Lithium disilicate glass-ceramic, method for production thereof and use thereof
The invention relates to glass-ceramics based on the lithium disilicate system which can be mechanically machined easily in an intermediate step of crystallization and, after complete crystallization, represent a very strong, highly-translucent and chemically-stable glass-ceramic. Likewise, the invention relates to a method for the production of these glass-ceramics. The glass-ceramics according to the invention are used as dental material.
1. A lithium disilicate glass-ceramic having the following composition:
55 to 70% by weight of SiO 2 ,
10 to 15% by weight of Li 2 O,
10 to 20% by weight of the stabiliser selected from the group consisting of ZrO 2 , HfO 2 and mixtures thereof,
0.1 to 5% by weight of K 2 O,
0.1 to 5% by weight of Al 2 O 3 ,
0 to 10% by weight of additives selected from the group consisting of boron oxide, phosphorus oxide, fluorine, sodium oxide, barium oxide, strontium oxide, magnesium oxide, zinc oxide, calcium oxide, yttrium oxide, titanium oxide, niobium oxide, tantalum oxide, lanthanum oxide and mixtures thereof, and
0 to 10% by weight of colourants.
2. The lithium disilicate glass-ceramic according to claim 1 , wherein the colourants are glass-colouring oxides and/or pigments.
3. The lithium disilicate glass-ceramic according to claim 2 , wherein the glass-colouring oxides are selected from the group of the oxides of iron, titanium, cerium, copper, chromium, cobalt, nickel, manganese, selenium, silver, indium, gold, and rare earth metals.
4. The lithium disilicate glass-ceramic according to claim 2 , wherein the pigments are doped spinels.
5. The lithium disilicate glass-ceramic according to claim 1 having the following composition:
58 to 64% by weight of SiO 2 ,
11 to 13% by weight of Li 2 O,
10 to 15% by weight of the stabiliser selected from the group consisting of ZrOz, HfO 2 and mixtures thereof,
2 to 5% by weight of K 2 O,
2 to 5% of Al 2 O 3 ,
2 to 5% of P 2 O and also
0 to 5% by weight of additives selected from the group consisting of boron oxide, fluorine, sodium oxide, barium oxide, strontium oxide, magnesium oxide, zinc oxide, calcium oxide, yttrium oxide, titanium oxide, niobium oxide, tantalum oxide, lanthanum oxide and mixtures thereof, and
0 to 10% by weight of colourants.
6. A method for the production of a lithium disilicate glass-ceramic according to claim 1 , in which
a) an initial glass is produced which comprises the composition of the glass-ceramic,
b) the initial glass is subjected to a first heat treatment in order to produce a glass-ceramic which has lithium metasilicate as main crystal phase,
c) the glass-ceramic of b) is subjected to a second heat treatment in which the lithium metasilicate is converted with SiO 2 from the initial glass into lithium disilicate and subsequently lithium disilicate is present as main crystal phase.
7. The method according to claim 6 ,
wherein the first heat treatment is effected at a temperature of 620° C. to 800° C. over a period of time of 1 to 200 min.
8. The method according to claim 7 ,
wherein the second heat treatment is effected at a temperature of 800° C. to 1,040° C. over a period of time of 5 to 200 min.
9. The lithium disilicate glass-ceramic according to claim 3 , wherein the rare earth metals are selected from the group consisting of neodymium, praseodymium, samarium and europium.
10. The method according to claim 7 , wherein the first heat treatment is effected at a temperature of 650° C. to 750° C. over a period of time of 10 to 60 min.
11. The method according to claim 8 , wherein the second heat treatment is effected at a temperature of 800° C. to 870° C. over a period of time of 5 to 30 min.
12. A dental material comprising the lithium disilicate glass-ceramic according to claim 1 .
13. A shaped dental product comprising the lithium disilicate glass-ceramic according to claim 1 .
14. The shaped dental product according claim 13 , which is an inlay, an onlay, a bridge, a pin construction, a veneer, or a crown.