Methods of making and using oxide ceramic solids and products and devices related thereto
Various embodiments relate to a method comprising combining a chelating agent, one or more non-aqueous organic solvents and one or more metallic compounds to produce an oxide ceramic solid in a non-aqueous solution based reaction, wherein the oxide ceramic solid contains metal-oxygen-metal bonds. The oxide ceramic solid can comprise, for example, a gel or a powder. Various devices, including electrolyte interfaces and energy storage devices, are also provided. In one embodiment, the oxide ceramic solid is a cubic garnet having a nominal formula of Li 7 La 3 Zr 2 O 12 (LLZO).
1. A method of making an electrolyte interface comprising:
providing a slurry formed using a chelating agent in a non-aqueous solution-based reaction performed at a temperature ranging from about −15 to about 50° C. and including an oxide ceramic compound having an atomic formula comprising: A x R y C z S a O 12 ,
wherein A is a first cationic species selected from H, Li, Na, Mg, Al and/or Ga and residing in an 8a, 16f, 32g, 24d, 48g or 96h site;
R is a second cationic species selected from La, Ba and/or Ce and residing in a 24c site; and
C is a third cationic species selected from Zr, Ta, Nb, Y or Hf and residing in the 16a site;
providing an oxide ceramic electrolyte that includes a compound selected from A x R y C z S a O 12 ;
forming at least one 3D feature on the oxide ceramic electrolyte to provide an un-sintered electrolyte interface, wherein the 3D feature includes the slurry; and
sintering the un-sintered electrolyte interface to provide the electrolyte interface.
2. The method of claim 1 , wherein the forming step comprises ink-jet printing the slurry on the oxide ceramic electrolyte, self-assembled patterning, stamping the 3D feature into the slurry or using a mold.
3. The method of claim 2 , wherein the mold comprises fibers bonded to the oxide ceramic electrolyte or a patterned sheet.
4. The method of claim 1 , wherein the at least one of the 3D features on the oxide ceramic electrolyte is arranged in a pattern to form an electrolyte interface with hierarchical and highly ordered porosity.
5. An energy storage device comprising an electrolyte that includes an electrolyte interface made by the method of claim 1 .
6. The energy storage device of claim 5 comprising a battery, fuel cell or semi-fuel cell.
7. The energy storage device of claim 6 comprising at least one electrode that includes lithium or sodium.