Methods for cementing in a subterranean formation using a cement composition containing a set retarder of a polyester
According to an embodiment, a cement composition for use in an oil or gas well, the cement composition comprises: cement; water; and a polymer, wherein the polymer: (i) comprises a monomer or monomers capable of forming a polyester; and (ii) is capable of providing a thickening time of at least 2 hours at a temperature of 400° F. (204.4° C.) and a pressure of greater than about 500 psi (3.4 MPa) for a test composition consisting essentially of: the cement; the water; and the polymer, and in the same proportions as in the cement composition. According to another embodiment, a method of cementing in a subterranean formation comprises: introducing the cement composition into the subterranean formation; and allowing the cement composition to set.
1. A method of cementing in a subterranean formation comprising:
introducing a cement composition into the subterranean formation, wherein the cement composition comprises:
cement;
water; and
a polymer, wherein the polymer:
(i) is capable of providing a thickening time of at least 2 hours at a temperature of 400° F. (204.4° C.) and a pressure of greater than about 500 psi (3.4 MPa) for a test composition consisting essentially of: the cement; the water; and the polymer, and in the same proportions as in the cement composition;
(ii) increases the setting time of the cement composition due to degradation of the polymer; and
(iii) is polylactic acid or polyglycolic acid,
wherein the subterranean formation has a bottomhole temperature greater than or equal to the glass transition temperature and/or the melting point temperature of the polymer; and
allowing the cement composition to set, wherein the polymer does not create voids in the set cement composition.
2. The method according to claim 1 , wherein the water is selected from the group consisting of freshwater, brackish water, and saltwater, in any combination thereof in any proportion.
3. The method according to claim 1 , wherein the polymer is in at least a sufficient concentration such that the cement composition has a thickening time in the range of about 2 to about 7 hours at a temperature of 400° F. (204.4° C.) and a pressure of greater than about 500 psi (3.4 MPa).
4. The method according to claim 1 , wherein the polymer is in a concentration equal to or less than a sufficient concentration such that the cement composition has a setting time of less than 48 hours at a temperature of 400° F. (204.4° C.).
5. The method according to claim 1 , wherein the polymer is in a concentration in the range of about 1% to about 5% by weight of the cement.
6. The method according to claim 1 , wherein the cement composition further includes a degradation catalyst.
7. The method according to claim 1 , wherein the polymer undergoes complete degradation in a specified period of time.
8. The method according to claim 7 , wherein the specified period of time is the time it takes for the cement composition to be introduced into and situated in the portion of the subterranean formation to be cemented.
9. The method according to claim 1 , wherein the cement composition further includes a second set retarder.
10. The method according to claim 9 , wherein the second set retarder is selected from the group consisting of citric acid, glucanolactone, boric acid, tartaric acid, sodium pentaborate, and combinations thereof.
11. The method according to claim 1 , wherein the cement composition further includes a salt.
12. The method according to claim 1 , wherein the subterranean formation is penetrated by a well.
13. The method according to claim 12 , wherein the polymer is in at least a sufficient concentration such that the cement composition has a thickening time in the range of about 1 to about 7 hours at the bottomhole temperature and pressure of the well.
14. The method according to claim 12 , wherein the well is a high-temperature well, a high-pressure well, a geothermal well, a sour gas well, or an acid gas well.
15. The method according to claim 1 , wherein the cement is a calcium aluminate cement.
16. The method according to claim 1 , wherein the polymer partially or completely degrades before the cement sets.
17. The method according to claim 1 , wherein the polymer degrades and decreases in molecular weight at a rate of 5% to 30% per hour at a temperature greater than or equal to the glass transition temperature and/or the melting point temperature of the polymer.