Chemically strengthened glass plate and method for manufacturing same
The present invention aims to provide a chemically strengthened glass plate which has a good yield in a cutting process of the chemically strengthened glass plate and has sufficient strength. The chemically strengthened glass plate has a surface compressive stress of not less than 600 MPa at a surface of the chemically strengthened glass plate, and a compressive stress layer containing two types of stress patterns A and B. The stress pattern A is a stress pattern of a surface portion of the glass plate, and the stress pattern B is a stress pattern of an inside of the glass plate. The stress patterns satisfy the formula S A >S B where S A represents a slope of the stress pattern A and S B represents a slope of the stress pattern B when the stress patterns A and B are each approximated by a linear function.
1. A chemically strengthened glass plate manufactured by ion exchange of a surface of a glass plate to replace alkali metal ions A which are largest in amount among all alkali metal ion components of the glass plate with alkali metal ions B having a larger ionic radius than the alkali metal ions A,
the chemically strengthened glass plate having:
a surface compressive stress of not less than 600 MPa at a surface of the chemically strengthened glass plate; and
a compressive stress layer containing two types of stress patterns X and Y, the stress pattern X being a stress pattern of a surface portion of the glass plate, the stress pattern Y being a stress pattern of an inside of the glass plate,
wherein the stress patterns satisfy the formula S A >S B where S A represents a slope of the stress pattern X and S B represents a slope of the stress pattern Y when the stress patterns X and Y are each approximated by a linear function,
wherein, when an interference pattern of the chemically strengthened glass plate is observed with a surface stress meter based on a principle of an optical waveguide effect, at least one of values r 2 /r 1 and r 3 /r 2 is in a range of 0.3 to 0.7, where r 1 represents an interval between a line of an interference pattern closest to the surface of the glass, and a line of an interference pattern second closest to the surface of the glass; r 2 represents an interval between the line of an interference pattern second closest to the surface of the glass, and a line of an interference pattern third closest to the surface of the glass; and r 3 represents an interval between the line of an interference pattern third closest to the surface of the glass, and a line of an interference pattern fourth closest to the surface of the glass,
wherein the compressive stress layer at the surface of the chemically strengthened glass plate has a depth of 5 to 25 μm.
2. The chemically strengthened glass plate according to claim 1 ,
wherein the surface compressive stress at the surface of the chemically strengthened glass plate is 600 to 900 MPa.
3. The chemically strengthened glass plate according to claim 1 ,
wherein the chemically strengthened glass plate has a thickness of 0.03 to 3 mm.
4. The chemically strengthened glass plate according to claim 1 ,
wherein the glass before the ion exchange is made of soda-lime glass substantially composed of SiO 2 : 65 to 75%, Na 2 O+K 2 O: 5 to 20%, CaO: 2 to 15%, MgO: 0 to 10%, and Al 2 O 3 : 0 to 5% on a mass basis.
5. The chemically strengthened glass plate according to claim 1 ,
wherein the ion exchange includes:
a first step of contacting the glass plate with a first salt that includes alkali metal ions A and B at a proportion P of the alkali metal ions A as expressed as a molar percentage of a total amount of the alkali metal ions A and B; and
a subsequent second step of contacting the glass plate with a second salt that includes alkali metal ions A and B at a proportion Q of the alkali metal ions A as expressed as a molar percentage of the total amount of the alkali metal ions A and B, where the proportion Q is smaller than the proportion P.
6. A method of manufacturing the chemically strengthened glass plate according to claim 1 ,
wherein the ion exchange includes:
a first step of contacting the glass plate with a first salt that includes alkali metal ions A and B at a proportion P of the alkali metal ions A as expressed as a molar percentage of the total amount of the alkali metal ions A and B; and
a subsequent second step of contacting the glass plate with a second salt that includes alkali metal ions A and B at a proportion Q of the alkali metal ions A as expressed as a molar percentage of the total amount of the alkali metal ions A and B, where the proportion Q is smaller than the proportion P.
7. The method according to claim 6 ,
wherein the compressive stress layer formed through the first step at a surface of the glass plate has a depth of 5 to 23 μm.
8. The method according to claim 6 ,
wherein the proportion P is 5 to 50 mol%.
9. The method according to claim 6 ,
wherein the proportion Q is 0 to 10 mol%.