Process for manufacturing a battery incorporating an anodized metallic battery separator having through-pores
A process of manufacturing a lithium ion battery that includes an anode and a cathode. In the process, a cathodic electrode layer and a composite structure are assembled to form a stack. The stack includes the cathodic electrode layer, an anodic electrode layer and a separator layer between the cathodic electrode layer and the anodic electrode layer. The composite structure includes the anodic electrode layer and the separator layer. The separator layer includes a porous anodized metal oxide layer containing substantially straight and parallel nanometer scale through-pores haying a diameter of less than 100 nm. The anodized metal oxide of the porous anodized metal oxide layer is selected from the group consisting of aluminum oxide, titanium oxide, zirconium oxide, niobium oxide, tungsten oxide, tantalum oxide, and hafnium oxide.
1. A process of manufacturing a lithium ion battery, the process comprising assembling a cathodic electrode layer and a composite structure to form a stack, the stack comprising the cathodic electrode layer, an anodic electrode layer and a separator layer between the cathodic electrode layer and the anodic electrode layer wherein the composite structure comprises the anodic electrode layer and the separator layer, wherein the separator layer comprises a porous anodized metal oxide layer containing substantially straight and parallel nanometer scale through-pores having a diameter of greater than 10 but less than 100 nm and extending through the entire thickness of the porous anodized metal oxide layer, the anodic electrode layer comprises an anodic material capable of reversibly inserting lithium, and the cathodic electrode layer comprises a cathodic material capable of reversibly inserting lithium, wherein the porous anodized metal oxide separator layer comprises an anodized metal oxide selected from the group consisting of aluminum oxide, titanium oxide, zirconium oxide, niobium oxide, tungsten oxide, tantalum oxide, and hafnium oxide, and wherein the anodic electrode layer comprises a material selected from the group consisting of vanadium, carbon, silicon, aluminum, tin, and lithium titanate.
2. The process of claim 1 wherein the separator layer comprises the porous anodized metal oxide layer and a polymeric separator layer.
3. The process of claim 1 wherein the separator layer comprises the porous anodized metal oxide layer and a polymeric separator layer.
4. The process of claim 1 wherein the separator layer comprises the porous anodized metal oxide layer and a polymeric separator layer.
5. The process of claim 1 wherein the separator layer comprises the porous anodized metal oxide layer and two polymeric separator layers and the porous anodized metal oxide layer is sandwiched between the two polymeric separator layers.
6. The process of claim 5 wherein the anodic material comprises a material selected from the group consisting of vanadium, carbon, silicon, aluminum, tin, and lithium titanate.