Porous material, manufacturing method of the same, and honeycomb structure
There is disclosed a porous material. The porous material contains aggregates, and a bonding material which bonds the aggregates to one another in a state where pores are formed among the aggregates, the bonding material contains crystalline cordierite, the bonding material further contains a rare earth element or a zirconium element, and a ratio of a mass of the bonding material to a total mass of the aggregates and the bonding material is from 12 to 45 mass %. The bonding material preferably contains, in the whole bonding material, 8.0 to 15.0 mass % of MgO, 30.0 to 60.0 mass % of Al 2 O 3 , 30.0 to 55.0 mass % of SiO 2 , and 1.5 to 10.0 mass % of a rare earth oxide or zirconium oxide.
1. A porous material containing aggregates, and a bonding material which bonds the aggregates to one another in a state where pores are formed among the aggregates,
wherein the bonding material contains crystalline cordierite,
the bonding material further contains a rare earth oxide or a zirconium oxide in an amount of 1.5 to 10.0 mass %,
a ratio of a mass of the bonding material to a total mass of the aggregates and the bonding material is from 12 to 45 mass %; and
a bending strength is 10 MPa or more and a bending strength/Young's modulus ratio is 1.8×10 −3 or more.
2. The porous material according to claim 1 ,
wherein the bonding material contains, in the whole bonding material, 8.0 to 15.0 mass % of MgO, 30.0 to 60.0 mass % of Al 2 O 3 , and 30.0 to 55.0 mass % of SiO 2 .
3. The porous material according to claim 1 ,
wherein the rare earth oxide is at least one selected from the group consisting of yttrium, lanthanum, cerium, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium.
4. The porous material according to claim 1 ,
wherein the bonding material contains 50 mass % or more of crystalline cordierite in the whole bonding material.
5. The porous material according to claim 1 ,
wherein the aggregates are silicon carbide particles or silicon nitride particles.
6. The porous material according to claim 1 ,
wherein a porosity is from 35 to 75%.
7. The porous material according to claim 1 ,
wherein a thermal expansion coefficient is 4.0×10 −6 /K or less.
8. A honeycomb structure which is constituted of the porous material according to claim 1 , and
comprises partition walls defining a plurality of cells extending from a first end face which is one end face to a second end face which is the other end face.
9. The honeycomb structure according to claim 8 ,
which comprises plugging portions disposed in open ends of the predetermined cells in the first end face and open ends of the residual cells in the second end face.
10. The porous material according to claim 1 , wherein the addition of the rare earth oxide or the zirconium oxide broadens the temperature range within which the porous material will sinter in a non-oxidizing atmosphere or atmosphere having an oxygen partial pressure of 10% or less to 1370° C. to 1450° C.
11. A manufacturing method of a porous material, comprising:
firing, at 1370 to 1450° C., a raw material for the porous material containing:
aggregate powder; and
a raw material for a bonding material including a cordierite forming raw material and a rare earth oxide or a zirconium oxide in an amount of 1.5 to 10.0 mass %, and
containing 12 to 45 mass % of the raw material for the bonding material in a total mass of the aggregate powder and the raw material for the bonding material, to manufacture the porous material;
wherein a bending strength of the porous material is 10 MPa or more and a bending strength/Young's modulus ratio is 1.8×10 −3 or more.