IP Library Granted Patent US 9,115,097
Granted Patent B2
US 9,115,097 · App. 13/723,418 · Granted Aug 25, 2015

Surface modified nanoparticles

Inventor: Imad Naasani (Manchester, GB)
Assignee: Nanoco Technologies Ltd.
C07D251/70B82Y30/00B82Y40/00C09K11/565C09K11/623C09K11/70H01L33/502
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Quick Facts
Patent No.
US 9,115,097
App. No.
13/723,418
Granted
Aug 25, 2015
Kind
B2
Abstract

Surface-modified nanoparticles are produced by associating ligand interactive agents with the surface of a nanoparticle. The ligand interactive agents are bound to surface modifying ligands that are tailored to impart particular solubility and/or compatibility properties. The ligand interactive agents are crosslinked via a linking/crosslinking agent, such as hexamethoxymethylmelamine or a derivative thereof. The linking/crosslinking agent may provide a binding site for binding the surface modifying ligands to the ligand interactive agents.

Claims (34)

1. A method of functionalizing a InP/ZnS nanoparticle, comprising:

associating a ligand interactive agent consisting essentially of a C 8 -C 20 fatty acid with the nanoparticle;

crosslinking the ligand interactive agent with a linking/crosslinking agent consisting essentially of hexamethoxymethylmelamine; and

binding a surface modifying ligand to the ligand interactive agent.

2. The method of claim 1 , further comprising providing capping ligands on the nanoparticle and wherein associating a ligand interactive agent with the nanoparticle comprises intercalating the ligand interactive agent with the capping ligands.

3. The method of claim 1 , wherein the surface modifying ligand is water soluble.

4. The method of claim 1 , wherein the surface modifying ligand comprises a polyether.

5. The method of claim 1 , wherein the surface modifying ligand is a monomethoxy polyethylene glycol.

6. The method of claim 1 , wherein the surface modifying ligand comprises a silicone.

7. The method of claim 1 , wherein associating a ligand interactive agent with the nanoparticle comprises incubating the ligand interactive agent with the nanoparticle to yield a ligand interactive agent-nanoparticle association complex.

8. The method of claim 7 , wherein crosslinking the ligand interactive agent comprises contacting the ligand interactive agent-nanoparticle association complex with a solution of the hexamethoxymethylmelamine linking/crosslinking agent to effect crosslinking of the ligand interactive agent.

9. The method of claim 8 , wherein the solution of linking/crosslinking agent further comprises a catalyst.

10. The method of claim 8 , wherein the solution of linking/crosslinking agent further comprises the surface modifying ligand.

11. A functionalized nanoparticle, comprising:

a core comprising InP/ZnS;

a crosslinked ligand interactive agent consisting essentially of a C 8 -C 20 fatty acid associated with the surface of the functionalized nanoparticle; and

at least one surface modifying ligand bound to the ligand interactive agent.

12. The nanoparticle of claim 11 , wherein the ligand interactive agents are associated with the surface of the nanoparticle by intercalating with capping ligands on the nanoparticle.

13. The nanoparticle of claim 11 , wherein the ligand interactive agents are crosslinked via a linking/crosslinking agent consisting essentially of hexamethoxymethylmelamine.

14. The nanoparticle of claim 13 , wherein the surface modifying ligands are bound to the ligand interactive agent via the linking/crosslinking agent.

15. The nanoparticle of claim 11 , wherein the surface modifying ligand comprises a polyether.

16. The nanoparticle of claim 11 , wherein the surface modifying ligand comprises a silicone.

17. The nanoparticle of claim 11 , wherein the nanoparticle is water soluble.

18. The nanoparticle of claim 17 , wherein the nanoparticle has a quantum yield of greater than about 35%.

19. The nanoparticle of claim 18 , wherein the nanoparticle does not comprise cadmium.

20. A composition comprising a nanoparticle and hexamethoxymethylmelamine.

21. The composition of claim 20 , wherein the nanoparticle comprises:

a core comprising InP;

a crosslinked ligand interactive agent consisting essentially of a C 8 -C 20 fatty acid associated with the surface of the nanoparticle; and

at least one surface modifying ligand bound to the ligand interactive agent.

22. The composition of claim 21 , further comprising a polar solvent.

23. The composition of claim 22 , wherein the nanoparticle has a quantum yield of greater than about 35%.

24. The composition of claim 23 , wherein the nanoparticle does not comprise cadmium.

25. The composition of claim 24 , wherein the composition is an ink.

Assignments (3)
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEE PREVIOUSLY RECORDED ON REEL 062977 FRAME 0157. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT OF ASSIGNORS INTEREST. Recorded Jul 13, 2023
From: NANOCO TECHNOLOGIES LTD
To: SAMSUNG ELECTRONICS CO., LTD.
Reel/Frame 064273/0340 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 7, 2023
From: NANOCO TECHNOLOGIES LTD
To: SAMSUNG ELECTRONICS CO. LTD
Reel/Frame 062977/0157 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 8, 2013
From: NAASANI, IMAD
To: NANOCO TECHNOLOGIES, LTD.
Reel/Frame 030174/0322 →
Continuity (2)
Provisional Application 61579440 · Dec 22, 2011
Related Publication 20130190493A1 · Jul 25, 2013