Primer layer for multilayer optical film
Disclosed herein is an optical article including a multilayer optical film and a primer layer disposed on the multilayer optical film. The primer layer consists essentially of a sulfopolyester and a crosslinker. The multilayer optical film may be a reflective film, a polarizer film, a reflective polarizer film, a diffuse blend reflective polarizer film, a diffuser film, a brightness enhancing film, a turning film, a mirror film, or a combination thereof. A microstructured or unstructured optical layer may be disposed on the primer layer opposite the multilayer optical film. Also disclosed herein is a method of making the optical article. Also disclosed herein is a display device including the optical article.
1. An optical article comprising:
a multilayer optical film, and
a primer layer disposed on the multilayer optical film, the primer layer consisting of a sulfopolyester, a melamine-formaldehyde crosslinker, a catalyst and a surfactant, wherein the ratio of sulfopolyester to crosslinker is from about 1:1 to about 20:1.
2. The optical article of claim 1 , the sulfopolyester comprising a water soluble sulfopolyester or a water dispersible sulfopolyester.
3. The optical article of claim 1 , the sulfopolyester comprising:
one or more dicarboxylic acid monomers selected from the group consisting of sulfonated isophthalic acid, isophthalic acid, and terephthalic acid; and
one or more diol monomers selected from the group consisting of ethylene glycol, diethylene glycol, neopentyl glycol, and 1,4-cyclohexane dimethanol.
4. The optical article of claim 1 , the primer layer having a thickness of from about 30 to about 500 nm.
5. The optical article of claim 1 , the primer layer having a Tg of at least about 50° C.
6. The optical article of claim 1 , the multilayer optical film comprising a reflective film, a polarizer film, a reflective polarizer film, a diffuse blend reflective polarizer film, a diffuser film, a brightness enhancing film, a turning film, a mirror film, or a combination thereof.
7. The optical article of claim 1 , the multilayer optical film comprising alternating layers of first and second optical layers, the first and second optical layers comprising first and second polymers, respectively, the first and second polymers selected from the group consisting of polyethylene terephthalate, polyethylene naphthalate, cellulose triacetate, polypropylene, polyester, polycarbonate, polymethylmethacrylate, polyimide, polyamide, and blends thereof.
8. The optical article of claim 1 , further comprising a microstructured layer disposed on the primer layer, wherein the microstructured layer comprises a structured surface having a plurality of microstructures, and the structured surface comprises an outer surface of the article.
9. The optical article of claim 8 , the microstructured layer being halogen-free.
10. A display device comprising:
a display panel,
one or more light sources, and
the article of claim 1 .
11. A method of making an optical article, comprising:
coating a primer composition on a multilayer optical film thereby forming a primed multilayer optical film, the primer composition consisting of a sulfopolyester, a melamine-formaldehyde crosslinker, a catalyst and a surfactant, wherein the ratio of sulfopolyester to crosslinker is from about 1:1 to about 20:1; and
optionally stretching the primed multilayer optical film in at least one direction.
12. The method of claim 11 , the primed multilayer optical film having an original length, and wherein stretching comprises stretching the primed multilayer optical film to at least 6 times the original length.