Fiber-based organic electrochemical transistor
An organic electrochemical transistor (OECT) that may be used as a biosensor is built up by layers applied to a monofilament. A first conducting layer applied to the monofilament includes generally cylindrical source and drain contacts with a gap therebetween. An electro-active layer of an organic material altering its electrical conductivity through a change in redox state is in electrical contact with the source and drain contacts, and has a transistor channel interface for contacting an electrolyte. A gate electrode is spaced apart from the first monofilament, and may comprise a cylindrical layer built up on another length of monofilament.
1. An electrochemical transistor device comprising:
a first monofilament and a second monofilament, wherein at least one of the first and second monofilaments is a nylon fiber;
a first conducting layer and an electro-active layer that are substantially coaxial with, and extend circumferentially about, the first monofilament, wherein
the first conducting layer comprises a source contact and a drain contact and includes a gap between the source contact and the drain contact,
the electro-active layer is in electrical contact with the source contact and the drain contact,
the electro-active layer has a transistor channel interface for contacting an electrolyte, and
the electro-active layer is an organic material having an electrical conductivity altered by a change in redox state of the electro-active layer; and
a gate electrode spaced from the first monofilament and comprising a second conducting layer that is substantially coaxial with, and extends circumferentially about, the second monofilament, wherein current flow between the source contact and the drain contact is controllable by a voltage applied to the gate electrode.
2. The electrochemical transistor device of claim 1 , wherein
the first conducting layer abuts the first monofilament, and
the electro-active layer fills the gap.
3. The electrochemical transistor device of claim 2 , wherein the electro-active layer at least partially covers the source and drain contacts.
4. The electrochemical transistor device of claim 1 , further comprising a dielectric layer that is substantially coaxial with, and extends circumferentially about, the first monofilament, wherein the dielectric layer comprises a first section and a second section axially spaced apart and exposing the transistor channel interface between the first and second sections.
5. The electrochemical transistor device of claim 4 , wherein the dielectric layer overlies the electro-active layer.
6. The electrochemical transistor device of claim 4 , wherein the source and drain contacts, and the first and second sections of the dielectric layer are substantially cylindrical.
7. The electrochemical transistor device of claim 4 , wherein the dielectric layer comprises poly(p-xylylene).
8. The electrochemical transistor device of claim 1 , wherein the transistor channel interface is arranged such that flow of electrons between the source contact and the drain contact is controllable by a voltage applied between the gate electrode and one of the source contact and the drain contact.
9. The electrochemical transistor device of claim 1 , wherein the organic material restrains or promotes flow of electrons between the source contact and the drain contact in response to application of the voltage to the gate electrode.
10. The electrochemical transistor device of claim 1 , wherein the organic material is a polymer selected from the group consisting of polythiophenes, polypyrroles, polyanilines, polyisothianaphtalenes, polyphenylene vinylenes, and copolymers thereof.
11. The electrochemical transistor device of claim 10 wherein the organic material comprises poly(3,4-ethylenedioxythiopene) poly(styrene sulfonate).
12. The electrochemical transistor device of claim 1 , wherein at least one of the first and second conducting layers comprises a layer of a metal or a metal compound selected from the group consisting of titanium, platinum, gold, an alloy thereof, and combinations thereof.
13. The electrochemical transistor device of 1 , wherein
at least one of the first and second conducting layers comprises a first metal layer and a second metal layer, and
each of the first and second metal layers comprises a metal or a metal compound selected from the group consisting of titanium, platinum, gold, an alloy thereof, and combinations thereof.
14. A biosensor comprising an electrochemical transistor according to claim 1 , wherein a surface of the gate electrode is functionalized with a material selected from the group consisting of biomolecules, nanoparticles, biocompatible polymers, and combinations thereof.
15. The biosensor of claim 14 , wherein the material functionalizing the surface of the gate electrode is selected from the group consisting of chitosan, graphene, enzymes, DNA molecules, and combinations thereof.