Nano-coatings for articles
A composite includes a substrate, a binder layer disposed on a surface of the substrate; and a nanofiller layer comprising nanographene and disposed on a surface of the binder layer opposite the substrate. In addition, a nano-coating layer for coating a substrate includes multiple alternating layers of the binder layer and the nanofiller layer. Articles coated with the nano-coating layer prepared from alternating layers of nanofiller layer and binder layer have improved barrier properties, and may be used in down-hole applications.
1. A composite comprising:
a substrate comprising a fluoroelastomer, a perfluoroelastomer, a hydrogenated nitrile butyl rubber, an ethylene-propylene-diene monomer (EPDM) rubber, a silicone, an epoxy, a polyetheretherketone, a bismaleimide, a polyvinylalcohol, a phenolic resin, a tetrafluoroethylene-propylene elastomeric copolymer, iron, steel, a chrome alloy, hastelloy, titanium, molybdenum, or a combination comprising at least one of the foregoing;
a binder layer disposed on a surface of the substrate; and
a nanofiller layer comprising nanographene and disposed on a surface of the binder layer opposite the substrate, wherein the nanographene is derivatized to have functional groups including epoxy, ether, ketone, amine, hydroxy, alkoxy, alkyl, lactone, aryl, or a combination comprising at least one of the forgoing functional groups; and the binder layer is different than the nanofiller layer;
wherein the binder layer is a positively charged binder layer, comprising a polyethyleneamine, a polyethyleneimine, a hyperbranched polyamine, a dendrimeric polyamine, a polyaminoacrylate, a polyaminoacrylate copolymer, or combinations comprising at least one of the foregoing polymers; or wherein the binder layer is a negatively charged binder layer comprising a polycarboxylic acid, a salt of a polycarboxylic acid, a polycarboxylic acid copolymer, or combinations comprising at least one of the foregoing polymers; and
wherein the nanofiller layer further comprises carbon black, mica, clays, or a combination thereof.
2. The composite of claim 1 , wherein the substrate further comprises polyethylene, nylon, polycarbonate, a polyurethane, or a combination comprising at least one of the foregoing.
3. The composite of claim 1 , wherein the binder layer has a positive or negative charge, the nanofiller layer has a positive or negative charge not identical to the charge of the binder layer, and the substrate is neutral or has a charge opposite that of the binder layer.
4. The composite of claim 1 , wherein the substrate is untreated, or is treated by corona treatment, organosilane treatment, or polymer-based primer treatment.
5. The composite of claim 1 , wherein the binder layer is the negatively charged binder layer which comprises polyacrylic acid.
6. The composite of claim 1 , wherein the binder layer is the positively charged binder layer which comprises polyethyleneimine.
7. The composite of claim 1 , wherein the binder layer comprises a binder material which forms interparticle bonds with the derivatized nano graphene.
8. The composite of claim 1 , further comprising additional nano filler comprising fullerenes, nanographite, nanographene, graphene oxide, nanotubes, nanodiamonds, polysilsesquioxanes, or combinations comprising at least one of the foregoing.
9. The composite of claim 8 , wherein the nanofillers are further coated with a metallic coating of Ni, Pd, Fe, Pt, or an alloy comprising at least one of the foregoing.
10. The composite of claim 1 , further comprising multiple alternating layers of the binder layer and the nanofiller layer.
11. The composite of claim 1 , wherein the composite is a coated article.
12. The composite of claim 11 , wherein the article is a sealing element, a valve, a cover, an insulator, or a cutter.
13. A nano-coating for an article, comprising:
multiple alternating layers of
a layer comprising nanographene particles having an aspect ratio greater than or equal to 10 and at least one of carbon black, mica, and clays, and
a binder layer comprising a binder material,
wherein the nano-coating is disposed on a surface of an article comprising a fluoroelastomer, a perfluoroelastomer, a hydrogenated nitrile butyl rubber, an ethylene-propylene-diene monomer (EPDM) rubber, a silicone, an epoxy, a polyetheretherketone, a bismaleimide, a polyvinylalcohol, a phenolic resin, a tetrafluoroethylene-propylene elastomeric copolymer, iron, steel, a chrome alloy, a hastelloy, titanium, molybdenum, or a combination comprising at least one of the foregoing,
the binder layer is different than the layer comprising nanographene particles,
the binder layer is a positively charged binder layer, comprising a polyethyleneamine, a polyethyleneimine, a hyperbranched polyamine, a dendrimeric polyamine, a polyaminoacrylate, a polyaminoacrylate copolymer, or combinations comprising at least one of the foregoing polymers; or the binder layer is a negatively charged binder layer comprising a polycarboxylic acid, a salt of a polycarboxylic acid, a polycarboxylic acid copolymer, or combinations comprising at least one of the foregoing polymers; and
the nanographene particles are derivatized to have functional groups including epoxy, ether, ketone, amine, hydroxy, alkoxy, alkyl, lactone, aryl, or a combination comprising at least one of the forgoing functional groups.