Process for preparation of catalyst carrier and its use in catalyst preparation
View Patent ↗This invention relates to catalyst carriers to be used as supports for metal and metal oxide catalyst components of use in a variety of chemical reactions. More specifically, the invention provides a process of formulating an alpha alumina carrier that is suitable as a support for silver and the use of such catalyst in chemical reactions, especially the epoxidation of ethylene to ethylene oxide. The composition comprises at least one hydrated precursor of alpha alumina; an optional alpha alumina; and a binder. The composition is substantially free of seeding particles.
1. A composition for producing an alpha alumina catalyst support, the composition comprising at least one alpha alumina having a median particle size of at least 5 microns, in an amount of about 20 percent to about 60 percent by weight of total alumina in the composition; at least one hydrated precursor of alpha alumina in an amount of about 40 percent to about 80 percent by weight of total alumina in the composition; and a binder, wherein the composition is substantially free of seeding particles.
2. The composition of claim 1 , wherein the composition is free of seeding particles.
3. The composition of claim 1 , wherein the at least one hydrated precursor of alpha alumina comprises an aluminum hydroxide.
4. The composition of claim 3 , wherein the aluminum hydroxide is selected from the group consisting of gibbsite, boehmite, diaspore, bayerite, and combinations thereof.
5. The composition of claim 1 , wherein the composition is substantially free of ferric oxide, chromium oxide, and sub-micron size particles of alpha alumina.
6. The composition of claim 1 , further comprising water in an amount sufficient to render the composition extrudable.
7. The composition of claim 1 , wherein the binder comprises a material selected from the group consisting of thermally decomposable organic compounds, clays, silica, silicates of elements of Group II of the Periodic Table of the elements, and combinations thereof.
8. The composition of claim 1 , wherein the binder comprises a material selected from the group consisting of polyolefin oxides, oil, acacia, carbonaceous materials, cellulose, substituted celluloses, cellulose ether, stearates, waxes, granulated polyolefins, polystyrene, polycarbonate, sawdust, ground nut shell flour, silica, an alkali metal salt, and combinations thereof.
9. The composition of claim 1 , wherein the composition further comprises talc.
10. The composition of claim 1 , wherein the composition further comprises a water-soluble titanium compound.
11. The composition of claim 1 , wherein the composition further comprises a burnout material.
12. The composition of claim 1 , wherein the composition further comprises a blowing agent.
13. The composition of claim 12 , wherein the blowing agent propels a gas upon the application of sufficient heat.
14. The composition of claim 1 , wherein the composition further comprises boron.
15. A process for producing an alpha alumina catalyst support, the process comprising:
a) preparing a composition comprising at least one alpha alumina having a median particle size of at least 5 microns, in an amount of about 20 percent to about 60 percent by weight of total alumina in the composition; at least one hydrated precursor of alpha alumina in an amount of about 40 percent to about 80 percent by weight of total alumina in the composition; and a binder, wherein the composition is substantially free of seeding particles;
b) molding the composition into a structure;
c) heating said structure for a sufficient time and at a sufficient temperature to form a porous structure; and
d) calcining the porous structure at a temperature above 1000° C. for a sufficient time to convert the at least one hydrated precursor of alpha alumina to a porous and fused alpha alumina structure.
16. The process of claim 15 , wherein step c), step d), or both step c) and step d), are conducted in an atmosphere of an inert gas.
17. A process for producing a catalyst, the process comprising producing an alpha alumina catalyst support according to claim 15 , and then e) depositing a catalytically effective amount of silver onto a surface of said catalyst support.
18. The process of claim 17 , further comprising depositing a promoting amount of a promoter onto the surface of the catalyst support, the promoter comprising one or more alkali metal-containing compounds, one or more transition metal-containing compounds, one or more sulfur components, one or more fluorine-containing components, or a combination thereof.
19. A process for the oxidation of ethylene to ethylene oxide, the process comprising vapor phase oxidation of ethylene with molecular oxygen in a fixed bed tubular reactor in the presence of the catalyst produced by the process of claim 17 .
20. The catalyst produced by the process of claim 18 .
21. The composition of claim 1 , wherein said at least one hydrated precursor of alpha alumina is in an amount of about 75 percent to about 80 percent by weight of total alumina in the composition.