Light-emitting element
A light-emitting element having extremely high efficiency of approximately 25% is provided. The light-emitting element includes a light-emitting layer which contains a phosphorescent guest, an n-type host, and a p-type host, where the light-emitting layer is interposed between an n-type layer including the n-type host and a p-type layer including the p-type host, and where the n-type host and the p-type host are able to form an exciplex in the light-emitting layer. The light-emitting element exhibits an extremely high emission efficiency (power efficiency of 74.3 lm/W, external quantum efficiency of 24.5%, energy efficiency of 19.3%) at a low driving voltage (2.6 V) at which luminance of 1200 cd/m 2 is attainable.
1. A light-emitting element comprising:
a first electrode;
a hole-injection layer over the first electrode;
a first layer over the hole-injection layer, the first layer containing a first organic compound which has a hole-transport property;
a light-emitting layer over the first layer, the light-emitting layer containing a phosphorescent compound, the first organic compound, and a second organic compound which has an electron-transport property;
a second layer over the light-emitting layer, the second layer containing the second organic compound;
an electron-injection layer over the second layer; and
a second electrode over the electron-injection layer,
wherein the first organic compound and the second organic compound are selected so that an exciplex is formed therebetween, and
wherein the phosphorescent compound is an organometallic complex whose absorption originating from a triplet metal-to-ligand charge transfer transition overlaps with an emission of the exciplex.
2. The light-emitting element according to claim 1 , wherein the phosphorescent compound contains iridium.
3. The light-emitting element according to claim 1 , wherein the first organic compound is an aromatic amine or a carbazole derivative.
4. The light-emitting element according to claim 1 , wherein the second organic compound has a π-electron deficient heteroaromatic ring.
5. The light-emitting element according to claim 4 , wherein the π-electron deficient heteroaromatic ring is a 6-membered ring having, as a constituting element of the ring, an element whose electronegativity is greater than that of carbon.
6. The light-emitting element according to claim 4 , wherein the π-electron deficient heteroaromatic ring is benzoquinoxaline.
7. The light-emitting element according to claim 1 , further comprising an electron-transport layer between the second electrode and the second layer.
8. The light-emitting element according to claim 1 ,
wherein the first layer further contains the second organic compound, and
wherein, in the first layer, a concentration of the second organic compound changes in a direction from the first electrode to the light-emitting layer.
9. The light-emitting element according to claim 1 ,
wherein the second layer further contains the first organic compound, and
wherein, in the second layer, a concentration of the first organic compound changes in a direction from the second electrode to the light-emitting layer.
10. The light-emitting element according to claim 1 , wherein, in the light-emitting layer, a concentration of the first organic compound and a concentration of the second organic compound change in a direction from the first layer to the second layer.
11. An electronic device comprising the light-emitting element according to claim 1 .
12. A lighting device comprising the light-emitting element according to claim 1 .