Nanoscale switching devices with partially oxidized electrodes
A nanoscale switching device is provided. The device comprises: a first electrode of a nanoscale width; a second electrode of a nanoscale width; an active region disposed between the first and second electrodes, the active region having a non-conducting portion comprising an electronically semiconducting or nominally insulating and a weak ionic conductor switching material capable of carrying a species of dopants and transporting the dopants under an electric field and a source portion that acts as a source or sink for the dopants; and an oxide layer either formed on the first electrode, between the first electrode and the active region or formed on the second electrode, between the second electrode and the active region. A crossbar array comprising a plurality of the nanoscale switching devices is also provided. A process for making at least one nanoscale switching device is further provided.
1. A nanoscale switching device, comprising:
a first electrode of a nanoscale width;
a second electrode of a nanoscale width;
an active region disposed between the first and second electrodes, the active region having a non-conducting portion comprising an electronically semiconducting or nominally insulating and a weak ionic conductor switching material capable of carrying a species of dopants and transporting the dopants under an electric field and a source portion that acts as a source or sink for the dopants; and
an oxide layer either formed on the first electrode, between the first electrode and the active region or formed on the second electrode, between the second electrode and the active region, wherein the electrode with which the oxide layer is associated is metal and wherein the oxide layer is an oxide of the metal.
2. The nanoscale switching device of claim 1 wherein the active region comprises a multi-valent metal oxide.
3. The nanoscale switching device of claim 2 , wherein the multi-valent metal oxide is titanium dioxide and the dopants are oxygen vacancies.
4. The nanoscale switching device of claim 1 wherein the source region is present on the side of the non-conducting oxide region opposite to that of the metal oxide layer.
5. The nanoscale switching device of claim 1 wherein the non-conducting portion is thinner than the source portion.
6. A process for making at least one nanoscale switching device of claim 1 , comprising:
providing the first electrode;
forming on the first electrode the active region disposed over the first electrode; and
providing the second electrode over the active region,
wherein either the oxide is formed between the first electrode and the active region or the oxide-is formed between the second electrode and the active region, wherein the electrode with which the oxide layer is associated is metal and wherein the oxide layer is an oxide of the metal.
7. The process of claim 6 wherein the non-conducting portion comprises TiO 2 and the dopants comprise oxygen vacancies.
8. The process of claim 6 wherein either the oxide is formed on the first electrode, the non-conducting portion is formed on the oxide, the source portion is formed on the non-conducting portion, and the second electrode is formed on the source portion or the source portion is formed on the first electrode, the non-conducting portion is formed on the source portion, the oxide is formed on the non-conducting portion, and the second electrode is formed on the oxide.
9. A nanoscale crossbar array comprising:
a first group of conducting nanowires running in a first direction;
a second group of conducting nanowires-running in a second direction and intersecting the first group of nanowires;
a plurality of switching devices formed at intersections of the first and second groups of nanowires, each switching device having a first electrode formed by a first nanowire of the first group and a second electrode formed by a second nanowire of the second group, and an active region disposed at the intersection between the first and second nanowires, the active region having a non-conducting portion comprising an electronically semiconducting or nominally insulating and a weak ionic conductor switching material capable of carrying a species of dopants and transporting the dopants under an electric field and a source portion that acts as a source or sink for the dopants; and
an oxide layer either formed on the first electrode, between the first electrode and the active region or formed on the second electrode, between the second electrode and the active region, wherein the electrode with which the oxide layer is associated is metal and wherein the oxide layer is an oxide of the metal.
10. The nanoscale crossbar array of claim 9 wherein the active region comprises a multi-valent metal oxide.
11. The nanoscale crossbar array of claim 10 , wherein the multi-valent metal oxide is titanium dioxide and the dopants are oxygen vacancies.
12. The nanoscale crossbar array of claim 9 wherein the source region is present on the side of the non-conducting oxide region opposite to that of the metal oxide layer.
13. The nanoscale crossbar array of claim 9 wherein the non-conducting portion is thinner than the source portion.