Liquid crystal display device
A liquid crystal display device includes: a pair of substrates at least one of which is transparent; a liquid crystal layer disposed between the pair of substrates; an electrode group formed on at least one substrate of the pair of substrates, for applying an electric field to the liquid crystal layer; a plurality of active elements connected to the electrode group; and a liquid crystal alignment film disposed on at least one substrate of the pair of substrates, in which the liquid crystal alignment film, which is formed by a photo-alignment process, contains polyimide formed using tetracarboxylic acid dianhydride and/or diamine each having a specific chemical structure.
1. A liquid crystal display device, comprising:
a pair of substrates at least one of which is transparent; a liquid crystal layer disposed between the pair of substrates;
an electrode group formed to one substrate of the pair of substrates, for applying an electric field to the liquid crystal layer, the electric field having a component parallel to the one substrate;
a plurality of active elements connected to the electrode group; and
a liquid crystal alignment film disposed to at least one substrate of the pair of substrates,
wherein the liquid crystal alignment film, which is formed by a photo-alignment process, contains polyimide formed using at least one kind of tetracarboxylic acid dianhydride selected from a compound group A represented by the following Chemical Formulae (1) to (5):
where R 1 s each independently represent hydrogen, an alkyl group having a carbon number of 3 or less, or a dialkylamino group, and at least one R 1 represents a dialkylamino group, where S represents —(CH 2 ) n-, and n represents an integer of 1 to 10.
2. The liquid crystal display device according to claim 1 , wherein any alkyl group of the dialkylamino group represents a dialkylamino group having a carbon number of 3 or less.
3. The liquid crystal display device according to claim 1 , wherein the dialkylamino group is a dimethylamino group.
4. The liquid crystal display device according to claim 1 , wherein an interface tilt angle between the liquid crystal layer and the liquid crystal alignment film is set to 1 degree or less.
5. The liquid crystal display device according to claim 1 , wherein the tetracarboxylic acid dianhydride reacts with at least one kind of diamine selected from a compound group B represented by the following Chemical Formulae (8) to (10):
where among R 2 s contained in each of the formulae (8) to (10), at least two R 2 s each independently represent a methyl group, an alkoxy group having a carbon number of 3 or less, a dialkylamino group, or an alkylamino group and the other R 2 s each independently represent hydrogen or an alkyl group having a carbon number of 3 or less.
6. The liquid crystal display device according to claim 5 , wherein the diamine is represented by the following Chemical Formula (18):
where R 4 s each independently represent hydrogen, an alkyl group having a carbon number of 3 or less, an alkoxy group having a carbon number of 3 or less, a dialkylamino group, or an alkylamino group; and R 5 s each independently represent a methyl group, an alkoxy group having a carbon number of 3 or less, a dialkylamino group, or an alkylamino group.
7. The liquid crystal display device according to claim 1 , wherein the polyimide is formed by imidizing a polyimide precursor formed using the at least one kind of tetracarboxylic acid dianhydride selected from the compound group A, wherein 50% to 95% of a total amount of the polyimide precursor is imidized to form the polyimide.
8. A liquid crystal alignment film varnish comprising a polyamic acid and/or a polyamic acid ester formed using at least one kind of tetracarboxylic acid dianhydride selected from a compound group A represented by the following Chemical Formulae (1) to (5), wherein the liquid crystal alignment film varnish is for a photo-alignment process
where R 1 s each independently represent hydrogen, an alkyl group having a carbon number of 3 or less, or a dialkylamino group, and at least one R 1 represents a dialkylamino group, where S represents —(CH 2 )n-, and n represents an integer of 1 to 10.
9. The liquid crystal alignment film varnish according to claim 8 , wherein any alkyl group of the dialkylamino group represents a dialkylamino group having a carbon number of 3 or less.
10. The liquid crystal alignment film varnish according to claim 8 , wherein the dialkylamino group is a dimethylamino group.
11. The liquid crystal alignment film varnish according to claim 8 , wherein the tetracarboxylic acid dianhydride reacts with at least one kind of diamine selected from a compound group B represented by the following Chemical Formulae (8) to (10):
where among R 2 s contained in each of the formulae (8) to (10), at least two R 2 s each independently represent a methyl group, an alkoxy group having a carbon number of 3 or less, a dialkylamino group, or an alkylamino group and the other R 2 s each independently represent hydrogen or an alkyl group having a carbon number of 3 or less.
12. The liquid crystal alignment film varnish according to claim 11 , wherein the diamine is represented by the following Chemical Formula (18):
where R 4 s each independently represent hydrogen, an alkyl group having a carbon number of 3 or less, an alkoxy group having a carbon number of 3 or less, a dialkylamino group, or an alkylamino group; and R 5 s each independently represent a methyl group, an alkoxy group having a carbon number of 3 or less, a dialkylamino group, or an alkylamino group.