Aromatic dicyanate compounds with high aliphatic carbon content
Aromatic dicyanate compounds which comprise aliphatic moieties having at least about six carbon atoms and resins and thermoset products based on these compounds.
1. A dicyanante compound of formula (Ia):
wherein:
each m independently is 1 or 2;
the moieties R independently represent halogen, cyano, nitro, optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted alkoxy, optionally substituted alkenyl, optionally substituted alkenyloxy, optionally substituted aryl having from 6 to about 10 carbon atoms, optionally substituted aralkyl having from 7 to about 12 carbon atoms, optionally substituted aryloxy having from 6 to about 10 carbon atoms, and optionally substituted aralkoxy having from 7 to about 12 carbon atoms and n has a value of from about 7 to about 24;
and any non-aromatic cyclic moieties comprised in the above formula (Ia) may optionally carry one or more substituents and/or may optionally comprise one or more double bonds and/or may optionally be polycyclic.
2. The dicyanate compound of claim 1 , wherein n has a value of from about 9 to about 16.
3. The dicyanate compound of claim 1 , wherein n has a value of 10, 11, or 12.
4. The dicyanate compound of claim 1 , wherein n equals 11.
5. The dicyanate compound of claim 1 , wherein each m independently is 1.
6. A dicyanate compound, chosen from 1,1-bis(4-cyanatophenyl)cyclododecane, 1,1-bis(4-cyanato-3,5-dimethylphenyl)cyclo-dodecane, 1,1-bis(4-cyanato-3-methylphenyl)cyclododecane, 1,1-bis(4-cyanatophenyl)cyclodecane, 2,2-bis(4-cyanatophenyl)adamantanone, 4,4′-bis(4-cyanatophenyl)octahydro-1,4:5,8-dimethanonaphthalen-2(1H)ylidene and 5,5-bis(4-cyanatophenyl)hexahydro-4,7-methanoindane.
7. A dicyanate compound which is 1,1-bis(4-cyanatophenyl)cyclododecane.