Composite anode active material, anode including the same and lithium battery using the anode
A composite anode active material includes a composite of a carbon-based anode active material, a metal-based anode active material and polymer particles. By increasing the conductivity of the composite anode active material, a lithium battery having a large capacity, high initial efficiency, high rate capability and improved cycle life performance can be obtained. An anode includes the composite anode active material and a lithium battery includes the anode.
1. An anode active material composition comprising:
a composite material consisting of a carbon-based anode active material, a metal-based anode active material, and crosslinked elastic polymer particles,
wherein an amount of the metal-based anode active material is in the range of from 1 to 100 parts by weight, with respect to 100 parts by weight of the carbon-based anode active material,
the crosslinked elastic polymer particles comprise at least one selected from the group consisting of a polystyrene-based polymer, a poly(meth)acrylate-based polymer, a polyurethane-based polymer, polyvinylalcohol-based polymer, and a polyolefin-based polymer, or a copolymer or a crosslinked polymer of at least two polymers selected from the group consisting of a polystyrene-based polymer, a poly(meth)acrylate-based polymer, a styrene-butadiene-based copolymer, a polyurethane-based polymer, a polyvinylalcohol-based polymer, and a polyolefin-based polymer; and
a binder.
2. The anode active material composition of claim 1 , wherein an average diameter of the crosslinked elastic polymer particles is in the range of from 20 nm to 20 μm.
3. The anode active material composition of claim 1 , wherein the crosslinked elastic polymer particles comprise a vinyl-based polymer.
4. The anode active material composition of claim 1 , wherein an amount of the crosslinked elastic polymer particles in the composite material is in the range of from 1 to 30 parts by weight with respect to 100 parts by weight of the carbon-based anode active material.
5. The anode active material composition of claim 1 , wherein the carbon-based anode active material comprises at least one selected from the group consisting of graphite, natural graphite, artificial graphite, soft carbon and hard carbon.
6. The anode active material composition of claim 1 , wherein the metal-based anode active material comprises at least one metal selected from the group consisting of Si, Sn, Al, Ge, Pb, Zn, Ag and Au, or an alloy thereof.
7. An anode active material composition comprising:
a composite material consisting of a carbon-based anode active material, a metal-based anode active material comprising a first metal, metal particles comprising a second metal different from the first metal, and crosslinked elastic polymer particles,
wherein an amount of the metal-based anode active material is in the range of from 1 to 100 parts by weight, with respect to 100 parts by weight of the carbon-based anode active material,
the crosslinked elastic polymer particles comprise at least one selected from the group consisting of a polystyrene-based polymer, a poly(meth)acrylate-based polymer, a polyurethane-based polymer, a polyvinylalcohol-based polymer, and a polyolefin-based polymer, or a copolymer or a crosslinked polymer of at least two polymers selected from the group consisting of a polystyrene-based polymer, a poly(meth)acrylate-based polymer, a styrene-butadiene-based copolymer, a polyurethane-based polymer, a polyvinylalcohol-based polymer, and a polyolefin-based polymer; and
a binder.
8. The anode active material composition of claim 7 , wherein the first metal comprises at least one selected from the group consisting of Si, Sn, Al, Ge, Pb, Zn, Ag and Au, or an alloy thereof and the second metal comprises at least one selected from the group consisting of Ni, Cu, Co, Ag and Au, or an alloy thereof.
9. The anode active material composition of claim 7 , wherein an average diameter of the metal particles is in the range of from 20 nm to 10 μm.
10. The anode active material composition of claim 7 , wherein an amount of the metal particles in the composite material is in the range of from 1 to 30 parts by weight, with respect to 100 parts by weight of the carbon-based anode active material.
11. The anode active material composition of claim 7 , wherein an average diameter of the crosslinked elastic polymer particles is in the range of from 20 nm to 20 μm.
12. The anode active material composition of claim 7 , wherein the crosslinked elastic polymer particles comprise a vinyl-based polymer.
13. The anode active material composition of claim 7 , wherein an amount of the crosslinked elastic polymer particles in the composite material is in the range of from 1 to 30 parts by weight with respect to 100 parts by weight of the carbon-based anode active material.
14. The anode active material composition of claim 7 , wherein the carbon-based anode active material comprises at least one selected from the group consisting of graphite, natural graphite, artificial graphite, soft carbon and hard carbon.
15. An anode comprising an anode current collector and the anode active material composition of claim 1 coated on the anode current collector.
16. A lithium battery comprising the anode according to claim 15 , a cathode and an electrolytic solution.
17. An anode comprising an anode current collector and the anode active material composition of claim 7 coated on the anode current collector.
18. A lithium battery comprising the anode according to claim 17 , a cathode and an electrolytic solution.