Process for preparing silicate shell microcapsules
View Patent ↗A process for preparing silicate shell microcapsules comprises adding a water reactive silicon compound to an oil in water emulsion, thereby condensing and polymerizing the water reactive silicon compound to form silicate shell microcapsules having a core comprising the oil phase of the said emulsion. The water reactive silicon compound comprises a tetraalkoxysilane and an alkoxysilane having an amino or quaternary ammonium substituted alkyl group.
1. A process for preparing silicate shell microcapsules, the process comprising adding a water reactive silicon compound to an oil in water emulsion, thereby condensing and polymerizing the water reactive silicon compound to form silicate shell microcapsules having a core comprising the oil phase of the emulsion, characterized in that the water reactive silicon compound comprises a tetraalkoxysilane and an alkoxysilane having an amino or quaternary ammonium substituted alkyl group.
2. The process according to claim 1 wherein the tetraalkoxysilane is tetraethoxysilane.
3. The process according to claim 1 wherein the alkoxysilane having an amino or quaternary ammonium substituted alkyl group is a quaternised aminoalkyltrialkoxysilane.
4. The process according to claim 3 wherein the quaternised aminoalkyltrialkoxysilane has the formula R′ 3 —Si—Y—N + R″ 3 , wherein each group R′ is an alkoxy group having one or two carbon atoms, each group R″ is an alkyl group having 1 to 18 carbon atoms, and Y is a divalent hydrocarbon radical having 1 to 18 carbons.
5. The process according to claim 3 wherein the quaternised aminoalkyltrialkoxysilane has the formula (CH 3 O) 3 SiCH 2 CH 2 CH 2 N + (CH 3 ) 2 (CH 2 ) 17 CH 3 Cl − .
6. The process according to claim 1 wherein a mixture of the tetraalkoxysilane and the alkoxysilane having an amino or quaternary ammonium substituted alkyl group is added to the oil in water emulsion.
7. The process according to claim 1 wherein the tetraalkoxysilane and the alkoxysilane having an amino or quaternary ammonium substituted alkyl group are added sequentially to the oil in water emulsion.
8. The process according to claim 1 wherein the aqueous phase of the oil in water emulsion contains a cationic surfactant.
9. The process according to claim 1 wherein the oil phase comprises 10 to 50% by weight of the oil in water emulsion.
10. The process according to claim 1 wherein the median particle size of the oil phase of the oil in water emulsion is 2 to 30 μm.
11. The process according to claim 1 wherein the oil phase of the oil in water emulsion, which becomes encapsulated in the silicate shell microcapsules, comprises a fabric, skin, hair or fibre conditioning agent.
12. The process according to claim 1 wherein the oil phase of the oil in water emulsion, which becomes encapsulated in the silicate shell microcapsules, comprises a silicone textile treatment composition.
13. A process of using an alkoxysilane having an amino or quaternary ammonium substituted alkyl group in the production of silicate shell microcapsules, the process comprising adding a tetraalkoxysilane to an oil in water emulsion, whereby the alkoxysilane having an amino or quaternary ammonium substituted alkyl group modifies the silicate shell structure of the microcapsules produced.
14. The process according to claim 13 , whereby the alkoxysilane having an amino or quaternary ammonium substituted alkyl group confers to the silicate shell structure of the microcapsules a positive surface charge as measured by zeta-potential.
15. The process according to claim 2 wherein the alkoxysilane having an amino or quaternary ammonium substituted alkyl group is a quaternised aminoalkyltrialkoxysilane.
16. The process according to claim 15 wherein the quaternised aminoalkyltrialkoxysilane has the formula R′ 3 —Si—Y—N + R″ 3 , wherein each group R′ is an alkoxy group having one or two carbon atoms, each group R″ is an alkyl group having 1 to 18 carbon atoms, and Y is a divalent hydrocarbon radical having 1 to 18 carbons.
17. The process according to claim 15 wherein the quaternised aminoalkyltrialkoxysilane has the formula (CH 3 O) 3 SiCH 2 CH 2 CH 2 N + (CH 3 ) 2 (CH 2 ) 17 CH 3 Cl − .
18. A silicate shell microcapsule wherein the silicate shell microcapsule is obtained from a process comprising adding a water reactive silicon compound to an oil in water emulsion, thereby condensing and polymerizing the water reactive silicon compound to form silicate shell microcapsules having a core comprising the oil phase of the emulsion, wherein the water reactive silicon compound comprises a tetraalkoxysilane and an alkoxysilane having an amino or quaternary ammonium substituted alkyl group.
19. The silicate shell microcapsule of claim 18 , wherein the oil phase is controlled released.