Stabilizer composition for halogen-containing polymers
The present invention relates to a stabilizer composition for halogen-containing polymers and polymer mixtures, comprising at least one metal salt of isocyanuric acid, isothiocyanuric acid or a derivative thereof, to a process for the preparation thereof, the thus produced stabilizer compositions, polymer compositions comprising the stabilizer compositions, and to methods of using the stabilizer compositions.
1. A stabilizer composition for halogen-containing polymers, comprising at least one metal salt of a compound of formula I or stereoisomer thereof:
wherein
R 1 , R 2 and R 3 are independently hydroxyethyl or 2,3-epoxypropanyl; and
X is O.
2. The stabilizer composition of claim 1 , wherein the metal salt of the compound of formula I is a compound of formula II:
wherein
Me is a metal ion, x is an integer from 1 to 6, and y is an integer from 1 to 4.
3. The stabilizer composition of claim 1 , wherein the metal is an alkali metal, alkaline earth metal, aluminum, lead or zinc.
4. The stabilizer composition of claim 3 , wherein the alkali metal or alkaline earth metal is selected from the group consisting of sodium, potassium, magnesium and calcium.
5. The stabilizer composition of claim 4 , wherein the isocyanuric acid metal salt is trisodium trishydroxyethylene isocyanurate.
6. The stabilizer composition of claim 1 , further comprising one or more additional components selected from the group consisting of primary stabilizers, co-stabilizers, zeolites, antioxidants, fillers, plasticizers, dyestuffs, pigments, antistatic agents, surfactants, blowing agents, impact modifiers, UV stabilizers, lubricants, processing agents and other auxiliaries.
7. The stabilizer composition of claim 6 , wherein the primary stabilizers or co-stabilizers are selected from the group consisting of 1,3-diketone compounds, polyols, metal salts, natural or synthetic minerals, amino acid derivatives, organic esters of phosphorous acid, epoxy compounds, salts of halogen-containing oxy acids and amino alcohols.
8. A process of preparing a stabilizer composition according to claim 1 , comprising: reacting a compound of formula I or stereoisomer thereof:
wherein
R 1 , R 2 and R 3 are independently hydroxyethyl or 2,3-epoxypropanyl and
X is O;
with a metal hydroxide or metal oxide, wherein the reaction is carried out in the presence of water as a catalyst.
9. The process of claim 8 , wherein the metal hydroxide or metal oxide is selected from the group consisting of alkali metal hydroxides, alkaline earth metal hydroxides, aluminum hydroxide, lead hydroxide, lead oxide, zinc oxide, and zinc hydroxide.
10. The process of claim 8 , further comprising the step of drying the reaction product.
11. The process of claim 8 , further comprising adding one or more additional components selected from the group consisting of primary stabilizers, co-stabilizers, zeolites, antioxidants, fillers, plasticizers, dyestuffs, pigments, antistatic agents, surfactants, blowing agents, impact modifiers, UV stabilizers, lubricants, processing agents and other auxiliaries to said composition before, during or after the reaction step.
12. A stabilizer composition obtainable by the process of claim 8 .
13. A polymer composition comprising a halogen-containing polymer and a stabilizer composition of claim 1 .
14. The polymer composition of claim 13 , wherein the halogen-containing polymer is a thermoplastic.
15. The polymer composition of claim 14 , wherein the thermoplastic is polyvinylchloride.
16. The polymer composition of claim 13 , further comprising one or more additional components selected from the group consisting of primary stabilizers, co-stabilizers, zeolites, antioxidants, fillers, plasticizers, dyestuffs, pigments, antistatic agents, surfactants, blowing agents, impact modifiers, UV stabilizers, lubricants, processing agents and other auxiliaries.
17. The polymer composition of claim 13 , wherein the amount of stabilizer composition in the polymer composition is from about 1 to 20 per hundred halogen-containing polymer resin (phr).
18. A molded article comprising or consisting of the polymer composition of claim 13 .
19. A method for the stabilization of halogen-containing polymers, comprising contacting the halogen-containing polymer with a stabilizer composition according to claim 1 .
20. The method according to claim 19 , wherein the halogen-containing polymer is polyvinylchloride.