Garnet-type lithium ion-conducting oxide and all-solid-state lithium ion secondary battery containing the same
An all-solid-state lithium ion secondary battery containing a novel garnet-type oxide serving as a solid electrolyte. The garnet-type lithium ion-conducting oxide is one represented by the formula Li 5+X La 3 (Zr X , A 2-X )O 12 , wherein A is at least one selected from the group consisting of Sc, Ti, V, Y, Nb, Hf, Ta, Al, Si, Ga, Ge, and Sn and X satisfies the inequality 1.4≦X<2, or is one obtained by substituting an element having an ionic radius different from that of Zr for Zr sites in an garnet-type lithium ion-conducting oxide represented by the formula Li 7 La 3 Zr 2 O 12 , wherein the normalized intensity of an X-ray diffraction (XRD) pattern with a diffraction peak, as normalized on the basis of the intensity of a diffraction peak, is 9.2 or more.
1. A garnet-type lithium ion-conducting oxide that is represented by the formula Li 5+X La 3 (Zr X , A 2−X )O 12 ,
wherein A is Nb or Ta, and X satisfies the inequality 1.4≦X<2.
2. The garnet-type lithium ion-conducting oxide according to claim 1 , wherein X satisfies the inequality 1.6≦X≦1.95.
3. The garnet-type lithium ion-conducting oxide according to claim 1 , wherein X satisfies the inequality 1.65≦X≦1.9.
4. An all-solid-state lithium ion secondary battery in which a solid electrolyte layer is sandwiched between a positive electrode containing a positive electrode active material capable of occluding and releasing lithium ions and a negative electrode containing a negative electrode active material capable of releasing and occluding lithium ions,
wherein the solid electrolyte layer is composed of a garnet-type lithium ion-conducting oxide according to claim 1 .