Positive electrode material for lithium battery, positive electrode prepared from the positive material, and lithium battery including the positive electrode
A positive electrode material for a lithium battery, a positive electrode prepared from the positive electrode material, and a lithium battery including the positive electrode are disclosed. The positive electrode material includes a positive active material, an aqueous binder, and tungsten trioxide. Due to the inclusion of the positive active material, the aqueous binder, and the tungsten trioxide (WO 3 ), the positive electrode material may substantially prevent corrosion of an aluminum substrate. The positive electrode material has high electric conductivity. Lithium batteries including positive electrodes prepared from the positive electrode material have decreased resistance of the electrode plate, high rate characteristics, and good lifespan characteristics.
1. A positive electrode slurry composition for a lithium battery, the positive electrode slurry composition comprising: a positive active material; an aqueous binder; tungsten trioxide (WO 3 ) having an average particle diameter of about 5 nm to about 5 μm; and water.
2. The positive electrode slurry composition of claim 1 , wherein an average particle diameter of the tungsten trioxide (WO 3 ) is about 5 nm to about 1 μm.
3. The positive electrode slurry composition of claim 1 , wherein the tungsten trioxide (WO 3 ) is present in the positive electrode slurry composition in an amount of about 0.001 to about 50 parts by weight based on 100 parts by weight of the positive active material.
4. The positive electrode slurry composition of claim 1 , wherein the positive active material comprises at least one of lithium cobalt-based oxide, lithium nickel cobalt manganese-based oxide, or lithium nickel cobalt aluminum-based oxide.
5. The positive electrode slurry composition of claim 1 , wherein the aqueous binder comprises a material selected from the group consisting of carboxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, polyvinylidenefluoride, polytetrafluoroethylene, polyethylene, polypropylene, polybutadiene, butyl rubber, fluorine rubber, polyethyleneoxide, polyvinylalcohol, polyacrylic acid and salts thereof, polyvinylpyrrolidone, polyepichlorohydrin, polyphosphazene, polyacrylonitrile, polystyrene, polyvinylpyridine, chlorosulfonated polyethylene, latex, polyester resins, acryl resins, phenol resins, epoxy resins, polymers of propylene and an olefin having 2 to 8 carbon atoms, copolymers of (meth)acrylic acid and (meth)acrylic acid alkyl ester, and combinations thereof.
6. The positive electrode slurry composition of claim 1 , wherein the aqueous binder is present in the positive electrode slurry composition in an amount of about 0.1 to about 10 parts by weight based on 100 parts by weight of the positive active material.
7. The positive electrode slurry composition of claim 1 , further comprising a conductive agent.
8. The positive electrode slurry composition of claim 7 , wherein the conductive agent comprises at least one of natural graphite, artificial graphite, carbon black, acetylene black, Ketjen black, carbon fiber, carbon nanotube, metal powder, metal fiber, or a conductive polymer.
9. A positive electrode for a lithium battery, the positive electrode comprising:
a metal substrate that is capable of being corroded by a strong alkali; and
a positive electrode layer on at least one surface of the metal substrate, the positive electrode layer comprising a dried layer of the positive electrode slurry composition of claim 1 .
10. The positive electrode of claim 9 , wherein the metal substrate is an aluminum substrate.
11. A lithium battery comprising:
the positive electrode of claim 9 ;
a negative electrode facing the positive electrode and comprising a negative active material; and
an electrolyte between the positive electrode and the negative electrode.