IP Library Granted Patent US 8,785,049
Granted Patent B2
US 8,785,049 · App. 13/053,160 · Granted Jul 22, 2014

Negative active material for rechargeable lithium battery and rechargeable lithium battery including same

Inventors: Bong-Chull Kim (Yongin-si, KR); Cheol-Hee Hwang (Yongin-si, KR); Dong-Yung Kim (Yongin-si, KR); Se-Ho Park (Yongin-si, KR); Hyun-Jun Choi (Yongin-si, KR); In-Ho Jung (Yongin-si, KR); Su-Ho Song (Yongin-si, KR)
Assignee: Samsung SDI Co., Ltd.
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Quick Facts
Patent No.
US 8,785,049
App. No.
13/053,160
Granted
Jul 22, 2014
Kind
B2
Abstract

A negative active material for a rechargeable lithium battery includes a core including crystalline carbon, a metal nano particle and a MO x nano particle (where x is from 0.5 to 1.5, and M is Si, Sn, In, Al, or a combination thereof) disposed on the core surface, and a coating layer including an amorphous carbon surrounding the core surface, the metal nano particle and the MO x nano particle. A lithium rechargeable battery includes the negative active material.

Claims (21)

1. A negative active material for a rechargeable lithium battery, comprising:

a core comprising crystalline carbon;

at least one metal particle and at least one MO x particle disposed on a surface of the core, wherein x is from about 0.5 to about 1.5, the metal particle comprises a metal selected from the group consisting of Si, Sn, In, Al, and combinations thereof, the metal particle has a FWHM of an X-ray diffraction angle (2θ) at a (111) plane of about 0.3 degrees (°) to about 0.9 degrees (°) as measured using a CuKα ray, and M is Si, Sn, In, Al, or a combination thereof; and

a coating layer surrounding at least a portion of the core, the metal particle and the MO x particle, the coating layer comprising an amorphous carbon.

2. The negative active material for a rechargeable lithium battery of claim 1 , wherein the metal particle and the MO x particle are mixed in a weight ratio of about 9:1 to about 2:8.

3. The negative active material for a rechargeable lithium battery of claim 1 , wherein the metal particle has an average particle diameter of about 50 nm to about 800 nm.

4. The negative active material for a rechargeable lithium battery of claim 1 , wherein the MO x particle has an average particle diameter of about 50 nm to about 800 nm.

5. The negative active material for a rechargeable lithium battery of claim 1 , wherein the metal particle has a FWHM of a X-ray diffraction angle (2θ) at a (220) plane of about 0.35 degrees (°) to about 0.95 degrees (°) as measured using a CuKα ray.

6. The negative active material for a rechargeable lithium battery of claim 1 , wherein the core has at least one pore.

7. The negative active material for a rechargeable lithium battery of claim 6 , wherein the metal particle, or the MO x particle, or a mixture of the metal particle and the MO x particle is present in the pore.

8. The negative active material for a rechargeable lithium battery of claim 1 , wherein the metal particle and the MO x particle are included in a combined amount of about 3 wt % to about 30 wt % based on the entire weight of the negative active material.

9. The negative active material for a rechargeable lithium battery of claim 1 , wherein the core is included in an amount of about 60 wt % to about 95 wt % based on the entire weight of the negative active material.

10. The negative active material for a rechargeable lithium battery of claim 1 , wherein the crystalline carbon comprises a material selected from the group consisting of natural graphite, artificial graphite, and mixtures thereof.

11. The negative active material for a rechargeable lithium battery of claim 1 , wherein the coating layer is included in an amount of about 2 wt % to about 20 wt % based on the entire weight of the negative active material.

12. The negative active material for a rechargeable lithium battery of claim 1 , wherein the amorphous carbon comprises a material selected from the group consisting of soft carbon, hard carbon, mesophase pitch carbonized products, fired cokes, and mixtures thereof.

13. A rechargeable lithium battery comprising:

a negative electrode comprising a first negative active material comprising the negative active material of claim 1 ;

a positive electrode comprising a positive active material; and

a non-aqueous electrolyte.

14. The rechargeable lithium battery of claim 13 , wherein the negative electrode further comprises a second negative active material comprising a carbon-based negative active material.

15. The rechargeable lithium battery of claim 14 , wherein the first negative active material and the second negative active material are mixed in a ratio of about 5:95 wt % to about 95:5 wt %.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 12, 2011
From: KIM, BONG-CHULL; HWANG, CHEOL-HEE; KIM, DONG-YUNG; PARK, SE-HO; CHOI, HYUN-JUN; JUNG, IN-HO; SONG, SU-HO
To: SAMSUNG SDI CO., LTD.
Reel/Frame 026112/0318 →
Priority Claims (1)
KR 10-2010-0109158 · Nov 4, 2010 · national
Continuity (1)
Related Publication 20120115033A1 · May 10, 2012