Chlorohydrin processing equipment comprising stainless steel
The present invention provides a process for the production of chlorohydrins, comprising generating a chlorohydrins processing stream and contacting at least a portion of a surface comprising a austenitic stainless steel with the chlorohydrin processing stream. It has now been surprisingly discovered that certain stainless steels can be utilized to form portions, or the entirety of, one or more pieces of processing equipment utilized in such processes.
1. A process for the production of a chlorohydrin comprising
generating a chlorohydrin process stream; and
contacting at least a portion of a surface comprising a austenitic stainless steel comprising from about 0.18 wt % to about 0.52 wt % nitrogen, from about 19.5 wt % to about 24.5 wt % chromium, from about 17.5 wt % to about 22.5 wt % nickel, from about 6.0 wt % to about 7.5 wt % molybdenum, from about 0.01 wt % to about 0.02 wt % carbon, with the remainder being incidental impurities and the balance iron, with the chlorohydrin process stream.
2. The process of claim 1 , wherein the chlorohydrin process stream has a pH of greater than about 9.
3. The process of claim 1 , wherein the chlorohydrin process stream has a salt concentration of at least about 5 wt %.
4. The process of claim 1 , wherein the chlorohydrin process stream has a temperature of at least about 70° C.
5. The process of claim 1 , wherein the chlorohydrin process stream has an oxidation potential of up to about 300 mV/Ag-AgCl.
6. The process of claim 1 , wherein the chlorohydrin process stream is a waste stream.
7. The process of claim 1 , wherein the stainless steel comprises from about 0.18 wt % to about 0.22 wt % nitrogen, from about 23.5 wt % to about 24.5 wt % chromium, from about 21.5 wt % to about 22.5 wt % nickel, from about 6.0 wt % to about 6.5 wt % molybdenum, and from about 0.01 wt % to about 0.02 wt % carbon.
8. The process of claim 1 , wherein the stainless steel comprises from about 0.48 wt % to about 0.52 wt % nitrogen, from about 19.5 wt % to about 20.5 wt % chromium, from about 17.5 wt % to about 18.5 wt % nickel, from about 7.1 wt % to about 7.5 wt % molybdenum, and from about 0.01 wt % to about 0.02 wt % carbon.
9. The process of claim 1 , wherein the surface comprises a portion of a heat exchanger.
10. The process of claim 1 , wherein the chlorohydrin produced is epichlorohydrin.
11. The process of claim 10 , wherein the epichlorohydrin is produced by reacting allyl chloride with chlorine in the presence of water to form glycerol dichlorohydrin and treating the glycerol dichlorohydrin with a base to provide the epichlorohydrin.
12. The process of claim 10 , wherein the epichlorohydrin is produced by reacting glycerol with hydrochloric acid to form glycerol dichlorohydrin and treating the glycerol dichlorohydrin with a base to provide the epichlorohydrin.
13. The process of claim 10 , wherein the epichlorohydrin is produced by reacting allylalcohol dissolved in hydrochloric acid with gaseous chlorine to form glycerol dichlorohydrin and treating the glycerol dichlorohydrin with a base to provide the epichlorohydrin.