Method for the rapid pyrolysis of lignocellulose
Method for fast pyrolysis of lignocellulose including: mechanically comminuting the lignocellulose to lignocellulose particles; at least one of completely drying and preheating the lignocellulose particles; mixing the lignocellulose particles with heat transfer particles so as to provide a mixture; heating the heat transfer particles, prior to the mixing, to a temperature between 500° C. and 650° C.; and heating, in a pyrolysis reactor with oxygen excluded, the lignocellulose particles using the heat transfer particles so as to establish a temperature between 400° C. and 600° C. for 1 to 50 seconds and so as to react the lignocellulose particles so as to provide pyrolysis coke, pyrolysis condensate, and pyrolysis gas.
1. A method for fast pyrolysis of lignocellulose, comprising;
a) mechanically comminuting the lignocellulose to lignocellulose particles while preheating the lignocellulose particles to a range of 170 to 200° C. under a low oxygen environment;
b) mixing the lignocellulose particles with heat transfer particles after the mechanical comminuting and preheating so as to provide a mixture, the heat transfer particles including grains of at least one of metal, ceramic and hard material, the grains having a diameter greater than 3 mm;
c) introducing the heat transfer particles, at a temperature in a range of 400° C. to 500° C. to a heat exchanger and heating the heat transfer particles, prior to the mixing, to a temperature between 500° C. and 650° C.; and
d) heating, in a pyrolysis reactor with oxygen excluded, the lignocellulose particles using the heat transfer particles so as to establish a temperature between 400° C. and 600° C. for 1 to 50 seconds and so as to react the lignocellulose particles so as to provide pyrolysis coke, pyrolysis condensate, and pyrolysis gas.
2. The method according to claim 1 , further comprising separating the heat transfer particles and pyrolysis coke by a sieving process.
3. The method according to claim 1 , wherein the method is a continuous method and the heating of the heat transfer particles is carried out in the material circuit outside of, and separated on a gas side from, the pyrolysis reactor,
further comprising distributing the lignocellulose once as a continuous material stream and distributing the heat transfer particles repeatedly as a recycling material circuit.
4. The method according to claim 3 , wherein the heating of the heat transfer particles includes contacting the heat transfer particles with a hot combustion gas of a combustion process.
5. The method according to claim 4 , wherein the combustion process includes combusting at least one of pyrolysis gas and pyrolysis coke with preheated air.
6. The method according to claim 1 , further comprising combusting at least one of the pyrolysis gas, a portion of the pyrolysis coke and a lower quality portion of the pyrolysis coke in a combustion process so as to provide low-oxygen exhaust gas, and wherein the preheating is performed using the low-oxygen exhaust gas.
7. The method according to claim 1 , wherein the heat transfer particles are spheres that include at least one of Inconel, Incoloy and another HCl-resistant alloy.
8. The method according to claim 1 , wherein the heat transfer particles are coated with a wear protection layer or with a wear protection layer composite, including at least one layer of a hard material or a hard metal.
9. The method according to claim 1 , further comprising performing the mixing in free fall and before a receiving of the mixture into the pyrolysis reactor.
10. The method according to claim 1 , wherein the mechanically comminuting the lignocellulose while preheating the lignocellulose particles is performed so as to remove at least 99% of the free water component of the lignocellulose.
11. The method according to claim 1 , wherein the heat transfer particles comprise an HCl-resistant alloy.
12. The method according to claim 1 , wherein the heat transfer particles comprise Inconel.
13. The method according to claim 1 , wherein the heat transfer particles comprise Incoloy.
14. The method according to claim 1 , wherein the heat transfer particles are coated with a wear protection layer comprising a harder material than underlying components of the heat transfer particle.
15. The method according to claim 1 , wherein the heat transfer particles comprise a ceramic.
16. The method according to claim 1 , wherein the heat transfer particles comprise SiC.
17. The method according to claim 1 , wherein the heat transfer particles comprise Al 2 O 3 .
18. The method according to claim 1 , wherein the heat transfer particles comprise quartz.
19. The method according to claim 1 , wherein the heat transfer particles comprise graphite.
20. The method according to claim 1 , wherein a dwell time in d) at between 400° C. and 600° C. is 3 to 30 seconds.