Heterocyclic radical or diradical, the dimers, oligomers, polymers, dispiro compounds and polycycles thereof, the use thereof, organic semiconductive material and electronic or optoelectronic component

1. A heterocyclic compound, or a dimer, oligomer, polymer, dispiro compound, or polycycle thereof, having a structure according to one of the following formulae:

wherein at least one of A 1 and A 2 are present; and A 1 and A 2 , independently, are cyclic linkages that form a ring system selected from the group consisting of, substituted or unsubstituted, carbocyclic, heterocyclic, and polycyclic ring systems; and wherein T is selected from CR 22 , CR 22 R 23 , N, NR 21 , O, or S; or

wherein structure 7 has one or more bridge bonds Z, Z 1 , and Z 2 , and wherein Z, Z 1 and Z 2 are independently selected from alkyl, alkenyl, alkynyl, cycloalkyl, sililyl, alkylsililyl, diazo, disulphide, heterocycloalkyl, heterocyclyl, piperazinyl, dialkyl ether, polyether, primary alkylamine, arylamine, polyamine, aryl, or heteroaryl;

wherein X and Y are independently selected from O, S, N, NR 21 , P, or PR 21 ; wherein R 1-2 and R 21-23 are independently selected from, substituted or unsubstituted, aryl, heteroaryl, heterocyclyl, diarylamine, diheteroarylamine, dialkylamine, heteroarylalkylamine, arylalkylamine, H, F, cycloalkyl, halocycloalkyl, heterocycloalkyl, alkyl, alkenyl, alkynyl, trialkylsilyl, triarylsilyl, halogen, styryl, alkoxy, aryloxy, thioalkoxy, thioaryloxy, sililyl, trialkylsilylalkynyl, (hetero)aliphatic ring system, or (hetero)aromatic ring system, wherein the (hetero)aliphatic or (hetero)aromatic ring system comprises one or more of R 1-2 and R 21-23 .

2. The heterocyclic compound, or the dimer, oligomer, polymer, dispiro compound, or polycycle thereof according to claim 1 , wherein A 1 and A 2 are independently selected from, substituted or unsubstituted, aromatic or heteroaromatic ring systems.

3. The heterocyclic compound, or the dimer, oligomer, polymer, dispiro compound, or polycycle thereof according to claim 2 , wherein the aromatic or heteroaromatic ring systems are independently selected from benzo, naphtho, thiophene, furan, thiazole, imidazole, oxazole, thiadiazole, pyrazine, thiopyran, dithiine, phthalic acid imide, or dithiazole radicals.

4. The heterocyclic compound, or the dimer, oligomer, polymer, dispiro compound, or polycycle thereof according to claim 3 , wherein at least one of the benzo, naphtho, thiophene, furan, thiazole, imidazole, oxazole, thiadiazole, pyrazine, thiopyran, dithiine, phthalic acid imide, or dithiazole radicals are substituted with one or more substituents selected from R 1-2 and R 21-23 .

5. The heterocyclic compound, or the dimer, oligomer, polymer, dispiro compound, or polycycle thereof according to claim 1 , wherein Z, Z 1 , and Z 2 are selected from piperazinyl, alkyl, or cycloalkyl.

6. The heterocyclic compound, or the dimer, oligomer, polymer, dispiro compound, or polycycle thereof according to claim 1 having one of the following structures:

wherein X 1 and Y 1 are independently selected from N or P, and wherein R 3-18 are independently selected from, substituted or unsubstituted, aryl, heteroaryl, heterocyclyl, diarylamine, diheteroarylamine, dialkylamine, heteroarylalkylamine, arylalkylamine, H, F, cycloalkyl, halocycloalkyl, heterocycloalkyl, alkyl, alkenyl, alkynyl, trialkylsilyl, triarylsilyl, halogen, styryl, alkoxy, aryloxy, thioalkoxy, thioaryloxy, sililyl, trialkylsilylalkynyl, (hetero)aliphatic ring system, or (hetero)aromatic ring system, wherein the (hetero)aliphatic or (hetero)aromatic ring system comprises one or more of R 3-18 and R 21-23 .

7. The heterocyclic compound, or the dimer, oligomer, polymer, dispiro compound, or polycycle thereof according to claim 1 , wherein R 1-2 and R 21-23 are individually selected from, substituted or unsubstituted, phenyl, biphenyl, naphthyl, anthranyl, thienyl, imidazolyl, pyrrolyl, thiazolyl, oxazolyl, thiadiazolyl, piperidyl, pyrrolidyl, morpholyl, or thiomorpholyl.

8. The heterocyclic compound, or the dimer, oligomer, polymer, dispiro compound, or polycycle thereof according to claim 1 , wherein R 1-2 and R 21-23 are independently selected from alkyl, cycloalkyl, dialkylamine, diarylamine, alkoxy, aryloxy, thioaryl, thioalkoxy, or perfluoroalkyl.

9. The heterocyclic compound, or the dimer, oligomer, polymer, dispiro compound, or polycycle thereof according to claim 1 , wherein the polycycle is a tricycle.

10. An electronic or optoelectronic component comprising the heterocyclic compound, or the dimer, oligomer, polymer, dispiro compound, or polycycle thereof according to claim 1 , wherein the heterocyclic compound, or the dimer, oligomer, polymer, dispiro compound, or polycycle thereof is a dopant for doping an organic semiconductive matrix material, a blocking layer, a charge injection layer, an electrode material, a memory material, or a semiconductor layer itself in the electronic and optoelectronic component.

11. An organic semiconductive material comprising at least one organic matrix material and the heterocyclic compound, or the dimer, oligomer, polymer, dispiro compound, or polycycle thereof according to claim 1 , wherein the heterocyclic compound, or the dimer, oligomer, polymer, dispiro compound, or polycycle thereof is a dopant.

12. The organic semiconductive material according to claim 11 , wherein the molar doping ratio of dopant to matrix molecule or the doping ratio of dopant to monomeric units of a polymeric matrix molecule is between 1:1 and 1:100,000.

13. An electronic or optoelectronic component comprising an electronically functionally active area, wherein the electronically active area comprises a heterocyclic compound, or a dimer, oligomer, polymer, dispiro compound, or polycycle thereof, having a structure according to one of the following formulae:

wherein at least one of A 1 and A 2 are present; and A 1 and A 2 , independently, are cyclic linkages that form a ring system selected from the group consisting of, substituted or unsubstituted, carbocyclic, heterocyclic, and polycyclic ring systems; and wherein T is selected from CR 22 , CR 22 R 23 , N, NR 21 , O, or S; or

wherein structure 7 has one or more bridge bonds Z, Z 1 , and Z 2 , and wherein Z, Z 1 and Z 2 are independently selected from alkyl, alkenyl, alkynyl, cycloalkyl, sililyl, alkylsililyl, diazo, disulphide, heterocycloalkyl, heterocyclyl, piperazinyl, dialkyl ether, polyether, primary alkylamine, arylamine, polyamine, aryl, or heteroaryl;

wherein X and Y are independently selected from O, S, N, NR 21 , P, or PR 21 ; wherein R 1-2 and R 21 are independently selected from, substituted or unsubstituted, aryl, heteroaryl, heterocyclyl, diarylamine, diheteroarylamine, dialkylamine, heteroarylalkylamine, arylalkylamine, H, F, cycloalkyl, halocycloalkyl, heterocycloalkyl, alkyl, alkenyl, alkynyl, trialkylsilyl, triarylsilyl, halogen, styryl, alkoxy, aryloxy, thioalkoxy, thioaryloxy, sililyl, trialkylsilylalkynyl, (hetero)aliphatic ring system, or (hetero)aromatic ring system, wherein the (hetero)aliphatic or (hetero)aromatic ring system comprises one or more of R 1-2 and R 21-23 .

14. The electronic or optoelectronic component according to claim 13 , wherein the electronically active area comprises an organic semiconductive matrix material and a dopant, wherein the dopant modifies the electronic properties of the semiconductive matrix material, and the dopant comprises the heterocyclic compound, or the dimer, oligomer, polymer, dispiro compound, or polycycle thereof.

15. The electronic or optoelectronic component according to claim 13 , wherein the electronic or optoelectronic component is an organic light-emitting diode, a photovoltaic cell, an organic solar cell, an organic diode, an organic field effect transistor, or a photoinitiated and magnetic memory.