Negative active material for a rechargeable lithium battery, a method of preparing the same, and a rechargeable lithium battery comprising the same
The present invention relates to a negative active material for a rechargeable lithium battery, which includes a silicon-based composite having a silicon oxide of the form SiO x where x≦1.5 and at least one element selected from the group consisting of B, P, Li, Ge, Al, and V, and a carbonaceous material. The negative active material of the present invention can improve the cycle-life and high-rate charge/discharge characteristics of a rechargeable lithium battery.
1. A method for preparing a negative active material for a rechargeable lithium battery, comprising:
mixing one or more compounds selected from the group consisting of B 2 O 3 , B 2 O, P 2 O 5 , P 2 O 3 , Li 2 O, Li 2 CO 3 , LiOH, GeO 2 , Al 2 O 3 , V 2 O 5 , and combinations thereof, with SiO 2 and Si to thereby produce a mixture;
heat treating the mixture to prepare a silicon-based composite comprising a silicon oxide of the form SiO x where x≦1.5, and one or more elements selected from the group consisting of B, P, Li, Ge, Al, and V;
quenching the silicon-based composite; and
coating the silicon-based composite with a carbonaceous material.
2. The method for preparing a negative active material for a rechargeable lithium battery according to claim 1 , wherein the SiO 2 and Si are mixed in a weight ratio between 3:1 and 1:1.
3. The method for preparing a negative active material for a rechargeable lithium battery according to claim 1 , wherein the one or more compounds selected from the group consisting of B-containing compounds, P-containing compounds, Li-containing compounds, Ge-containing compounds, Al-containing compounds, and V-containing compounds is a glass network former.
4. The method for preparing a negative active material for a rechargeable lithium battery according to claim 1 , wherein the one or more compounds are added in an amount between 10 and 30 wt % based on the total weight of SiO 2 and Si.
5. The method for preparing a negative active material for a rechargeable lithium battery according to claim 1 , wherein the heat treating is performed at a temperature between 600° C. and 1000° C.
6. The method for preparing a negative active material for a rechargeable lithium battery according to claim 1 , wherein x is between 0.5 and 1.5.
7. The method for preparing a negative active material for a rechargeable lithium battery according to claim 1 , wherein the carbonaceous material is crystalline carbon or amorphous carbon.
8. A method for preparing a negative active material for a rechargeable lithium battery, comprising:
mixing SiO 2 and Si with one or more compounds selected from the group consisting of B 2 O 3 , B 2 O, P 2 O 5 , P 2 O 3 , Li 2 O, Li 2 CO 3 , LiOH, GeO 2 , Al 2 O 3 , and V 2 O 5 to thereby produce a mixture;
heat treating the mixture to prepare a silicon-based composite comprising: a silicon oxide of the form SiO x where x≦1.5, and one or more elements selected from the group consisting of B, P, Li, Ge, Al, and V; and
mixing the silicon-based composite with a carbonaceous material.
9. The method for preparing a negative active material for a rechargeable lithium battery according to claim 8 , wherein the SiO 2 and Si are mixed in a weight ratio between 3:1 and 1:1.
10. The method for preparing a negative active material for a rechargeable lithium battery according to claim 8 , wherein the one or more compounds are a glass network former.
11. The method for preparing a negative active material for a rechargeable lithium battery according to claim 8 , wherein the heat treating is performed at a temperature between 600° C. and 1000° C.
12. The method for preparing a negative active material for a rechargeable lithium battery according to claim 8 , further comprising quenching after performing the heat treatment.
13. The method for preparing a negative active material for a rechargeable lithium battery according to claim 8 , wherein x is between 0.5 and 1.5.
14. The method for preparing a negative active material for a rechargeable lithium battery according to claim 8 , wherein the one or more compounds are added in an amount between 10 and 30 wt % based on the total weight of SiO 2 and Si.
15. The method for preparing a negative active material for a rechargeable lithium battery according to claim 8 , wherein the carbonaceous material is crystalline carbon or amorphous carbon.
16. The method for preparing a negative active material for a rechargeable lithium battery according to claim 8 , wherein the silicon-based composite and the carbonaceous material are provided in weight ratio between 10:90 and 90:10.
17. The method for preparing a negative active material for a rechargeable lithium battery according to claim 16 , wherein the weight ratio of the silicon-based composite to the carbonaceous material is between 30:70 and 70:30.
18. The method for preparing a negative active material for a rechargeable lithium battery according to claim 8 , wherein the carbonaceous material is a first carbonaceous material, the method further comprising coating the mixture of the silicon-based composite and the first carbonaceous material with a second carbonaceous material.