Self-adhesive silicone compositions which can be crosslinked to form elastomers
Self-adhesive crosslinkable silicone compositions may be transparent and prepared without conventional adhesion promoters, and contain (1) an organopolysiloxane having a minimum of two aliphatically unsaturated carbon-carbon bond-containing groups, (2) a pendant Si—H functional organopolysiloxane having at least 3 Si—H groups and a minimum of 0.7 weight percent of Si-bonded hydrogen, and (3) a linear organopolysiloxane bearing terminal Si—H groups, wherein the mol ratio of silicon-bonded hydrogen in (2) to that in [(2) and (3)] is from 0.05 to 1.
1. A silicone composition which can be crosslinked to form elastomers, comprising:
(1) organosilicon compound(s) which have SiC-bonded radicals having aliphatic carbon-carbon multiple bonds and comprise units of the formula
R a R 1 b SiO (4-a-b)/2 (I),
where
the radicals R are identical or different and are each an optionally substituted, SiC-bonded, aliphatically saturated hydrocarbon radical,
the radicals R 1 are identical or different and are each an optionally substituted, SiC-bonded, aliphatically unsaturated hydrocarbon radical,
a is 0, 1, 2 or 3 and
b is 0, 1, 2 or 3,
with the proviso that the sum a+b is less than or equal to 3 and at least two radicals R 1 are present per molecule,
(2) organopolysiloxane(s) which have Si-bonded hydrogen atoms and comprise units of the formula
R 2 c H d SiO (4-c-d)/2 (II),
where
the radicals R 2 are identical or different and each have one of the meanings given above for R,
c is 0, 1, 2 or 3 and
d is 0, 1 or 2,
with the proviso that the sum c+d is less than or equal to 3 and there are on average at least three units of the formula (II) with c=d=1 present per molecule, where the content of Si-bonded hydrogen is greater than or equal to 1.0% by weight,
(3) essentially linear organopolysiloxane(s) having terminally Si-bonded hydrogen atoms and
(4) a catalyst which promotes the addition of Si-bonded hydrogen onto aliphatic multiple bonds, with the proviso that the molar ratio of Si-bonded hydrogen originating from component (3) and based on 100 parts by weight of composition, to the sum of the Si-bonded hydrogen originating from the components (2) and (3), in each case based on 100 parts by weight of composition, is in the range from 0.05 to 1, and wherein the composition, which when cured, exhibits a Shore A hardness >5.
2. The composition of claim 1 , wherein component (1) comprises essentially linear siloxanes in a mixture with organopolysiloxane resin(s).
3. The composition of claim 2 , wherein component (2) comprises linear siloxane(s) or cyclic siloxane(s).
4. The composition of claim 2 , wherein organopolysiloxanes (3) are of the formula
R 3 2 HSiO(SiR 3 2 O) p SiR 3 2 H (III)
where
the radicals R 3 are identical or different and are each an optionally substituted, SiC-bonded, aliphatically saturated hydrocarbon radical and
p is 0 or an integer from 1 to 250.
5. The composition of claim 2 , wherein the ratio of the proportions by weight of the component (3) to the component (2) is in the range from 60:1 to 0.3:1.
6. The composition of claim 2 , wherein the molar ratio of the total SiH groups in the components (2) and (3) to Si-bonded radicals having an aliphatic carbon-carbon multiple bond of the component (1) is from 1.0 to 5.
7. The composition of claim 1 , wherein component (2) comprises linear siloxanes or cyclic siloxanes.
8. The composition of claim 7 , wherein organopolysiloxane(s) (3) are of the formula
R 3 2 HSiO(SiR 3 2 O) p SiR 3 2 H (III)
where
the radicals R 3 are identical or different and are each an optionally substituted, SiC-bonded, aliphatically saturated hydrocarbon radical and
p is 0 or an integer from 1 to 250.
9. The composition of claim 1 , wherein organopolysiloxanes (3) are of the formula
R 3 2 HSiO(SiR 3 2 O) p SiR 3 2 H (III)
where
the radicals R 3 are identical or different and are each an optionally substituted, SiC-bonded, aliphatically saturated hydrocarbon radical, and
p is 0 or an integer from 1 to 250.
10. The composition of claim 1 , wherein the ratio of the proportions by weight of the component (3) to the component (2) is in the range from 60:1 to 0.3:1.
11. The composition of claim 1 , wherein the molar ratio of the total SiH groups in the components (2) and (3) to Si-bonded radicals having an aliphatic carbon-carbon multiple bond of the component (1) is from 1.0 to 5.
12. A process for producing the composition of claim 1 , comprising mixing the individual components in any order.
13. A molding, produced by crosslinking a crosslinkable silicone composition prepared by the process of claim 12 .
14. A molding produced by crosslinking the composition of claim 1 .
15. The molding of claim 14 which is a material composite in which at least part of the composite consists of a silicone elastomer produced by crosslinking a crosslinkable silicone composition comprising:
(1) organosilicon compound(s) which have SiC-bonded radicals having aliphatic carbon-carbon multiple bonds and comprise units of the formula
R a R 1 b SiO (4-a-b)/2 (I),
where
the radicals R are identical or different and are each an optionally substituted, SiC-bonded, aliphatically saturated hydrocarbon radical,
the radicals R 1 are identical or different and are each an optionally substituted, SiC-bonded, aliphatically unsaturated hydrocarbon radical,
a is 0, 1, 2 or 3 and
b is 0, 1, 2 or 3,
with the proviso that the sum a+b is less than or equal to 3 and at least two radicals R 1 are present per molecule,
(2) organopolysiloxane(s) which have Si-bonded hydrogen atoms and comprise units of the formula
R 2 c H d SiO (4-c-d)/2 (II),
where
the radicals R 2 are identical or different and each have one of the meanings given above for R,
c is 0, 1, 2 or 3 and
d is 0, 1 or 2,
with the proviso that the sum c+d is less than or equal to 3 and there are on average at least three units of the formula (II) with c=d=1 present per molecule, where the content of Si-bonded hydrogen is greater than or equal to 1.0% by weight,
(3) essentially linear organopolysiloxane(s) having terminally Si-bonded hydrogen atoms and
(4) a catalyst which promotes the addition of Si-bonded hydrogen onto aliphatic multiple bonds, with the proviso that the molar ratio of Si-bonded hydrogen originating from component (3) and based on 100 parts by weight of composition to the sum of the Si-bonded hydrogen originating from the components (2) and (3), in each case based on 100 parts by weight of composition, is in the range from 0.05 to 1.
16. A process for producing a material composite, comprising applying a crosslinkable silicone composition of claim 1 to at least one substrate, and crosslinking the crosslinkable silicone composition.
17. The composition of claim 1 , wherein the weight ratio of component (3) to component (2) is from 25:1 to 1:1.
18. The composition of claim 1 , which when cured, exhibits a Shore A hardness >10.
19. The composition of claim 1 , which when cured, exhibits a Shore A hardness of from 20 to 60.