Metal separator plate for a fuel cell having a coating layer comprising carbon particles dispersed in a binder resin, and a production method therefor
Disclosed herein is a method of manufacturing a metallic bipolar plate for fuel cells, which can maintain good corrosion resistance and contact resistance without any side effect not only initially but also after a predetermined period of time even in an environment of severe vibration as in vehicles while allowing a continuous process to provide high productivity. The method includes (a) preparing a metal plate as a matrix of the metallic bipolar plate; (b) pickling a surface of the metal plate; (c) coating a composition comprising a binder resin, carbon particles, and a solvent on the pickled surface of the metal plate; and (d) drying the surface of the metal plate, on which the composition is coated, at a temperature less than a thermal decomposition temperature of the binder resin and greater than or equal to a boiling point of the solvent to form a coating layer on the surface of the metal plate, the coating layer having the carbon particles dispersed in a matrix of the binder resin, wherein these processes are performed as a continuous process.
1. A method of manufacturing a metallic bipolar plate for fuel cells, comprising:
(a) preparing a metal plate as a matrix of the metallic bipolar plate;
(b) degreasing and pickling a surface of the metal plate for pretreatment;
(c) coating a composition on the pickled surface of the metal plate, the composition comprising a binder resin, carbon particles and a solvent, and a mixing ratio of the carbon particles and the binder resin being 1:1˜6:1 in terms of weight; and
(d) drying the surface of the metal plate, on which the composition is coated, at a temperature less than a thermal decomposition temperature of the binder resin and greater than or equal to a boiling point of the solvent to form a coating layer on the surface of the metal plate, the coating layer having the carbon particles dispersed in a matrix of the binder resin.
2. The method according to claim 1 , wherein the metal plate is selected from a stainless steel plate, an aluminum plate, and a carbon steel plate.
3. The method according to claim 1 , wherein the composition used in step (c) comprises 10˜60 wt % of the carbon particles, 5˜10 wt % of the binder resin, and the balance of the solvent.
4. The method according to claim 1 , wherein the binder resin is at least one selected from acrylic resins, phenolic resins, urethane resins, melanin resins, fluorine reins, silicone resins, and epoxy resins.
5. The method according to claim 1 , wherein the carbon particles comprise one selected from carbon black, graphite, and carbon nano-tube (CNT).
6. The method according to claim 5 , wherein the carbon black has a particle size of 1 μm or less and the graphite has a particle size of 3 μm or less.
7. The method according to claim 1 , wherein the carbon particles comprise a mixture of the carbon black and the graphite in a ratio of 1:1˜1:3 to increase a filling rate of the carbon particles in the coating layer, the carbon black having an average particle size of 0.03˜0.1 μm and the graphite having an average particle size of 0.5˜1.0 μm.
8. The method according to claim 1 , wherein the binder resin and the carbon particles are contained in an amount of 55 wt % or less in the composition.
9. The method according to claim 1 , wherein the solvent comprises an organic solvent selected from hexanes, ketones, alcohols and acetates to be used alone or in a combination thereof, or comprises water (H 2 O).
10. The method according to claim 1 , wherein the drying in step (d) is performed at a temperature of 160˜340 ° C.
11. The method according to claim 1 , further comprising: pre-heating the metal plate having the composition coating layer on the surface thereof at a temperature less than the boiling point of the solvent between step (c) and step (d).
12. The method according to claim 11 , wherein the preheating is performed at 50˜150 ° C. for 5˜30 minutes.
13. The method according to claim 1 , wherein the coating layer has a thickness of 0.1˜10 μm.
14. The method according to claim 1 , wherein the drying in step (d) is performed for 13 seconds ˜ 30 minutes.
15. The method according to claim 1 , wherein the manufactured bipolar plate for fuel cells has a corrosion current of 1 μA/cm 2 or less and a contact resistance of 20 mΩ·cm 2 or less.
16. A metallic bipolar plate for fuel cells, comprising: a metal plate having a pickled surface;
and a coating layer formed on the pickled surface of the metal plate, wherein the coating layer has carbon particles dispersed throughout a volume of a matrix composed of a binder resin, wherein a mixing ratio of the carbon particles and the binder resin ranges from 1:1-6:1, and the bipolar plate having a corrosion current of 1 μA/cm 2 or less and a contact resistance of 20 mΩ·cm 2 or less.
17. The metallic bipolar plate according to claim 16 , wherein the metal plate is selected from a stainless steel plate, an aluminum plate, and a carbon steel plate.
18. The metallic bipolar plate according to claim 16 , wherein the binder resin is at least one selected from acrylic resins, phenolic resins, urethane resins, melanin resins, fluorine reins, silicone resins, and epoxy resins.
19. The metallic bipolar plate according to claim 16 , wherein the carbon particles comprise one selected from carbon black, graphite, and carbon nano-tube (CNT).
20. The metallic bipolar plate according to claim 16 , wherein the carbon black has a particle size of 1 μm or less and the graphite has a particle size of 3 μm or less.
21. The metallic bipolar plate according to claim 16 , wherein the carbon particles comprise a mixture of the carbon black and the graphite in a ratio of 1:1˜1:3, the carbon black having an average particle size of 0.03˜0.1 μm and the graphite having an average particle size of 0.5˜1.0 μm.
22. The metallic bipolar plate according to claim 16 , wherein the coating layer has a thickness of 0.1˜10 μm.
23. The method according to claim 3 , wherein the binder resin is at least one selected from acrylic resins, phenolic resins, urethane resins, melanin resins, fluorine reins, silicone resins, and epoxy resins.
24. The method according to claim 3 , wherein the carbon particles comprise one selected from carbon black, graphite, and carbon nano-tube (CNT).
25. The method according to claim 3 , wherein the carbon particles comprise a mixture of the carbon black and the graphite in a ratio of 1:1˜1:3 to increase a filling rate of the carbon particles in the coating layer, the carbon black having an average particle size of 0.03˜0.1 μm and the graphite having an average particle size of 0.5˜1.0 μm.
26. The method according to claim 3 , wherein the binder resin and the carbon particles are contained in an amount of 55 wt % or less in the composition.
27. The method according to claim 3 , wherein the solvent comprises an organic solvent selected from hexanes, ketones, alcohols and acetates to be used alone or in a combination thereof, or comprises water (H 2 O).