb, or both each represent a substituted or unsubstituted dibenzophenanthrene ring.
13. The organic electroluminescence device according to claim 1 , wherein Ra, Rb, or both represent a substituted or unsubstituted benzochrysene ring.
14. The organic electroluminescence device according to claim 1 , wherein Ra, Rb, or both represent a substituted or unsubstituted picene ring.
15. An organic electroluminescence device, comprising:
a cathode;
an anode; and
a single-layered or multilayered organic thin-film laver provided between the cathode and the anode, wherein
the organic thin-film layer comprises at least one emitting layer, and
the at least one emitting layer comprises: at least one phosphorescent material; and a host material having excited triplet energy of of 2.0 eV to 2.8 eV, the host material represented by a formula (1) as follows,
Ra—Ar 1 —Rb (1)
where:
Ar 1 represents a condensed aromatic hydrocarbon ring selected from a substituted or unsubstituted naphthalene ring, a substituted or unsubstituted dibenzophenanthrene ring, a substituted or unsubstituted benzochrysene ring, and a substituted or unsubstituted picene ring;
wherein Ra, Rb, or both represent a substituted or unsubstituted chrysene ring, a substituted or unsubstituted fluoranthene ring, a substituted or unsubstituted phenanthrene ring, a substituted or unsubstituted benzophenanthrene ring, a substituted or unsubstituted dibenzophenanthrene ring, a substituted or unsubstituted benzochrysene ring, and a substituted or unsubstituted picene ring, wherein the substituents for Ra and Rb are not aryl groups,
wherein when Ra, Rb, or both are substituted with a substituent, the substituent is one or more of an alkyl group comprising 1 to 20 carbon atoms, a haloalkyl group comprising 1 to 20 carbon atoms, a cycloalkyl group comprising 5 to 18 carbon atoms, a silyl group comprising 3 to 20 carbon atoms, a cyano group, and a halogen atom,
wherein when Ar 1 is substituted with a substituent, the substituent is one or more of an aryl group comprising 6 to 22 carbon atoms, an alkyl group comprising 1 to 20 carbon atoms, a haloalkyl group comprising 1 to 20 carbon atoms, a cycloalkyl group comprising 5 to 18 carbon atoms, a silyl group comprising 3 to 20 carbon atoms, a cyano group, and a halogen atom.
16. The organic electroluminescence device according to claim 15 , wherein Ar 1 is a substituted or unsubstituted naphthalene ring.
17. The organic electroluminescence device according to claim 15 , wherein Ar 1 is a substituted or unsubstituted benzochrysene ring.
18. The organic electroluminescence device according to claim 15 , wherein Ar 1 is a substituted or unsubstituted picene ring.