Method for improving high temperature rheology in drilling fluids
A method for enhancing the rheology of drilling fluids that is effective for any mud weight “clay-free” invert emulsion drilling fluid, even when drilling at high temperatures. The improved rheology is effected with addition of a silicon oil to the drilling fluid. A nonlimiting example of such a rheology additive comprises polydimethylsiloxane.
1. A method for drilling in a subterranean formation comprising providing or using in the drilling a clay free invert emulsion drilling fluid having an oleaginous continuous phase, a non-oleaginous discontinuous phase, and a rheology additive comprising a silicon oil, wherein the drilling fluid with the rheology additive, when compared to the drilling fluid without the rheology additive, restricts the increase in plastic viscosity to 50% or less and has at least one of an increased yield point and an increased low shear yield point.
2. The method of claim 1 wherein the silicon oil is polydi methylsiloxane.
3. The method of claim 1 wherein the oleaginous continuous phase comprises: a synthetic oil comprising an ester or olefin; a diesel oil; or a mineral oil selected from the group consisting of n-paraffins, iso-paraffins, cyclic alkanes, branched alkanes, and mixtures thereof.
4. The method of claim 1 wherein the drilling fluid has mud weight in the range of about 9 to about 20 ppg.
5. The method of claim 4 wherein the drilling fluid has mud weight in the range of about 9 to about 12 ppg.
6. The method of claim 1 wherein the drilling fluid comprises from about 0.1 ppb to about 40 ppb of the rheology additive.
7. The method of claim 1 wherein the rheology additive comprises from about 5 ppb to about 30 ppb of silicon oil.
8. The method of claim 1 wherein the silicon oil has a viscosity of about 10 centipoise to about 300K centipoise.
9. The method of claim 1 wherein the drilling fluid has an oil:
water ratio in the range of about 50:50 to about 95:5.
10. The method of claim 1 wherein the non-oleaginous discontinuous phase contains a water activity lowering material selected from the group consisting of: sugar; glycerol, salts selected from the group consisting of calcium chloride, calcium bromide, sodium chloride, sodium bromide, and formate; and combinations thereof.
11. The method of claim 1 wherein the drilling fluid with the rheology additive has at least one of an increased yield point and an increased low shear yield point, when compared to the drilling fluid without the rheology additive.
12. The method of claim 1 wherein the clay-free invert emulsion fluid comprises at least one additive from the group consisting of: weighting agents, inert solids, fluid loss control agents, emulsifiers, salts, dispersion aids, corrosion inhibitors, emulsion thinners, emulsion thickeners, viscosifier, high pressure high temperature emulsifier-filtration control agents, and any combination thereof.
13. The method of claim 1 further comprising at least one of drilling a wellbore, running casing in a wellbore: and cementing a wellbore in the subterranean formation.
14. A method for drilling in a subterranean formation comprising providing or using in the drilling a clay-free invert emulsion drilling fluid having a mud weight in the range of about 9 ppg to about 12 ppg, wherein the drilling fluid comprises a continuous oleaginous phase and a discontinuous non-oleaginous phase in an oil: water ratio in the range of about 50:50 to about 95:5, and 5 ppb to 30 ppb rheology additive comprising a silicon oil, wherein the drilling fluid with the rheology additive, when compared to the drilling fluid without the rheology additive, restricts the increase in plastic viscosity to 50% or less and has a characteristic selected from the group consisting of: an increased yield point; an increased low shear yield point; an increased gel strength; and any combination thereof.
15. The method of claim 14 wherein the drilling fluid has an oleaginous phase selected from the group of oils consisting of: diesel oils; ester oils; olefins; and mineral oils selected from the group consisting of n-paraffins, iso-paraffins, cyclic alkanes, branched alkanes, and mixtures thereof.
16. The method of claim 14 wherein the silicon oil is a polydimethylsiloxane having the formula: (H 3 C) 3 SiO[Si(CH 3 ) 2 O] n Si(CH 3 ) 3 wherein n has a value of 2 to several hundred.
17. The method of claim 16 wherein the polydimethylsiloxane has the following chemical structure:
18. A method for drilling in a subterranean formation comprising providing or using in the drilling a clay-free invert emulsion drilling fluid having an oleaginous continuous phase, a non-oleaginous discontinuous phase, and a rheology additive comprising a silicon oil, wherein the drilling fluid comprises from about 0.1 ppb to about 40 ppb of the rheology additive, and wherein the drilling fluid has an oleaginous continuous phase to non-oleaginous discontinuous phase ratio in the range of about 50:50 to about 95:5; wherein the drilling fluid with the theology additive, when compared to the drilling fluid without the rheology additive, restricts the increase in plastic viscosity to 50% or less and has at least one of an increased yield point and an increased low shear yield point.