Red fluorescent material, method for producing red fluorescent material, white light source, illuminating device, and liquid crystal display
The present invention provides an efficient red fluorescent material and a method for producing the same, provides a white light source and an illuminating device each of which uses this red fluorescent material to achieve snow-white lighting, and furthermore provides a liquid crystal display having excellent color reproduction. The red fluorescent material contains an element (A), europium (Eu), silicon (Si), carbon (C), oxygen (O), and nitrogen (N), at an atomic ratio of the following in compositional formula (1). [A (m-x) Eu x ][Si (9-y) C y ]O n N [12-2(n-m)/3 ] Note that, in the compositional formula (1), element A is group 2 element including at least calcium (Ca) and strontium (Sr). Also, note that, in the composition formula (1), m, x, y, and n satisfy 3<m<5, 0<x<1, 0<y<9, and 0<n<10, respectively. Such red fluorescent material is able to improve quantum efficiency, compared with a red fluorescent material which does not contain calcium (Ca) but contains strontium (Sr) as the element A.
1. A red fluorescent material containing an element A, europium (Eu), silicon (Si), carbon (C), oxygen (O), and nitrogen (N), at an atomic ratio of the following composition formula (1):
[A (m-x) Eu x ][Si (9-y) C y ]O n N [12-2(n-m)/3 ],
wherein the element A is an group 2 element including at least calcium (Ca) and strontium (Sr), when, each of atomic ratios of Ca, Sr, and another group 2 element is α, β, and γ, respectively (m=α+β+γ), a relation of 0<α/(α+β)≦0.2 is satisfied; and m, x, y, and n satisfy 3<m<5, 0<x<1, 0<y<9, and 0<n<10, respectively.
2. The red fluorescent material according to claim 1 , wherein, in the composition formula (1), a relation of 0.012≦y≦0.10 is satisfied.
3. The red fluorescent material according to claim 1 , wherein, in a PLE (Photo Luminescence Excitation) spectrum, a relative value of a luminescence intensity of 550 nm excitation wavelength when a luminescence intensity of 400 nm excitation wavelength is defined as 1 is not more than 0.82.
4. A method for producing a red fluorescent material, comprising:
mixing a carbonate compound of an element A, europium nitride, silicon nitride, and melamine to form a mixture so that the element A, europium (Eu), silicon (Si), carbon (C), oxygen (O), and nitrogen (N) are contained at an atomic ratio of the following composition formula (1):
[A (m-x) Eu x ][Si (9-y) C y ]O n N [12-2(n-m)/3 ],
wherein the element A is a group 2 element including at least calcium (Ca) and strontium (Sr),
wherein, when, each of atomic ratios of Ca, Sr, and another group 2 element is α, β, and γ, respectively (m=α+β+γ), a relation of 0<α/(α+β)≦0.2 is satisfied, and
wherein m, x, y, and n satisfy 3<m<5, 0<x<1, 0<y<9, and 0<n<10, respectively;
burning the mixture to form a burned material; and
pulverizing the burned material.
5. The method for producing a red fluorescent material according to claim 4 , further comprising:
burning the pulverized burned material to form a second burned material; and
pulverizing the second burned material.
6. A white light source, comprising:
a blue light-emitting diode formed on an element substrate; and
a kneaded material which is obtained by kneading a red phosphor and a green phosphor with a transparent resin and is arranged on the blue light-emitting diode, the red phosphor containing an element A, europium (Eu), silicon (Si), carbon (C), oxygen (O), and nitrogen (N) at an atomic ratio of the following composition formula (1):
[A (m-x) Eu x ][Si (9-y) C y ]O n N [12-2(n-m)/3 ],
wherein the element A is a group 2 element including at least calcium (Ca) and strontium (Sr),
wherein, when, each of atomic ratios of Ca, Sr, and another group 2 element is α, β, and γ, respectively (m=α+β+γ), a relation of 0<α/(α+β)≦0.2 is satisfied, and
wherein m, x, y, and n satisfy 3<m<5, 0<x<1, 0<y<9, and 0<n<10, respectively.