Organic light emitting device and materials for use in same
The present invention provides an OLED in which an organic thin film layer comprising a single layer or plural layers is provided between a cathode and an anode, where the organic thin film layer comprises at least one light emitting layer, and the at least one light emitting layer comprises (a) a host material represented by the following Formula (1): Ra—Ar 1 —Ar 2 —Rb (1) where Ar 1 , Ar 2 , Ra and Rb represent a substituted or unsubstituted benzene ring or a condensed aromatic hydrocarbon group selected from a substituted or unsubstituted naphthalene ring, chrysene ring, a substituted or unsubstituted fluoranthene ring, triphenylene ring, a substituted or unsubstituted phenanthrene ring, a substituted or unsubstituted benzophenanthrene ring, a substituted or unsubstituted dibenzophenanthrene ring, a substituted or unsubstituted benzotriphenylene ring, a substituted or unsubstituted benzochrysene ring, a substituted or unsubstituted picene ring and a substituted or unsubstituted benzofluoranthene ring; and (b) at least one phosphorescent material comprises a phosphorescent organometallic complex having a substituted chemical structure represented by one of the following partial chemical structures represented by the formulas: wherein each R is independently hydrogen or an alkyl substituent having 1-3 carbon atoms, and wherein at least one ring of the formula has one or more of said alkyl substituent.
1. An organic light emitting device comprising an anode, a cathode and an emissive layer, wherein the emissive layer is located between the anode and the cathode, and the emissive layer comprises a host material and a phosphorescent emitter material, wherein:
(a) the host material comprises a substituted or unsubstituted hydrocarbon compound having the chemical structure represented by the formula:
Ra-Ar 1 -Ar 2 -Rb
wherein, in the host material, each of Ra and Ar 1 is a naphthalene ring, Ar 2 is a benzene ring, and Rb is a phenanthrene ring, and the host material has chemical structure represented by the formula:
and
(b) the phosphorescent emitter material comprises a phosphorescent organometallic complex having a substituted chemical structure represented by one of the following partial chemical structures represented by the formulas:
wherein R is hydrogen or methyl, and at least one of R is methyl,
wherein the dashed lines represent bonds with metal M.
2. The organic light emitting device of claim 1 , wherein the triplet energy of the host material is from about 2.0 eV to about 2.8 eV.
3. The organic light emitting device of claim 1 , wherein the phosphorescent emitter material comprises a phosphorescent organometallic complex wherein the substituted chemical structure is substituted with at least two methyl groups.
4. The organic light emitting device of claim 3 , wherein the phosphorescent emitter material comprises a phosphorescent organometallic complex having a substituted chemical structure represented by the following partial chemical structure:
5. The organic light emitting device of claim 1 , wherein the phosphorescent emitter material comprises a metal complex, and
the metal complex comprises a metal atom selected from Ir, Pt, Os, Au, Cu, Re, Ru and a ligand.
6. The organic light emitting device of claim 5 , wherein the metal complex has an ortho-metal bond.
7. The organic light emitting device of claim 5 , wherein the metal atom is Ir.
8. The organic light emitting device of claim 5 , wherein the phosphorescent emitter material comprises a phosphorescent organometallic compound having a substituted chemical structure represented by the following chemical structure:
9. The organic light emitting device of claim 1 , wherein at least one of the phosphorescent materials contained in the light emitting layer has a maximum value of 520 nm or more and 720 nm or less in a light emitting wavelength.
10. The organic light emitting device of claim 9 , wherein the emissive layer comprises an electron transporting layer or an electron injecting layer between the cathode and the light emitting layer, and the electron transporting layer or the electron injecting layer contains an aromatic ring having a nitrogen-containing six-membered or five-membered ring skeleton or a fused aromatic ring compound having a nitrogen-containing six-membered or five-membered ring skeleton.
11. An organic light emitting device comprising an anode, a cathode and an emissive layer, wherein the emissive layer is located between the anode and the cathode, and the emissive layer comprises a host material and a phosphorescent emitter material, wherein:
(a) the host material comprises a substituted or unsubstituted hydrocarbon compound having the chemical structure represented by the formula:
Ra-Ar 1 -Ar 2 -Rb
wherein Ar 2 , Ra, and Rb are each independently a substituted or unsubstituted benzene ring or a substituted or unsubstituted condensed aromatic hydrocarbon group selected from a naphthalene ring, a chrysene ring, a fluoranthene ring, a triphenylene ring, a phenanthrene ring, a benzophenanthrene ring, a dibenzophenanthrene ring, a benzotriphenylene ring, a benzochrysene ring, a picene ring, and a benzofluoranthene ring;
wherein Ar 1 is a substituted or unsubstituted condensed aromatic hydrocarbon group selected from a chrysene ring, a fluoranthene ring, a triphenylene ring, a phenanthrene ring, a benzophenanthrene ring, a dibenzophenanthrene ring, a benzotriphenylene ring, a benzochrysene ring, a picene ring, and a benzofluoranthene ring;
with the provisos that,
when Ar 1 is a substituted or unsubstituted benzene ring, each of Ra and Ar 2 is a different substituted or unsubstituted condensed aromatic hydrocarbon group,
when Ar 2 is a substituted or unsubstituted benzene ring, each of Rb and Ar 1 is a different substituted or unsubstituted condensed aromatic hydrocarbon group; and
substituents for Ra and Rb are not aryl groups; and
(b) the phosphorescent emitter material comprises a phosphorescent organometallic complex having a substituted chemical structure represented by one of the following partial chemical structures represented by the formulas:
wherein R is hydrogen or methyl, and at least one R is methyl,
wherein the dashed lines represent bonds with metal M.
12. The organic light emitting device of claim 11 , wherein the triplet energy of the host material is from about 2.0 eV to about 2.8 eV.
13. The organic light emitting device of claim 11 , wherein the phosphorescent emitter material comprises a phosphorescent organometallic complex wherein the substituted chemical structure is substituted with at least two methyl groups.
14. The organic light emitting device of claim 13 , wherein the phosphorescent emitter material comprises a phosphorescent organometallic complex having a substituted chemical structure represented by the following partial chemical structure:
15. The organic light emitting device of claim 11 , wherein the phosphorescent emitter material comprises a metal complex, and
the metal complex comprises a metal atom selected from Ir, Pt, Os, Au, Cu, Re, Ru and a ligand.
16. The organic light emitting device of claim 15 , wherein the metal complex has an ortho-metal bond.
17. The organic light emitting device of claim 15 , wherein the metal atom is Ir.
18. The organic light emitting device of claim 15 , wherein the phosphorescent emitter material comprises a phosphorescent organometallic compound having a substituted chemical structure represented by the following chemical structure:
19. The organic light emitting device of claim 11 , wherein at least one of the phosphorescent materials contained in the light emitting layer has a maximum value of 520 nm or more and 720 nm or less in a light emitting wavelength.
20. The organic light emitting device of claim 19 , wherein the emissive layer comprises an electron transporting layer or an electron injecting layer between the cathode and the light emitting layer, and the electron transporting layer or the electron injecting layer contains an aromatic ring having a nitrogen-containing six-membered or five-membered ring skeleton or a fused aromatic ring compound having a nitrogen-containing six-membered or five-membered ring skeleton.