Polymeric garment material

1. A method of making garment material, the method having the steps:

fitting a substrate onto a mould;

applying a coagulant to the substrate and then applying a layer of foam of a polymeric material to the substrate;

allowing for the coagulant to coagulate some of the foam for a controlled period so that an underside of the layer of foam polymeric material, which is closest to the substrate, coagulates to form a coagulated layer and an outer part of the foam layer does not coagulate and forms an uncoagulated layer;

removing the uncoagulated foam layer before a film skin can form on the layer of foam, to leave a cohesive, porous, and breathable coagulated layer of polymeric material on the substrate, wherein the controlled period is such that the garment or garment material when subjected to a temperature of 20+2° C. and a relative humidity of 65±2% for 265 minutes, will hold between 1.0 mg and 8.5 mg of water per cm 2 of the garment material; and

removing the garment material comprising the substrate and the coagulated polymeric material from the mould.

2. The method of claim 1 , wherein the step of removing the uncoagulated foam comprises directing a fluid at the substrate.

3. The method of claim 2 , wherein the fluid is a liquid.

4. The method of claim 2 , wherein the fluid is a gas.

5. The method of claim 1 , wherein the step of removing the uncoagulated foam from the substrate comprises immersing the substrate in liquid.

6. The method of claim 1 wherein the substrate comprises knitted nylon.

7. The method of claim 1 wherein the substrate is a blend of 95% nylon and 5% lycra.

8. The method of claim 1 comprising the step of immersing the substrate in water to remove coagulant after the step of removing the uncoagulated foam from the substrate.

9. The method of claim 8 comprising the step of drying the substrate after the step of immersing the substrate in water.

10. The method of claim 1 , wherein the coagulant is an aqueous solution of one or more electrolytes.

11. The method claim 1 , wherein the coagulant is an alcoholic solution of one or more electrolytes.

12. The method of claim 1 , wherein the polymeric material comprises at least one of: nitrile latex, natural latex, polyurethane latex, polyvinyl chloride latex, neoprene and polyvinylacetate.

13. The method of claim 1 , further comprising the step of applying a coating in an array of discrete areas to the layer of coagulated polymeric material.

14. The method of claim 13 further comprising at least one of the steps of:

washing the garment material to remove residue;

partially drying the garment material;

providing an array former; and

dressing the garment material on the array former before applying the coating; and

then curing the layer of coating; and

stripping the garment material from the array former.

15. The method of claim 13 , wherein the layer of coating comprises at least one of: nitrite latex, natural latex, PU latex and latex.

16. The method of claim 13 wherein the array of discrete areas of coating comprises an array of dots.

17. The method of claim 13 wherein the array of discrete areas of coating comprises a combination of an array of dots and strengthening patches.

18. A method of making garment material, the method having the steps:

fitting a substrate onto a mould;

applying a coagulant to the substrate and then applying a layer of foam of a polymeric material to the substrate;

allowing for the coagulant to coagulate some of the foam for a controlled period so that an underside of the layer of foam polymeric material, which is closest to the substrate, coagulates to form a coagulated layer and an outer part of the foam layer does not coagulate and forms an uncoagulated layer;

removing the uncoagulated layer before a film skin can form on the layer of foam, to leave a cohesive, porous, and breathable coagulated layer of polymeric material on the substrate; and

removing the garment material comprising the substrate and the coagulated polymeric material from the mould.