Flexographic printing original plate
The present invention aims to provide a flexographic printing original plate where, although it is a flexible aqueous developing plate, reproducibility of fine lines is good. A flexographic printing original plate which is a photosensitive printing original plate where at least (A) a supporting member, (B) a photosensitive resin layer, (C) a protective layer for preventing the polymerization inhibition due to oxygen in the photosensitive resin layer and (D) a heat-sensitive mask layer are successively layered, characterized in that, the photosensitive resin layer (B) is a layer which is able to be developed by water, Young's modulus of the protective layer (C) is 4 MPa to 35 MPa, layer thickness of the protective layer (C) is 0.2 μm to 2.0 μm and Young's modulus (MPa) and layer thickness (μm) of the protective layer (C) satisfy the following formula 1: 1≦(Young's modulus)×(Layer thickness) 2 ≦18 (Formula 1).
1. A flexographic printing original plate which is a photosensitive printing original plate where at least (A) a supporting member, (B) a photosensitive resin layer, (C) a protective layer for preventing the polymerization inhibition due to oxygen in the photosensitive resin layer and (D) a heat-sensitive mask layer are layered in the following order: (A), (B), (C), and (D),
wherein the photosensitive resin layer (B) is a layer which is able to be developed by a water-based developer, Young's modulus of the protective layer (C) is 4 MPa to 35 MPa, layer thickness of the protective layer (C) is 0.2 μm to 2.0 μm and Young's modulus (MPa) and layer thickness (μm) of the protective layer (C) satisfy the following Formula 1:1 MPa(μm) 2 ≦(Young's modulus)×(Layer thickness) 2 ≦18 MPa(μm) 2 (Formula 1), and the heat-sensitive mask layer (D) comprises a binder and a material capable of absorbing infrared rays and blocking ultraviolet rays.
2. The flexographic printing original plate according to claim 1 , wherein the photosensitive resin layer (B) comprises the latex as a main component.
3. The flexographic printing original plate according to claim 1 or 2 , wherein the protective layer (C) is soluble in water.
4. The flexographic printing original plate of claim 1 , wherein the binder comprises a polyamide.
5. The flexographic printing original plate of claim 4 , wherein the binder comprises a polyamide copolymer.
6. The flexographic printing original plate of claim 4 , wherein the binder comprises a cationic polyamide, an anionic polyamide, or a nonionic polyamide.
7. The flexographic printing original plate of claim 4 , wherein the polyamide comprises a tertiary amine group, a quaternary ammonium salt group, an ether group, or a sulfonic group.
8. The flexographic printing original plate of claim 1 , wherein the material comprises a dye or a pigment.
9. The flexographic printing original plate of claim 8 , wherein the pigment comprises carbon black, graphite, chromium oxide, or iron oxide.
10. The flexographic printing original plate of claim 1 , wherein the protective layer (C) comprises a water-soluble polymer.
11. The flexographic printing original plate of claim 10 , wherein the water-soluble polymer comprises a polyamide, a polyvinyl alcohol, a polyacrylic acid, a polyethylene oxide, an alkyl cellulose, a cellulose-based polymer, a cellulose acetate butyrate, a polybutyral, butyl rubber, a NBR rubber, an acrylic rubber, a styrene-butadiene rubber, a latex, a polyester, or a mixture thereof.
12. The flexographic printing original plate of claim 1 , wherein the protective layer (C) has a thermal decomposing temperature higher than that of the heat-sensitive mask layer (D).
13. The flexographic printing original plate of claim 2 , wherein the latex comprises a polybutadiene latex, a natural rubber latex, a styrene-butadiene copolymer latex, an acrylonitrile-butadiene latex, a polychloroprene latex, a polyisoprene latex, a polyurethane latex, a methylmethacrylate-butadiene copolymer latex, a vinylpyridine polymer latex, a butyl polymer latex, a thiokol polymer latex, an acrylate polymer latex, or a copolymer comprising acrylic acid or methacrylic acid.
14. The flexographic printing original plate of claim 2 , wherein the latex comprises a polybutadiene latex, a styrene-butadiene copolymer latex, an acrylonitrile-butadiene latex, a polyisoprene latex, or a methylmethacrylate-butadiene copolymer latex.