Positive active material for rechargeable lithium battery and recharge lithium battery including the same
A positive active material for a rechargeable lithium battery including a lithium-nickel cobalt manganese composite metal oxide; and 0.18 to 0.25 wt % of sulfur is provided.
1. A positive active material for a rechargeable lithium battery, comprising:
a lithium-nickel cobalt manganese composite metal oxide; and
about 0.20 wt % to 0.25 wt % of sulfur, wherein the sulfur is in the form of a precursor compound of unreacted nickel, cobalt and manganese.
2. The positive active material for a rechargeable lithium battery of claim 1 , wherein the lithium-nickel cobalt manganese composite metal oxide is represented by the following Chemical Formula 1:
Li a Ni x Co y Mn z M k O 2 [Chemical Formula 1]
wherein,
M is Al, Mg, Ti, Zr, or a combination thereof, 0.95≦a≦1.10, 0.45≦x≦0.65, 0.15≦y≦0.25, 0.15≦z≦0.35, 0≦k≦0.1, and x+y+z+k=1.
3. A rechargeable lithium battery, comprising
a negative electrode including a negative active material;
a positive electrode including a positive active material including a lithium-nickel cobalt manganese composite metal oxide and about 0.20 wt % to about 0.25 wt % of sulfur; and
a non-aqueous electrolyte, wherein the sulfur is in the form of a precursor compound of unreacted nickel, cobalt and manganese.
4. The rechargeable lithium battery of claim 3 , wherein the lithium-nickel cobalt manganese composite metal oxide is represented by the following Chemical Formula 1:
Li a Ni x Co y Mn n M k O 2 [Chemical Formula 1]
wherein,
M is Al, Mg, Ti, Zr, or a combination thereof, 0.95≦a≦1.10, 0.45≦x≦0.65, 0.15≦y≦0.25, 0.15≦z≦0.35, 0≦k≦0.1, and x+y+z+k=1.
5. The rechargeable lithium battery of claim 3 , wherein the negative active material comprises a material that reversibly intercalates/deintercalates lithium ions, a lithium metal, a lithium metal alloy, a material being capable of doping and dedoping lithium, or a transition metal oxide.
6. The rechargeable lithium battery of claim 3 , wherein the non-aqueous electrolyte comprises include a non-aqueous organic solvent of a carbonate-based, ester-based, ether-based, ketone-based, alcohol-based, or aprotic solvent.
7. The rechargeable lithium battery of claim 3 , wherein the non-aqueous electrolyte comprises 0.1 to 2.0M lithium salt.