IP Library Granted Patent US 9,257,643
Granted Patent B2
US 9,257,643 · App. 13/968,529 · Granted Feb 9, 2016

Phase change memory cell with improved phase change material

Inventors: Huai-Yu Cheng (White Plains, NY); Simone Raoux (New York, NY)
Assignees: INTERNATIONAL BUSINESS MACHINES CORPORATION; MACRONIX INTERNATIONAL COMPANY, LTD.
H01L45/148H01L45/06H01L45/1233
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Quick Facts
Patent No.
US 9,257,643
App. No.
13/968,529
Granted
Feb 9, 2016
Kind
B2
Abstract

A phase change memory cell. The phase change memory cell includes a substrate and a phase change material. The phase change material is deposited on the substrate for performing a phase change function in the phase change memory cell. The phase change material is an alloy having a mass density change of less than three percent during a transition between an amorphous phase and a crystalline phase.

Claims (26)

1. A phase change memory cell, comprising:

a substrate; and

a phase change material deposited on the substrate for performing a phase change function in the phase change memory cell, the phase change material being an alloy having a mass density change of less than three percent during a transition between an amorphous phase and a crystalline phase, wherein the phase change material is formed from a mixture consisting of Gallium and Antimony and at least one of Silicon, Germanium, Arsenic, Selenium, Indium, Tin, Bismuth, Silver, and Gold, wherein the phase change material is formed from the mixture of Gallium and Antimony, the mixture comprising three atomic % parts Gallium to seven atomic % parts Antimony.

2. The phase change memory cell of claim 1 , wherein the phase change material comprises

at least two of Silicon, Germanium, Arsenic, Selenium, Indium, Tin, Bismuth, Silver, and Gold added to the mixture of Gallium and Antimony.

3. The phase change memory cell of claim 2 , wherein the mixture consists of Gallium, Antimony, and at least two of Indium, Silver, and Gold from among Silicon, Germanium, Arsenic, Selenium, Indium, Tin, Bismuth, Silver, and Gold.

4. The phase change memory cell of claim 1 , wherein the phase change material has an electrical contrast above an electrical contrast threshold and a switching time below a switching time threshold.

5. The phase change memory cell of claim 1 , wherein the mixture consists of Gallium, Antimony, and at least one of Silver and Gold from among Silicon, Germanium, Arsenic, Selenium, Indium, Tin, Bismuth, Silver, and Gold.

6. A method for forming a phase change memory cell, comprising:

providing a substrate; and

depositing a phase change material on the substrate for performing a phase change function in the phase change memory cell, the phase change material being an alloy having a mass density change of less than three percent during a transition between an amorphous phase and a crystalline phase, wherein the phase change material is formed from a mixture consisting of Gallium and Antimony and at least one of Silicon, Germanium, Arsenic, Selenium, Indium, Tin, Bismuth, Silver, and Gold, wherein the phase change material is formed from the mixture of Gallium and Antimony, the mixture comprising three atomic % parts Gallium to seven atomic % parts Antimony.

7. The method of claim 6 , wherein said depositing step comprises:

adding at least two of Silicon, Germanium (Ge), Arsenic (As), Selenium, Indium, Tin, Bismuth, Silver, and Gold to the mixture; and

depositing the mixture on the substrate.

8. The method of claim 7 , wherein the mixture consists of Gallium, Antimony, and at least two of Indium, Silver, and Gold from among Silicon, Germanium, Arsenic, Selenium, Indium, Tin, Bismuth, Silver, and Gold.

9. The method of claim 6 , wherein the phase change material has an electrical contrast above an electrical contrast threshold and a switching time below a switching time threshold.

10. The method of claim 6 , wherein the mixture consists of Gallium, Antimony, and at least one of Silver and Gold from among Silicon, Germanium, Arsenic, Selenium, Indium, Tin, Bismuth, Silver, and Gold.

11. A method for forming a phase change memory cell, comprising:

providing a substrate for the phase change material; and

depositing a mixture consisting of Gallium, Antimony and at least one of Silicon, Germanium, Arsenic, Selenium, Indium, Tin, Bismuth, Silver, and Gold on the substrate as a phase change material for a phase change portion of the phase change memory cell, the phase change material having a mass density change of less than 3 percent during a transition between an amorphous phase and a crystalline phase, wherein the phase change material is formed from the mixture of Gallium and Antimony, the mixture comprising three atomic % parts Gallium to seven atomic % parts Antimony.

12. The method of claim 11 , wherein said depositing step comprises:

adding at least two of Silicon, Germanium, Arsenic, Selenium, Indium, Tin, Bismuth, Silver, Gold to the mixture; and

depositing the mixture on the substrate.

13. The method of claim 12 , wherein the mixture consists of Gallium, Antimony, and at least two of Indium, Silver, and Gold from among Silicon, Germanium, Arsenic, Selenium, Indium, Tin, Bismuth, Silver, and Gold.

14. The method of claim 11 , wherein the phase change material has an electrical contrast above an electrical contrast threshold and a switching time below a switching time threshold.

15. The method of claim 11 , wherein the mixture consists of Gallium, Antimony, and at least one of Silver and Gold from among Silicon, Germanium, Arsenic, Selenium, Indium, Tin, Bismuth, Silver, and Gold.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 16, 2013
From: RAOUX, SIMONE
To: INTERNATIONAL BUSINESS MACHINES CORPORATION
Reel/Frame 031024/0034 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 16, 2013
From: CHENG, HUAI-YU
To: MACRONIX INTERNATIONAL COMPANY, LTD.
Reel/Frame 031024/0046 →
Continuity (1)
Related Publication 20150048291A1 · Feb 19, 2015