Dihydroxypropylamide-modified polysiloxane compound
A modified polysiloxane compound is represented by following Formula (1), in which R 1 to R 9 represent hydrocarbon groups selected from linear alkyl groups having 1 to 20 carbon atoms, branched chain alkyl groups having 3 to 6 carbon atoms, and cyclic alkyl groups having 3 to 6 carbon atoms; p and q represent average numbers of siloxane units indicated in parentheses, where p is a number of 1 or more and q is a number of 2 or more; and “A” represents a group selected from a group represented by following Formula (2), a group represented by following Formula (3), and hydrogen atom. The modified polysiloxane compound has at least a siloxane unit wherein “A” is the group represented by following Formula (2), and a siloxane unit wherein “A” is the group represented by following Formula (3).
1. A modified polysiloxane compound of Formula (1):
wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , and R 9 are the same as or different from one another and independently represent a hydrocarbon group selected from the group consisting of a linear alkyl group having 1 to 20 carbon atoms, a branched chain alkyl group having 3 to 6 carbon atoms, and a cyclic alkyl group having 3 to 6 carbon atoms; p and q each represent an average number of siloxane units indicated in parentheses, where p is a number of 1 or more and q is a number of 2 or more; and “A” represents a group selected from the group consisting of a group of Formula (2), a group of Formula (3), and hydrogen atom, and wherein the modified polysiloxane compound has at least (i) a siloxane unit wherein “A” is the group of Formula (2) and (ii) a siloxane unit wherein “A” is the group of Formula (3):
wherein R 10 represents single bond or a linear or branched chain alkylene group having 1 to 17 carbon atoms; R 11 represents single bond or a linear or branched chain alkylene group having 1 to 17 carbon atoms; and R 12 represents hydrogen atom or a linear, branched chain, or cyclic alkyl group having 1 to 6 carbon atoms.
2. The modified polysiloxane compound according to claim 1 , wherein, in siloxane units of Formula (a):
wherein R 9 and “A” are as defined above, the content of a siloxane unit of Formula (a) wherein “A” is the group of Formula (3) is 1 mole percent or more based on the total moles of the siloxane units of Formula (a).
3. The modified polysiloxane compound according to claim 1 , wherein (p+q) is from 4 to 5000, and wherein p/(p+q) is from 0.05 to 0.9.
4. The modified polysiloxane compound according to claim 1 , wherein (p+q) is from 10 to 30.
5. The modified polysiloxane compound according to claim 1 , wherein R 1 to R 9 are methyl groups; and R 12 is hydrogen atom or methyl group.
6. A method for producing the modified polysiloxane compound of claim 1 , the method comprising the step of grafting, through a hydrosilylation reaction, a compound of Formula (5) and a compound of Formula (6):
wherein R 10 represents single bond or a linear or branched chain alkylene group having 1 to 17 carbon atoms; R 11 represents single bond or a linear or branched chain alkylene group having 1 to 17 carbon atoms; and R 12 represents hydrogen atom or a linear, branched chain, or cyclic alkyl group having 1 to 6 carbon atoms,
to a polysiloxane compound of Formula (4):
wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , and R 9 are the same as or different from one another and independently represent a hydrocarbon group selected from the group consisting of a linear alkyl group having 1 to 20 carbon atoms, a branched chain alkyl group having 3 to 6 carbon atoms, and a cyclic alkyl group having 3 to 6 carbon atoms; and p and q each represent an average number of siloxane units indicated in parentheses, where p is a number of 1 or more and q is a number of 2 or more.
7. The modified polysiloxane compound according to claim 1 , wherein,
in siloxane units of Formula (a):
wherein R 9 and “A” are as defined above, (p+q) is from 4 to 5000, and p/(p+q) is from 0.05 to 0.9, the content of a siloxane unit of Formula (a) wherein “A” is the group of Formula (2) is 75 to 99 mole percent based on the total moles of the siloxane units of Formula (a), and
in siloxane units of Formula (a):
wherein R 9 and “A” are as defined above, (p+q) is from 4 to 5000, and p/(p+q) is from 0.05 to 0.9, the content of a siloxane unit of Formula (a) wherein “A” is the group of Formula (3) is 1 to 25 mole percent based on the total moles of the siloxane units of Formula (a).