Electrode with polyamide imide-based binder for lithium secondary battery and lithium secondary battery comprising the same
An electrode for a lithium secondary battery and a lithium secondary battery including the same, the electrode including a polyamide imide (PAI)-based binder, wherein a 1,3-benzenediamine peak is not observed when a composition including components extracted from the electrode by a solvent capable of dissolving the polyamideimide (PAI)-based binder is analyzed with pyrolysis-gas chromatography (Py-GC) under conditions of a pyrolysis temperature of about 750 to about 780° C., a pyrolysis time of about 5 seconds to about 15 seconds, and increasing a gas chromatography oven temperature from about 40° C. to about 300° C. at a rate of about 10° C./min.
1. A lithium secondary battery, the lithium secondary battery comprising:
an electrode including a polyamide imide (PAI)-based binder, wherein:
the electrode includes a positive electrode, the positive electrode including a positive active material layer and a current collector,
the electrode includes the polyamideimide (PAI)-based binder in an amount of about 3 wt % to about 5 wt % based on the weight of the positive active material layer, and
wherein forming the electrode consists essentially of
mixing an active material, a conductive material, and the PAI-based binder with a solvent to form an active material composition;
disposing the active material composition on a current collector to form a coating;
performing a drying process at a temperature of from 80° C. to 145° C. for about 2 to 20 hours to form a dried coating; and
pressing the dried coating to provide an electrode, and
a 1,3-benzenediamine peak is not observed when a composition including components extracted from the electrode by a solvent capable of dissolving the polyamideimide (PAI)-based binder is analyzed with pyrolysis-gas chromatography (Py-GC) under conditions of a pyrolysis temperature of about 750 to about 780° C., a pyrolysis time of about 5 seconds to about 15 seconds, and increasing a gas chromatography oven temperature from about 40° C. to about 300° C. at a rate of about 10° C./min.
2. The lithium secondary battery as claimed in claim 1 , wherein the active material is a silicon-based active material.
3. The lithium secondary battery as claimed in claim 1 , wherein the drying process is performed at a temperature of about 100° C. to about 145° C.
4. The lithium secondary battery as claimed in claim 1 , wherein the drying process is performed for about 4 hours to about 20 hours.
5. The lithium secondary battery as claimed in claim 1 , wherein the drying process is performed under a vacuum or under an inert gas.
6. The lithium secondary battery as claimed in claim 1 , wherein a 1,3-benzenediamine peak is observed when the polyamideimide (PAI)-based binder extracted from the electrode for a lithium secondary battery prior to performing the drying process is analyzed with pyrolysis-gas chromatography (Py-GC) under conditions of: a pyrolysis temperature of about 750° C. to about 780° C., a pyrolysis time of about 5 seconds to about 15 seconds, and increasing a gas chromatography oven temperature from about 40° C. to about 300° C. at a rate of about 10° C./min.
7. The lithium secondary battery as claimed in claim 1 , wherein the solvent capable of dissolving the polyamideimide (PAI)-based binder includes at least one of N-methylpyrrolidone, toluene, and dimethyl sulfoxide (DMSO).
8. The lithium secondary battery as claimed in claim 1 , wherein the electrode does not include 1,3-benzenediamine.