Methods and compositions for altering the viscosity of treatment fluids used in subterranean operations
Methods of decreasing the viscosity of a treatment fluid through contact with a cyclodextrin modifier. Such methods include providing a cyclodextrin modifier; providing a treatment fluid that comprises a base fluid and a viscosifying agent wherein the viscosifying agent is selected from the group consisting of a hydrophobically modified polymer, a viscoelastic surfactant, a phosphonate surfactant, or a combination thereof; and, introducing the cyclodextrin modifier and the treatment fluid into a well bore penetrating a subterranean formation wherein the viscosity of the treatment fluid is decreased due to the combination of the hydrophobically modified polymer and the cyclodextrin modifier.
1. A method comprising:
providing a cyclodextrin modifier comprising hydroxypropyl-β-cyclodextrin;
providing a treatment fluid that comprises a base fluid and a viscosifying agent;
wherein the viscosifying agent comprises a hydrophobically modified polymer and the viscosifying agent optionally further comprises, a viscoelastic surfactant, a phosphonate surfactant, or a combination thereof; and,
wherein the hydrophobically modified polymer comprises hydroxyethyl cellulose
introducing the cyclodextrin modifier and the treatment fluid into a well bore penetrating a subterranean formation wherein the viscosity of the treatment fluid is decreased due to the combination of the hydrophobically modified polymer and the cyclodextrin modifier, wherein the cyclodextrin modifier is present in an amount of about 1% to about 20% by weight of the treatment fluid; and wherein the viscosifying agent is present in amount of about 0.1% to about 10% by weight of the treatment fluid.
2. The method of claim 1 wherein the cyclodextrin modifier further comprises a methyl cyclodextrin, a hydroxyethyl cyclodextrin, a 2-hydroxyethyl cyclodextrin, a carboxymethyl cyclodextrin, a carboxyethyl cyclodextrin, a glucosyl cyclodextrin, a maltosyl cyclodextrin or a combination thereof.
3. The method of claim 2 wherein the cyclodextrin modifier, in addition to hydroxypropyl-β-cyclodextrin, is selected from the group consisting of glucosyl-α-cyclodextrin, maltosyl-α-cyclodextrin, glucosyl-β-cyclodextrin, maltosyl-α-cyclodextrins, methyl-α-cyclodextrin, 2 hydroxypropyl-β-cyclodextrin, hydroxyethyl-α-cyclodextrin, and 2-hydroxypropyl-γ-cyclodextrin.
4. The method of claim 1 wherein the viscosifying agent further comprises a material selected from the group consisting of a hydrophobically modified hydroxypropyl guar, a hydrophobically modified carboxymethylhydroxypropyl guar, a hydrophobically modified polymethacrylate, a hydrophobically modified polyacrylamide, a hydrophobically modified polyvinyl alcohol, a hydrophobically modified polyvinylpyrrolidone, and combinations thereof.
5. A method comprising:
providing a treatment fluid that comprises a base fluid and a viscosifying agent;
wherein the viscosifying agent comprises a hydrophobically modified polymer and the viscosifying agent optionally further comprises, a viscoelastic surfactant, a phosphonate surfactant, or a combination thereof; wherein the viscosifying agent is present in amount of about 0.1% to about 10% by weight of the treatment fluid and,
wherein the hydrophobically modified polymer comprises hydroxethyl cellulose
introducing the treatment fluid into a well bore penetrating a subterranean formation at a pressure sufficient to create or enhance at least one fracture in the subterranean formation;
introducing a cyclodextrin modifier composition comprising a cyclodextrin modifier into the portion of the subterranean formation such that the cyclodextrin modifier contacts the treatment fluid wherein the viscosity of the treatment fluid is decreased due to the combination of the hydrophobically modified polymer and the cyclodextrin modifier wherein the cyclodextrin modifier comprises hydroxyethylcellulose; and wherein the cyclodextrin modifier is present in an amount of about 1% to about 20% by weight of the composition.
6. The method of claim 5 wherein the cyclodextrin modifier further comprises a methyl cyclodextrin, a hydroxyethyl cyclodextrin, a 2-hydroxyethyl cyclodextrin, a carboxymethyl cyclodextrin, a carboxyethyl cyclodextrin, a glucosyl cyclodextrin, and a maltosyl cyclodextrin.
7. The method of claim 6 wherein the cyclodextrin modifier, in addition to hydroxypropyl-β-cyclodextrin, is selected from the group consisting of glucosyl-α-cyclodextrin, maltosyl-α-cyclodextrin, glucosyl-β-cyclodextrin, maltosyl-α-cyclodextrins, methyl-α-cyclodextrin, 2-hydroxypropyl-β-cyclodextrin, hydroxyethyl-α-cyclodextrin, and 2-hydroxypropyl-γ-cyclodextrin.
8. The method of claim 5 wherein the viscosifying agent further comprises a material selected from the group consisting of a hydrophobically modified hydroxypropyl guar, a hydrophobically modified carboxymethylhydroxypropyl guar, a hydrophobically modified polymethacrylate, a hydrophobically modified polyacrylamide, a hydrophobically modified polyvinyl alcohol, a hydrophobically modified polyvinylpyrrolidone, and combinations thereof.
9. The method of claim 5 wherein the cyclodextrin modifier is introduced to the subterranean formation before the treatment fluid is placed.
10. The method of claim 5 wherein the cyclodextrin modifier is introduced to the subterranean formation after the treatment fluid is placed.