Binder for ink-jet printing ink, ink-jet printing ink containing the same, and printed matter
It is an object of the present invention to provide a binder for ink-jet printing ink that can form printed images having excellent scratch resistance and good alcohol resistance without impairing good discharge stability of ink. The present invention relates to a binder for ink-jet printing ink including a polyurethane (A) that has a hydroxyl group at a molecular terminal, has a weight-average molecular weight of 30,000 to 70,000, and is obtained by causing a reaction of a polyisocyanate and a polyol (a2) containing a particular polyether polyol so that the equivalent ratio [isocyanate group [X]/hydroxyl group [Y]] of an isocyanate group [X] in the polyisocyanate (a1) to a hydroxyl group [Y] in the polyol (a2) is in the range of 0.930 to 0.995 and an aqueous medium (B). The hydroxyl group present at the molecular terminal of the polyurethane (A) is a hydroxyl group derived from the polyether polyol.
1. A binder for ink-jet printing ink, comprising:
a polyurethane (A) that has a hydroxyl group at a molecular terminal, has a weight-average molecular weight of 30,000 to 70,000, and is obtained by preparing a urethane prepolymer having an isocyanate group at a molecular terminal through a reaction of a polyisocyanate (a1) and part of a polyol (a2) and then causing a reaction of the urethane prepolymer and the polyether polyol (a2-1); and
an aqueous medium (B),
wherein:
the hydroxyl group present at the molecular terminal of the polyurethane (A) is a hydroxyl group derived from the polyether polyol (a2-1);
the equivalent ratio of an isocyanate group [X] in the polyisocyanate (a1) to a hydroxyl group [Y] in the polyol (a2), isocyanate group [X]/hydroxyl group [Y], is in the range of 0.930 to 0.995; and
the polyol (a2) contains the polyether polyol (a2-1), which is represented by general formula [I]:
where R represents an alkylene group having 3 to 8 carbon atoms, and n is an average number of addition moles of a structural unit RO, n being in the range of 8 to 55.
2. The binder for ink jet printing ink according to claim 1 , wherein the polyurethane (A) has a hydrophilic group, and the hydrophilic group is an anionic group formed by neutralization with potassium hydroxide.
3. A method for producing the binder of claim 1 for ink jet printing ink, the binder containing a polyurethane (A) having, at a molecular terminal, a hydroxyl group derived from a polyether polyol (a2-1) represented by general formula and [I] an aqueous medium (B),
the method comprising producing the polyurethane (A) by preparing a urethane prepolymer having an isocyanate group at a molecular terminal through a reaction of a polyisocyanate (a1) and part of a polyol (a2) and then causing a reaction of the urethane prepolymer and the polyether polyol (a2-1) represented by general formula [I],
wherein the equivalent ratio of an isocyanate group [X] in the polyisocyanate (a1) to a hydroxyl group [Y] in the polyol (a2), isocyanate group [X]/hydroxyl group [Y], is in the range of 0.930 to 0.995, and the polyether polyol (a2-1) of general formula is:
where R represents an alkylene group having 3 to 8 carbon atoms, and n is an average number of addition moles of a structural unit RO, n being in the range of 8 to 55.
4. An ink-jet printing ink comprising the binder for ink-jet printing ink according to claims 1 and a pigment or dye.
5. Printed matter formed by performing printing with the ink-jet printing ink according to claim 4 .
6. An ink-jet printing ink comprising the binder for ink-jet printing ink according to claim 2 and a pigment or dye.
7. Printed matter formed by performing printing with the ink jet printing ink according to claim 6 .