Electrode of secondary cell including porous insulating layer, and manufacturing method thereof
The present invention provides a manufacturing method of a secondary cell electrode forming a porous insulating layer on at least one surface between a negative electrode and a positive electrode, including coating an electrode layer slurry on the electrode surface, coating the porous insulating layer while in a state in which the electrode layer slurry has not been dried, and simultaneously drying the electrode layer slurry and the porous insulating layer coating slurry so a binder of the porous insulating layer does not block the pores of the electrode layer.
1. A manufacturing method of a secondary cell electrode forming a porous insulating layer on at least one surface between a negative electrode and a positive electrode, comprising:
coating an electrode layer slurry on the electrode surface;
coating a porous insulating layer while in a state in which the electrode layer slurry has not been dried; and
drying the electrode layer slurry,
wherein the porous insulating layer is coated with only an inorganic compound powder or is coated with a mixed powder of the inorganic compound powder and functional inorganic compound additives,
wherein the additives of the functional inorganic compound include at least one of AlX 3 , MgX 2 , and SnX 2 ,
wherein X is a halogen, and
wherein the additives of the functional inorganic compound are included at 0.1 to 10 wt % of the solid content of the porous insulating layer.
2. The manufacturing method of claim 1 , wherein the electrode contains an active material, a conductive material, a polymer binder, and additives.
3. The manufacturing method of claim 2 , wherein the active material is at least one of a graphite series or a carbon series when the electrode is a negative electrode, and the active material is at least one of a transition metal-oxide series, a transition metal-phosphate series, a transition metal-silicate series, a transition metal-sulphate series, or polymer materials when the electrode is a positive electrode.
4. The manufacturing method of claim 2 , wherein the conductive material is at least one of graphite, carbon black, activated carbon, carbon nanotubes, and carbon nanofiber.
5. The manufacturing method of claim 2 , wherein the polymer binder is at least one of a copolymer of polyvinylidene fluoride, vinylidene fluoride, heaxfluoropropylene, a copolymer of vinylidene fluoride, maleic anhydride, polyvinyl chloride, polyvinyl alcohol, polyvinyl formal, polymethylmethacrylate, polymethacrylate, tetraethylene glycol diacrylate, cellulose triacetate, polyurethane, polysulfone, polyether, polyolefine, polyethylene oxide, polyisobutylene, polybutyldiene, polyacrylonitrile, polyimide, acrylonitrile-butadiene rubber, styrene-butadiene rubber, an ethylene-propylene-diene monomer, polydimethylsiloxane, and polysilicone.
6. The manufacturing method of claim 1 , wherein the inorganic compound powder is at least one of SiO 2 , Al 2 O 3 , TiO 2 , SnO 2 , ZnO, CeO 2 , ZrO 2 , BaTiO 3 , and Y 2 O 3 .
7. The manufacturing method of claim 6 , wherein the size of the inorganic compound powder is 0.001 to 1 micron.
8. The manufacturing method of claim 6 , wherein the content of the inorganic compound powder is 10 wt % or more of the porous insulating layer.
9. The manufacturing method of claim 1 wherein the coating thickness of the porous insulating layer after drying is 1 to 10 microns.
10. The manufacturing method of claim 1 wherein the electrode layer is dried at 50 to 200 degrees Celsius.