Conductive polymer, synthesis method thereof, and electroactive electrode covered with said conductive polymer
The present invention provides a conducting polymer, a synthesis method thereof, and an electroactive electrode covered with the said conducting polymer. The conducting polymer is synthesized as follows: use the polybasic acid as dopant and crosslinking agent, and polymerize monomers into conducting polymer hydrogel. The monomers are selected one or more from pyrrole or its derivatives, thiophene or its derivatives, aniline or its derivatives. The acid group of the polybasic acid contains phosphate or polybasic acid which contains at least two substituents per molecule selected from sulfate, nitrate or carboxylic in which the molecular weight of at least one acid group is no more than 800. The mole ratio of the acid group in polybasic acid to monomers of the conducting polymer is 1:12-12:1. The preparation applied in the invention is simple, and need not to import any impurity. The conducting polymer hydrogel has high ionic conductivity, super hydrophilicity, and good biocompatibility.
1. A method of synthesizing porous nanostructured conducting polymer, which comprises:
polymerizing monomers to form conducting polymer hydrogel by using a polybasic acid as a dopant and a crosslinking agent;
purifying and dehydrating said conducting polymer hydrogel to produce porous nanostructured conducting polymer;
wherein said monomer being selected from a group consisting of
(a) pyrrole or its derivatives,
(b) thiophene or its derivatives,
(c) aniline or its derivatives, and
wherein said polybasic acid either
containing phosphoric acid functional group, or
containing at least two acid functional groups per molecule,
selected from a category consisting of
(a) sulfonic acid group,
(b) nitric acid group, and
(c) carboxylic acid group,
and
having a molecular weight of less than or equal to 800 g/mol.
2. The method according to claim 1 , wherein the molar ratio of acid functional groups contained in the polybasic acid and the monomers of the conducting polymer is between 1:20 and 12:1.
3. The method according to claim 2 , wherein the polybasic acid is selected from the group consisting of phytic acid, phosphoric acid, polyethylene phosphoric acid, N-butylsulfonate-3-methylimidazolium hydrogen sulfate, N-butylsulfonate pyridinium hydrogen sulfate and 1,2,4,5-benzenetetracarboxylic acid.
4. The method according to claim 1 , wherein the polybasic acid is selected from a group consisting of phytic acid, phosphoric acid, polyethylene phosphoric acid, N-butylsulfonate-3-methylimidazolium hydrogen sulfate, N-butylsulfonate pyridinium hydrogen sulfate and 1,2,4,5-benzenetetracarboxylic acid.
5. The method according to claim 4 , wherein the polybasic acid is phytic acid.
6. The method according to claim 1 , wherein a water content of the conducting polymer hydrogel is between 30-85%.
7. The method according to claim 1 , wherein monomers are oxidized by an oxidant to form conducting polymer hydrogel by means of chemical oxidative polymerization.
8. The method according to claim 7 , wherein the oxidant is selected from a group consisting of persulfate, iron (III) chloride, copper (II) chloride, silver nitrate, hydrogen peroxide, chloroauric acid and ammonium cerium(IV) nitrate.
9. The method according to claim 7 further comprising:
(a) making solution (solution A) containing the oxidant;
(b) making solution (solution B) containing the monomers; and
(c) mixing solution A and solution B, so that monomers are polymerized to form conducting polymer hydrogel,
wherein solution A is aqueous solution, solution B is aqueous or organic solution, and the polybasic acid is added in solution A and/or solution B.
10. The method according to claim 1 , wherein a molar ratio of the acid functional groups contained in the polybasic acid and the monomers of the conducting polymer is between 2:1 and 1:2.
11. The method according to claim 1 , wherein a water content of the conducting polymer hydrogel is between 34-85%.